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111.
纳米金修饰玻碳电极在抗坏血酸共存下选择性测定去甲肾上腺素 总被引:16,自引:0,他引:16
利用电沉积的方法制得纳米金修饰玻碳电极 ,该修饰电极对去甲肾上腺素 (NE)氧化反应有催化作用。去甲肾上腺素在纳米金修饰玻碳电极上有很强的吸附作用。研究了磷酸缓冲溶液的pH值和浓度对NE的电化学行为的影响。从去甲肾上腺素和抗坏血酸在纳米金修饰电极的循环伏安图上可观察到两个明显分开的氧化峰 ,峰电位差达到 1 3 1mV ,因此 ,可利用该修饰电极在抗坏血酸存在下选择性测定去甲肾上腺素 ,线性范围为 1× 1 0 - 4 ~5× 1 0 - 6 mol L。 相似文献
112.
Sm修饰的Ni-MgO催化剂制备碳纳米管的研究 总被引:2,自引:0,他引:2
Carbon nanotubes (CNTs) have been synthesized over Ni-MgO and Ni-Sm-MgO catalysts by decomposition of CH4 at 650 ℃. The addition of Sm into Ni-MgO catalyst not only promotes the catalytic activity and lifetime of the catalyst, but also improves the graphitization and heat stability of carbon nanotubes. The yield of CNTs obtained over the Ni-10Sm-MgO catalyst reaches 33 g C·(g Ni)-1, being more than 5 times higher than that of the Ni-MgO catalyst. XRD and TPR results of the catalysts indicate that there is a remarkable interaction of Ni with Sm species, which facilitates the reduction of nickel and restrains the Ni particles from agglomerating. 相似文献
113.
Zdeněk Slanina 《Journal of Cluster Science》2004,15(1):3-11
Computational findings of temperature increase of clustering degree in saturated vapors are analyzed. A thermodynamic proof is presented and a simple criterion derived. Illustrations are based on saturated steam, magnesium and carbon vapor. The results are applicable to synthesis of fullerenes, metallofullerenes, and heterofullerenes, chemical vapor deposition technique, or atmospheric chemistry. 相似文献
114.
Organic chelating reagent influences upon the redox adsorption of activated carbon fibertowards Au3- were systematically investigated. The experimental results indicated that the presenceof organic chelating reagent on activated carbon fiber strongly affects adsorption capacity ofactivated carbon fiber towards Au3+. The reduction-adsorption amount of Au3+ increased three timesby the presence of 8-quinolinol. Furthermore, The reduction-adsorption amount of Au3+ depended onthe pH value of adsorption and temperature. 相似文献
115.
杂多酸的固载化─关于制备负载型酸催化剂的一般原理 总被引:10,自引:0,他引:10
杂多酸同时具有酸和氧化-还原的催化特性,有着很广泛的应用前景.这类化合物在一系列精细合成中取代硫酸作为催化剂以满足环保的要求,显示出了很大的潜力.杂多酸固载化后,不仅能在液相氧化和酸催化反应中把催化剂从反应介质中很方便地分离出来,而且还为这类均相催化反应的多相化,甚至利用催化蒸馏新工艺等创造了应有的条件,可以使生产工艺大大简化,获得更广泛的应用.本文以很好表征过的多种孔性材料,包括氧化物,如Al_2O_3、SiO_2、TiO_2、硅藻土、膨润土和来源不同的活性炭为载体,考察了负载杂多酸催化剂的催化活性.在大量前期工作的基础上,通过总结载体对固载杂多酸催化活性的影响等,探讨载体的内在性质在杂多酸固载、吸附和催化反应中的作用本质,为由吸附法制备各种负载型固体酸催化剂在液相中的应用提供可资参考的模型. 相似文献
116.
