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991.
Studies on Phase Behavior of Alkyl Polyglucoside Based on Microemulsions with Modified Fishlike Phase Diagram 总被引:1,自引:0,他引:1
JinLingCHAI GanZuoLI ZhaoYuDIAO GaoYongZHANG 《中国化学快报》2004,15(3):361-364
The three-phase behavior in the quaternary system of an alkyl (C8/10^- or C12/14^-)polyglucoside / 1-butanol / n-octane / water has been studied at 40℃ with the modified fishlike phase diagram, which is presented by us for the first time. The mass fraction of 1-butanol in the hydrophile-lipophile balanced interfacial layer, A^S, the coordinates of the start point B and the end point E of the phase diagram, and the solubilities of alkyl polyglucoside and 1-butanol in n-octane phase were calculated. The solubilization of the microemulsion was also discussed. 相似文献
992.
993.
Jakubus P. Adamski A. Kurzawa M. Sojka Z. 《Journal of Thermal Analysis and Calorimetry》2003,72(1):299-310
The structure and surface properties of ZrO2 strongly depend on its preparation. In the present work the impact of prolonged aging at basic conditions (pH = 9, T = 100°C, t = 48 h), on the phase composition and textural properties, obtained by calcination of the precipitate, was investigated using
several techniques conjointly (DTA/TG, DSC, XRD, porosimetry). The thermal effects accompanying the ZrO2·xH2O gel formation, the coalescence of the particles and crystallization were evaluated and discussed in terms of the structural
differences between the aged and non-aged samples.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
994.
The main thermodynamic characteristics of the adsorption of haloadamantanes on graphitized thermal carbon black were determined by experimental measurements and by calculations in terms of molecular-statistic theory of adsorption. Using experimental data, the Kovac retention indices were calculated and the optimum conditions for gas-chromatographic separation of haloadamantanes on stationary phases with different polarity were elucidated. The influence of the cage effect in the adamantane unit on the chromatographic properties of haloadamantanes was established. 相似文献
995.
STUDY OF Cu-Mu CATALYST FOR THE SYNTHESIS OF METHYL FORMATE AND METHANOL FROM SYNTHESIS GAS 下载免费PDF全文
将一种新型的CuMn催化剂用于由合成气合成甲酸甲酯和甲醇,该催化剂表现出良好的反应活性和甲酸甲酯选择性。考察了反应温度、合成气压力及催化剂制备方法等对合成甲酸甲酯和甲醇的反应活性及选择性的影响。在反应条件下,产物收率最高达60.10g/(L·h),产物甲酸甲酯的选择性很高。用BET、XRD及XPSAuger等测试方法对催化剂的比表面、晶相组成以及铜、锰在催化剂中的价态进行了表征,并探讨了催化剂失活的原因。 相似文献
996.
锆系Laves相储氢合金电极的性能研究 总被引:11,自引:0,他引:11
Zr(V0.2Mn0.2Mo0.06Ni0.54)2.4合金经HF溶液处理后,合金表面由富Zr和富Mn层转变成富Ni层,从而使电极初期活化周期明显缩短,电极表面氢吸附性能改善。表面反应电阻减小。本文探讨了上述电极表面反应机理,即表面Ni的催化、氢吸附和氢转移机理,对阻抗谱进行拟合,给出了相应的电极反应等效电路。 相似文献
997.
E. Lancry E. Levi A. Mitelman S. Malovany D. Aurbach 《Journal of solid state chemistry》2006,179(6):1879-1882
The Chevrel phase (CP), Mo6S8, was found to be an excellent cathode material for rechargeable magnesium batteries. Mo6S8 is obtained by a leaching process of Cu2Mo6S8, which removes the copper. A new method of Cu2Mo6S8 production was developed. In contrast to the well-known solid-state synthesis of CP, the method is based on the reaction in a molten salt media (KCl). A fast kinetics of this reaction allows using less active, but more convenient precursors (sulfides instead of sulfur), decreasing temperature and synthesis duration, as well as operation in the inert atmosphere instead of dynamic evacuated systems. It was shown that the composition and the electrochemical behavior of the products obtained by MSS and by the solid-state synthesis are identical. Thus, the molten salt method is extremely attractive for the large-scale production of the active materials for Mg batteries. 相似文献
998.
Suset Rodríguez-Alemn Ernesto M. Hernndez-Cooper Rolando Prez-lvarez Jos A. Otero 《Molecules (Basel, Switzerland)》2021,26(2)
Front tracking and enthalpy methods used to study phase change processes are based on a local thermal energy balance at the liquid–solid interface where mass accommodation methods are also used to account for the density change during the phase transition. Recently, it has been shown that a local thermal balance at the interface does not reproduce the thermodynamic equilibrium in adiabatic systems. Total thermal balance through the entire liquid–solid system can predict the correct thermodynamic equilibrium values of melted (solidified) mass, system size, and interface position. In this work, total thermal balance is applied to systems with isothermal–adiabatic boundary conditions to estimate the sensible and latent heat stored (released) by and salts which are used as high-temperature phase change materials. Relative percent differences between the solutions obtained with a local thermal balance at the interface and a total thermal balance for the thermal energy absorbed or released by high-temperature phase change materials are obtained. According to the total thermal balance proposed, a correction to the liquid–solid interface dynamics is introduced, which accounts for an extra amount of energy absorbed or released during the phase transition. It is shown that melting or solidification rates are modified by using a total thermal balance through the entire system. Finally, the numerical and semi-analytical methods illustrate that volume changes and the fraction of melted (solidified) solid (liquid) estimated through a local thermal balance at the interface are not invariant in adiabatic systems. The invariance of numerical and semi-analytical solutions in adiabatic systems is significantly improved through the proposed model. 相似文献
999.
采用多维气相色谱法,既可提高丙烯醛、丙酮、乙腈、丙烯腈相邻两组分的分离度,又可提高分析速度。按GDX-502与402的体积比为85∶15比例混装长4.5m、内径3mm的色谱柱;氢气作为载气,流速为65mL/min;柱箱初温140℃保持15min,以15℃/min的速率升至180℃保持12min。丙烯腈样品中7种组分即可全部出峰,总分析时间为30min,比原国标推荐的方法缩短了近50min。 相似文献
1000.
The present short review deals with electroanalytical aspects of electrochemical response of ascorbic acid (Vitamin C) at conducting and electrogenerated polymer modified electrodes. Two main topics are considered: (i) electrocatalytic oxidation of ascorbate at conducting polymer modified electrodes, leading to electroanalytical techniques for ascorbate assay, and (ii) retardation of ascorbate penetration through a layer of electrogenerated polymers, leading to permselective coatings and their diverse uses, especially for biosensing devices. 相似文献