全文获取类型
收费全文 | 3242篇 |
免费 | 342篇 |
国内免费 | 361篇 |
专业分类
化学 | 697篇 |
晶体学 | 16篇 |
力学 | 196篇 |
综合类 | 116篇 |
数学 | 2185篇 |
物理学 | 735篇 |
出版年
2024年 | 6篇 |
2023年 | 18篇 |
2022年 | 48篇 |
2021年 | 72篇 |
2020年 | 80篇 |
2019年 | 72篇 |
2018年 | 80篇 |
2017年 | 92篇 |
2016年 | 96篇 |
2015年 | 72篇 |
2014年 | 158篇 |
2013年 | 306篇 |
2012年 | 157篇 |
2011年 | 206篇 |
2010年 | 168篇 |
2009年 | 221篇 |
2008年 | 223篇 |
2007年 | 220篇 |
2006年 | 193篇 |
2005年 | 172篇 |
2004年 | 174篇 |
2003年 | 163篇 |
2002年 | 161篇 |
2001年 | 119篇 |
2000年 | 91篇 |
1999年 | 111篇 |
1998年 | 96篇 |
1997年 | 82篇 |
1996年 | 48篇 |
1995年 | 39篇 |
1994年 | 35篇 |
1993年 | 21篇 |
1992年 | 23篇 |
1991年 | 11篇 |
1990年 | 20篇 |
1989年 | 16篇 |
1988年 | 13篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 10篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1974年 | 2篇 |
1970年 | 1篇 |
1959年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有3945条查询结果,搜索用时 312 毫秒
121.
Hongyun Zhang Wen Li Xiaokai Zhang Fahong Miao Taohai Li Haihua Liu 《Surface and interface analysis : SIA》2013,45(5):919-929
A selection of suitable microstructures is critical to fabrication and properties of superhydrophobic surfaces (SHS). In this study, we introduce a three‐dimensional droplet model to thermodynamically analyze the superhydrophobic properties for the purpose of determining the second step of a two‐step microstructure suitable for the SHS based on the common models within the reach of the existing macro‐machining technology. It is found that a sinusoidal microstructure is the most suitable, followed by a cone frustum and a prism in the composite wetting state, as well as the transition from hydrophilic to hydrophobic depends basically on the solid fraction rather than non‐determinative surface microscopic topography. The predictions of the model are found in quite good agreement with the experimental observations. This study will facilitate fabrication of the SHS on how to select the suitable morphology. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
122.
Zhengxiao Zhang Prof. Eiji Nakata Dr. Huyen Dinh Dr. Masayuki Saimura Prof. Arivazhagan Rajendran Prof. Kazunari Matsuda Prof. Takashi Morii 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(72):18118-18128
Recognition-driven modification has been emerging as a novel approach to modifying biomolecular targets of interest site-specifically and efficiently. To this end, protein modular adaptors (MAs) are the ideal reaction model for recognition-driven modification of DNA as they consist of both a sequence-specific DNA-binding domain (DBD) and a self-ligating protein-tag. Coupling DNA recognition by DBD and the chemoselective reaction of the protein tag could provide a highly efficient sequence-specific reaction. However, combining an MA consisting of a reactive protein-tag and its substrate, for example, SNAP-tag and benzyl guanine (BG), revealed rather nonselective reaction with DNA. Therefore new substrates of SNAP-tag have been designed to realize sequence-selective rapid crosslinking reactions of MAs with SNAP-tag. The reactions of substrates with SNAP-tag were verified by kinetic analyses to enable the sequence-selective crosslinking reaction of MA. The new substrate enables the distinctive orthogonality of SNAP-tag against CLIP-tag to achieve orthogonal DNA-protein crosslinking by six unique MAs. 相似文献
123.
Let A be a basic hereditary artin algebra and R = A Q be the trivial extension of A by its minimal injective cogenerator Q. We construct some right (left) almost split morphisms and irreducible morphisms in modR through the corresponding morphisms in modA. Furthermore, we can determine its almost split sequences in modR. 相似文献
124.
