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81.
谢家麟 庄杰佳 黄永章 张令翊 林绍波 赵春农 李立华 吴钢 王钢 李承泽 傅恩生 苏憬 钟元元 王言山 李永贵 应润杰 杨学平 李有猛 韩斌 吴庆武 张玉珍 潘卫民 王建伟 张黎文 郭康柱 畅祥云 李亚南 戴立盛 徐金强 陆辉华 汪伯嗣 任廉重 田瑞生 《中国物理 C》1994,18(8):763-768
北京自由电子激光(BFEL)装置于1993年底在10.68μm处实现了饱和振荡.输出激光能量为3mJ,饱和平顶宽度2μs.对应饱和振荡平均功率为210kW(宏脉冲),峰值功率约为20MW,比自发辐射高8个量级,单程小讯号净增益为24%,转换效率为0.45%,与理论预期结果相符.光束质量接近衍射极限.目前装置可工作于9-11μm. 相似文献
82.
Thermotropic copolyester fibers of oxynaphthoate and oxybenzoate have been subjected to conditions that promote solid-state polymerization as well as annealing. The annealing process causes the crystals to perfect with a simultaneous increase in heat of fusion and melting temperature. Solid-state polymerization, a reaction rate-controlled process, causes the polymer viscosity average molecular weight to increase by chain extension from about 14,000 g/mole to more than 87,000 g/mole with a simultaneous impressive increase in tenacity from about 10 g/d (1.2 GPa) to almost 30 g/d (3.7 GPa). To understand the changes in mechanical properties, we have modeled the fiber structure as short rod-like molecules poorly bonded to a continuous matrix of parallel molecules. Lengthening of the reinforcing molecules facilitates better transfer of load from matrix to molecules, resulting in higher tenacity fibers. © 1994 John Wiley & Sons, Inc. 相似文献
83.
The question about the definition of the “internal pressure” concept is being discussed. It is shown that the previously found differential relation between the cohesion energy density and the internal pressure is one of the examples of an absolutely general interrelation between definitely connected differential functions. It is ascertained that the ratio (the internal pressure divided by the cohesion energy density) is a structuresensitive parameter inherent to the calorific (thermal) equation of a liquid state. 相似文献
84.
A new, high performance liquid chromatography method has been developed for the separation of monovinyl- and divinyl-protochlorophyllides, using commercially available, C30 reverse phase column and isocratic elution. This method can be used both for analytical applications and preparative scale purification of monovinyl- and divinyl-protochlorophyllides using the same column where submilimolar concentrations of the crude protochlorophyllide extract can be separated in one run. The purity of the obtained protochlorophyllides was demonstrated by spectroscopic methods, as well by the formation of aggregates in toluene. 相似文献
85.
We investigated the features of the glass transition relaxation of two room temperature ionic liquids using DSC. An important
observation was that the heat capacity jump, that is the signature of the glass transition relaxation, shows a particularly
strong value in this type of new and promising materials, candidates for a range of applications. This suggests a high degree
of molecular mobility in the supercooled liquid state. The study of the influence of the heating rate on the temperature location
of the glass transition signal, allowed the determination of the activation energy at the glass transition temperature, and
the calculation of the fragility index of these two ionic glass-formers. It was concluded that this kind of materials belong
to the class of relatively strong glass-forming systems.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
86.
Kaname SasakiHideyuki Nagai Shuichi MatsumuraKazunobu Toshima 《Tetrahedron letters》2003,44(30):5605-5608
The glycosidations of glucopyranosyl diethyl phosphite and alcohols using an ionic liquid, 1-n-hexyl-3-methylimidazolium trifluoromethanesulfonimidide (C6mim[NTf2]) containing a protic acid, trifluoromethanesulfonimide (HNTf2), as a novel solvent-catalyst system, effectively proceeded under mild conditions to give the corresponding glycosides in good to high yields. Furthermore, this acid-ionic liquid combination could be reused many times for the glycosidations without any loss in efficiency. 相似文献
87.
Kuan‐Wei Lee Hong‐Cheu Lin 《Journal of polymer science. Part A, Polymer chemistry》2007,45(20):4564-4572
A series of new liquid crystalline homopolymers, copolymers, and block copolymers were polymerized from styrene‐macroinitiator ( SMi ) and methacrylates with pendent 4,4′‐bis(biphenyl)fluorene ( M1 ) and biphenyl‐4‐ylfluorene ( M2 ) groups through atom transfer radical polymerization (ATRP). The number‐average molecular weights (Mn) of polymers P1 ‐ P4 were 10,007, 14,852, 6,275, and 10,463 g mol?1 with polydispersity indices values of 1.21, 1.15, 1.31, and 1.22, respectively. All polymers exhibit the nematic phase. The thermal, mesogenic, and photoluminescent properties of all polymers were investigated. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4564–4572, 2007 相似文献
88.
A liquid chromatography-mass spectrometry method for the determination of the coccidiostats metronidazole, ronidazole, dimetridazole,
secnidazole, tinidazole and ipronidazole in feedstuff was developed. The 5-nitroimidazoles were extracted from animal feed
with a pH 2 phosphate buffer solution followed by a solid phase extraction procedure based on HLB cartridges. The liquid chromatographic
separation of the extracts was performed on a C18 bonded silica column applying a gradient of elution with pH 4.3 ammonium acetate buffer solution and acetonitrile. Quantification
for each 5-nitroimidazole was carried out monitoring its molecular ion [M + H]+ obtained by positive electrospray ionisation mode. A pool of feedstuffs was used to optimise and validate the method. Linearity,
quantification limit, intra-day and inter-day reproducibility and accuracy were estimated using this pool of feedstuffs spiked
with the drugs. For the confirmatory assay, several fragment ions from each 5-nitroimidazole were obtained and monitored.
The method was applied successfully to determine 5-nitroimidazoles in feedstuff at level of 0.05 mg kg−1. 相似文献
89.
Thi Thi Nge Naruhito Hori Akio Takemura Hirokuni Ono Tsunehisa Kimura 《Journal of Polymer Science.Polymer Physics》2003,41(7):711-714
A high magnetic field of 5 T was used to fabricate a magnetically aligned, optically anisotropic, liquid‐crystalline chitin/poly(acrylic acid) composite. The aligned mesophase was fixed by photoinitiated free‐radical polymerization. From an examination of polarized optical micrographs and an X‐ray diffraction study, a high degree of orientation of 0.70 was observed for the composite with a higher liquid‐crystalline chitin concentration (10.70 wt %); the orientation was reduced with a decreased chitin concentration at a given acrylic acid concentration. The X‐ray data for the developed composite showed a uniplanar orientation for the chitin crystallites, with its molecular long axes perpendicular to the direction of the magnetic field. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 711–714, 2003 相似文献
90.
Isabel Cristina S. F. Jardim Kenneth E. Collins Carol H. Collins 《Microchemical Journal》2004,77(2):191-198
Polysiloxanes immobilized onto the surfaces of porous silica particles have proven to be good stationary phases for the separation of multiresidues of pesticides and their metabolic/degradation products by reversed-phase high-performance liquid chromatography (RP-HPLC). Similar materials have proven effective for pre-concentration and clean-up procedures using solid phase extraction. The present paper describes the preparation and some applications of several of these packing materials. 相似文献