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991.
992.
993.
真空电弧的特性直接受到从阴极斑点喷射出的等离子体射流的影响,对等离子体射流进行数值仿真有助于我们深入了解真空电弧的内部物理机制.然而,磁流体动力学和粒子云网格仿真方法受限于计算精度和计算效率的原因,无法有效地应用于真空电弧等离子体射流仿真模拟.本文开发了一套三维等离子体混合模拟算法,并在此基础上建立了真空电弧单阴极斑点射流仿真模型,模型中将离子作宏粒子考虑,而电子作无质量流体处理,仿真计算了自生电磁场与外施纵向磁场作用下等离子体的分布运动状态.仿真结果表明,单个阴极斑点情况下真空等离子体射流在离开阴极斑点后扩散至极板间,其整体几何形状为圆锥形,离子密度从阴极到阳极快速下降.外施纵向磁场会压缩等离子体,使得等离子体射流径向的扩散减少并且轴线上的离子密度升高.随着外施纵向磁场的增大,其对等离子体射流的压缩效应增强,表现为等离子体射流的扩散角度逐渐减小.此外,外施纵向磁场对等离子体射流的影响也受到电弧电流大小的影响,压缩效应随电弧电流的增加而逐渐减弱. 相似文献
994.
Polycrystalline K2.5Bi2.5Ti4O13 (I) is prepared by solid state reaction of KNO3, Bi2O3, and TiO2 (Al2O3 crucible, 750 °C, 16 h). 相似文献
995.
Chun‐Hai Wang Maxim Avdeev Brendan J. Kennedy Michael Kuepers Chris D. Ling 《ChemInform》2016,47(42):no-no
Polycrystalline gaudefroyite‐type YCa3(CrO)3(BO3)4 with Cr3+ ions (3d3, S = 3/2) forming an undistorted Kagome lattice is prepared by reaction of a stoichiometric mixture of Y2O3, CaCO3, Cr2O3, H3BO3 in a KCl flux (Al2O3 crucible, 1000 °C, 1 d) followed by re‐grinding and further annealing (1000 °C, 2 d, 95% yield). 相似文献
996.
Ghodrat Mahmoudi Habibar Chowdhury Samuel E. Lofland 《Journal of Coordination Chemistry》2017,70(12):1973-1983
Two coordination polymers, [Mn2(μ-L1)2(μ-N3)2]n (1) and [Mn(μ-HL2)(SCN)2]n (2), were assembled in a single-pot from MnCl2·4H2O, HL1 (2-acetylpyridine isonicotinoylhydrazone) or HL2 (2-acetylpyridine nicotinoylhydrazone) and ancillary ligand sources (NaN3 or NH4NCS). The products were fully characterized, including by single-crystal X-ray diffraction, which revealed a 2-D metal–organic layer in 1 and a 1-D zigzag coordination chain in 2. Both 1 and 2 are constructed from six-coordinate Mn(II) nodes that adopt distorted octahedral (MnN5O) environments; the adjacent nodes are driven by the μ-L1 and μ-N3 linkers in 1 or μ-HL2 linkers in 2 to form different metal–organic networks. Their topological classification was performed, disclosing the hcb and 2C1 topology in 1 and 2, respectively. Different weak non-covalent interactions promote dimensionality extension. Variable-temperature magnetic susceptibility measurements were carried out, revealing weak ferromagnetic and antiferromagnetic interactions in 1 and 2, respectively. 相似文献
997.
A new form of charged particle energy analyser is proposed. It is broadly based on the 180° magnetic spectrograph, but is intended to detect charged particles moving out of the dispersion plane with a helical motion. The analyser has the capability to acquire charged particle energy spectra over a large energy range, similar to those acquired in Auger electron spectroscopy, ca. 2500 eV and large angular range, up to 90°, in parallel. These conditions are more favourable for surface analysis by electron spectroscopy at high vacuum, where for example an electron energy resolution of 0.2% to 0.5% is typical. Expressions showing how the landing positions of the charged particles on the detector vary as a function of energy and polar take off angle are determined as well as the conditions for optimum energy resolution at a range of polar take off angles. The equations reveal that in general, the device obtains the highest resolution at angles of revolution greater than 180°. The design is simple and could be easily put into practice using available material and technologies and be used to analyse the energies of electrons emitted from a sample placed in a scanning electron microscope. It can be made to function with a primary electron beam of any desired energy and could fit in to the small space between the sample and the end of an electron column. However, the device is difficult to retrofit into existing SEMs and ideally an SEM column needs to be designed to work in association with the analyser. The direction of the magnetic field of the analyser is coincident with the axis of the electron gun so that the primary beam is little influenced by the magnetic field and symmetry can be maintained in the primary beam electron column. Because the device is intended to acquire electron spectra in parallel, any movement of the primary beam on the sample because of a ramping field in the analyser is avoided. The field of view and the effect of the analyser upon the operation of the SEM are discussed. Spectra including elastic and Auger peaks reveal an energy resolution of ~4 eV at 900‐eV electron energy. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
998.