Niels ten Brummelhuis Marcus Weck 《Journal of polymer science. Part A, Polymer chemistry》2014,52(11):1555-1559
Reversible addition‐fragmentation chain‐transfer (RAFT) polymerization was used to control the alternating copolymerization of styrene and 2,3,4,5,6‐pentaflurostyrene. The RAFT polymerization yields a high degree of control over the molecular weight of the polymers and does not significantly influence the reactivity ratios of the monomers. The controlled free‐radical polymerization could be initiated using AIBN at elevated temperatures or using a redox couple (benzoyl peroxide/N,N‐dimethylaniline) at room temperature, while maintaining control over molecular weight and dispersity. The influence of temperature and solvent on the molecular weight distribution and reactivity ratios were investigated. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1555–1559 相似文献
125.
B. A. Strukov 《Phase Transitions》2013,86(2-3):143-179
A review of the basic experimental results connected with the formation of long-living metastable states in the incommensurate phases of ferroelectric crystals and related phenomena is given. The interpretation and appropriate physical mechanisms underlying the global hysteresis phenomena associated with these states are considered. 相似文献
126.
LIN ZhengYan & ZHAO YueXu 《中国科学 数学(英文版)》2012,(10):2156-2179
We establish strong invariance principles for sums of stationary ρ-mixing random variables with finite and infinite second moments under weaker mixing rates.Some earlier results are improved.As applications,some results of the law of the iterated logarithm with finite and infinite variance are obtained,also a conjecture raised by Shao in 1993 is solved. 相似文献
127.
Fatigue damage behavior of a surface-mount electronic package under different cyclic applied loads 下载免费PDF全文
This paper studies and compares the effects of pull-pull and 3-point bending cyclic loadings on the mechanical fa- tigue damage behaviors of a solder joint in a surface-mount electronic package. The comparisons are based on experimental investigations using scanning electron microscopy (SEM) in-situ technology and nonlinear finite element modeling, respec- tively. The compared results indicate that there are different threshold levels of plastic strain for the initial damage of solder joints under two cyclic applied loads; meanwhile, fatigue crack initiation occurs at different locations, and the accumulation of equivalent plastic strain determines the trend and direction of fatigue crack propagation. In addition, simulation results of the fatigue damage process of solder joints considering a constitutive model of damage initiation criteria for ductile materials and damage evolution based on accumulating inelastic hysteresis energy are identical to the experimental results. The actual fatigue life of the solder joint is almost the same and demonstrates that the FE modeling used in this study can provide an accurate prediction of solder joint fatigue failure. 相似文献
128.
Yan Zhang 《Numerical Functional Analysis & Optimization》2019,40(11):1268-1290
G-frames generalize frames in Hilbert spaces. The literatures show that g-frames and frames share many similar properties, while they behave differently in redundancy and perturbation properties. Interestingly, g-frames have been extensively studied, but g-frame sequences have not. This problem is nontrivial since a g-frame and a frame both involve all vectors in the same Hilbert space, while a g-frame sequence and a frame sequence do not. They involve different linear spans. Using the synthesis and Gram matrix methods, we in this paper characterize g-frame sequences and g-Riesz sequences; obtain the Pythagorean theorem for g-orthonormal systems. These results recover several known results and lead to some new results on g-frames. 相似文献
129.
利用同余式、平方剩余、Pell方程的解的性质、递归序列证明了:不定方程x3-1=749y2仅有整数解(x,y)=(1,0). 相似文献
130.
张四保 《数学的实践与认识》2020,(7):273-276
设S(n)是Smarandache函数,其中n是一正整数.讨论Smarandache函数S(n)在数列F((2k),1)=F(n,1)=n2n+1(n=2k)与数列G(2n,1)=(2n)2n+1上的下界估计.基于初等方法证明了:当偶数n≥6时,有S(F((2k),1))=S(F(n,1))≥6×2n+1;当n≥4时,有S(G(2n,1))≥6×2n+1. 相似文献