Temperature Development of Homo- and Hetero-Clustering in Saturated Vapors |
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Authors: | Zdeněk Slanina |
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Institution: | (1) Department of Theoretical Studies, Institute for Molecular Science, Myodaiji, Okazaki, 444-8585, Japan;(2) Academia Sinica, Institute of Chemistry, 128 Yen-Chiu-Yuan Rd., Sec. 2, Nankang, Taipei, 11529, Taiwan, Republic of China |
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Abstract: | Computational findings of temperature increase of clustering degree in saturated vapors are analyzed. A thermodynamic proof is presented and a simple criterion derived. Illustrations are based on saturated steam, magnesium and carbon vapor. The results are applicable to synthesis of fullerenes, metallofullerenes, and heterofullerenes, chemical vapor deposition technique, or atmospheric chemistry. |
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Keywords: | Cluster formation thermodynamic computation carbon clusters water clusters atomic clusters |
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