Orthogonal array design was used to optimize arsenic speciation in drinking water in contact with materials by dispersive liquid–liquid microextraction followed by graphite furnace atomic absorption spectrometry. Arsenic speciation was achieved by the formation of an arsenic(III) hydrophobic complex with a new chelating agent, 1,2,6-hexanetriol trithioglycolate, at neutral pH. The complex was extracted into the organic phase, while arsenic(V) remained in aqueous solution. The concentration of As(V) was determined by subtracting As(III) from the total arsenic following the reduction of As(V) to As(III) by L-cysteine. Orthogonal array design with OA16 (44) and OA9 (33) matrices was used to optimize the efficiency of dispersive liquid–liquid microextraction and the reduction of As(V) to As(III), respectively. Under the optimal conditions, the detection limit was 0.03?µg?L?1 for As(III) and the relative standard deviation was 5.9% with an enhancement factor of 87. The calibration curve was linear from 0.19 to 3.0?µg?L?1 with a correlation coefficient of 0.9996. The developed method was used for arsenic speciation in solutions of drinking water that contacted materials. The recoveries of fortified samples were in an acceptable range from 92.0 to 113.3%. 相似文献
999.
Carla F. C. Ruschel Marcelo C. A. Marcelo Francisco P. dos Santos Marco F. Ferrão 《Analytical letters》2017,50(11):1767-1777
Automotive fuel adulteration is an old and significant problem. One common type of fuel adulteration is the addition of diesel to gasoline. Unsupervised models were developed through hierarchical cluster and principal component analysis models. Supervised models through partial least square discriminant analysis using 1H nuclear magnetic resonance spectra as the input were used to classify samples as adulterated or unadulterated. Quantitative models were developed using partial least squares to determine the gasoline and diesel concentrations in the samples. This set contained samples composed of pure gasoline and anhydrous ethanol reproducing commercial gasoline and other samples treated with diesel. Hierarchical cluster and principal component analysis did not distinguish between adulterated and unadulterated samples except for the most adulterated materials. However, partial least square discriminant analysis classified 100% of the samples correctly. The partial least square algorithm provided excellent regression models for the gasoline and diesel content. The determination coefficient was 0.9920 for both models, whereas the root mean square error of cross-validation and root mean square error of prediction for the diesel model were 2.32 and 1.42%, respectively, and 2.40 and 1.38% for the gasoline model. 相似文献
1000.
Ecaterina Matei Claudia Drăgan Cristian Pantilimon Cristian Predescu 《Analytical letters》2017,50(17):2822-2838
ABSTRACTTwo nanostructured hybrid materials are reported that include uncoated magnetic nanoiron oxides and magnetic nanoiron oxides treated with rose leaf extract. Atomic and molecular absorption spectrometry were used to evaluate the sensitivity of these materials for the isolation of Cr(VI), Zn(II), Pb(II), and Ca(II) from aqueous solution. The structure and physicochemical properties of the resulting nanohybrids were characterized by scanning electron microscopy coupled with energy-dispersive spectroscopy, atomic force microscopy, and X-ray diffraction. The results show that following 15?min of contact in acidic solution, the uncoated magnetic nanoiron oxides removed approximately 90% of Cr(VI), while the magnetic nanoiron oxides coated with rose leaf extract removed 92% of the analyte. These correspond to most industrial wastewater conditions. For the removal of Ca(II) and Zn(II), it was necessary to adjust the pH to neutral to maximize the efficiency. Pb(II) showed maximum removal efficiency when the solution is basic. The simple rose extract suspension was also used for metal removal with high capacity. The results demonstrate that the magnetic nanoiron oxides were uniformly distributed in the rose leaf extract. The extract served as a capping agent due to the presence of polyphenolics. 相似文献