Savos'kin M. V. Yaroshenko A. P. Mysyk R. D. Vaiman G. E. Vovchenko L. L. Popov A. F. 《Theoretical and Experimental Chemistry》2004,40(2):92-97
New thermally stable intercalation compounds of graphite were obtained by the further intercalation of a series of organic compounds into graphite nitrate. The stabilization is explained by the formation of hydrogen bonds between the protonated form of the modifying substance and neutral surrounding molecules. 相似文献
117.
V. P. Borovik I. Yu. Bagryanskaya Yu. V. Gatilov O. P. Shkurko 《Journal of Structural Chemistry》2003,44(4):650-654
The crystal structures of 2-amino-4-phenyl-9H-pyrimido[4,5-b]indole and its nitrate were determined by XRD analysis. 13C NMR, XRD, and quantum-chemical data indicate that the acid proton is predominantly localized at the N(3) atom of the pyrimidine ring in both isolated nitrate molecules and in molecules in crystal and solution. 相似文献
118.
A. Bismarck M. Pfaffernoschke M. Selimović J. Springer 《Colloid and polymer science》1998,276(12):1110-1116
The grafting method that has successfully been applied to methacrylic acid and liquid crystalline monomers was expanded to
prepare amphoteric carbon fiber surfaces using 2-(N,N-dimethylamino)ethyl methacrylate as monomer. The obtained carbon fiber surfaces were characterized by contact angle and ζ-potential
measurements. The expected basic behavior was not observed, instead an amphoteric character of the modified carbon fiber surface
was found. The fiber surfaces display a basic character in the acidic pH-range, while they are acidic in the alkaline part
of the pH-scale.
An important influence is derived from the amount of initiator used to graft the monomers onto the fibers. The smaller the
initiator concen-tration used during polymerization, the larger the amount of amino functionalities introduced to the carbon
fiber surface.
The wetting behavior versus water depends on the overall conformation of the immobilized polymer. During immersion into water
the polymer acts hydrophobic, while during emersion, a hydrophilic character is observed, probably derived from conformational
changes and swelling during the contact angle measure-ments in water.
Received: 9 June 1998 Accepted: 13 August 1998 相似文献
119.
采用固相反应法合成A缺位的(La0.8Sr0.2)0.95MnO3(LSM95)作为阴极材料,Zr0.9Sc0.1SO1.95(SSZ)商业粉体作为电解质材料,溶胶-凝胶法合成的La0.8Sr0.2Cr0.5Mn0.5O3-(LSCrM)作为阳极电催化材料,利用流延、共烧结及浸渍法得到结构为LSCrM-CeO2|SSZ|3YSZ-LSM95的阴极支撑型固体氧化物燃料电池,分别在氢气气氛和甲烷气氛中进行电化学性能测试. 结果表明,浸渍0.11 g·cm -2 CeO2的LSCrM-CeO2|SSZ|3YSZ-LSM95单电池在以CH4为燃料时,600、650、700、750和800 oC下的功率密度分别为1.68、4.70、12.40、28.08和54.78 mW·cm -2,表现出一定的电化学性能和较好的稳定性. 相似文献
120.
Densities of four aqueous NaNO3 solutions (0.100, 0.303, 0.580, 0.892 mol-kg–1 H2O) have been measured in the liquid phase with a constant-volume piezometer immersed in a precision liquid thermostat. Measurements were made at ten isotherms between 292 and 573 K. The range of pressure was 0.1–30 MPa. The total uncertainty of density, pressure, temperature, and concentration measurements were estimated to be less than 0.06%, 0.05%, 10 mK, and 0.014%, respectively. Values of saturated densities were determined by extrapolating experimental P- data to the vapor pressure at fixed temperature and composition. Apparent molar volumes were derived using measured values of density for the solutions and for pure water. The apparent molar volumes were extrapolated to zero concentration to yield partial molar volumes at infinite dilution. The temperature, pressure, and concentration dependence of partial and apparent molar volumes were studied. The measured values of density and apparent and partial molar volume were compared with data reported in the literature. 相似文献