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11.
为了研究AlGaN量子阱层和垒层中Al组分不同对AlGaN基深紫外发光二极管(LED)光电性能的影响,本文利用MOCVD生长、光刻和干法刻蚀工艺制备了AlGaN量子阱层和垒层具有不同Al组分的270/290/330nm深紫外LED,通过实验和数值模拟计算方法发现,量子阱层和垒层中具有低Al组分紫外LED的AlGaN材料具有较低的位错密度、较高的光输出功率和外量子效率。通过电流-电压(I-V)曲线拟合出的较大的理想因子(3.5)和能带结构图表明,AlGaN深紫外LED的电流产生是隧穿机制占据主导作用,这是因为高Al组分AlGaN量子阱中强极化场造成了有源层区域较大的能带弯曲和电势降。 相似文献
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A picosecond widely tunable deep-ultraviolet laser for angle-resolved photoemission spectroscopy 下载免费PDF全文
We develop a picosecond widely tunable laser in a deep-ultraviolet region from 175 nm to 210 nm,generated by two stages of frequency doubling of a 80-MHz mode-locked picosecond Ti:sapphire laser.A β-BaB2O4 walk-off compensation configuration and a KBe2BO3F2 prism-coupled device are adopted for the generation of second harmonic and fourth harmonics,respectively.The highest power is 3.72 mW at 193 nm,and the fluctuation at 2.85 mW in 130 min is less than ±2%. 相似文献
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We study the linear and nonlinear properties of two-dimensional matter-wave pulses in disk-shaped superfluid Fermi gases.A Kadomtsev-Petviashvili I(KPI) solitary wave has been realized for superfluid Fermi gases in the limited cases of Bardeen-Cooper-Schrieffer(BCS) regime,Bose-Einstein condensate(BEC) regime,and unitarity regime.Onelump solution as well as one-line soliton solutions for the KPI equation are obtained,and two-line soliton solutions with the same amplitude are also studied in the limited cases.The dependence of the lump propagating velocity and the sound speed of two-dimensional superfluid Fermi gases on the interaction parameter are investigated for the limited cases of BEC and unitarity. 相似文献
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Dr. María Francisco M.Sc. Adriaan van den Bruinhorst Prof. Dr. Maaike C. Kroon 《Angewandte Chemie (International ed. in English)》2013,52(11):3074-3085
A new generation of designer solvents emerged in the last decade as promising green media for multiple applications, including separation processes: the low‐transition‐temperature mixtures (LTTMs). They can be prepared by mixing natural high‐melting‐point starting materials, which form a liquid by hydrogen‐bond interactions. Among them, deep‐eutectic solvents (DESs) were presented as promising alternatives to conventional ionic liquids (ILs). Some limitations of ILs are overcome by LTTMs, which are cheap and easy to prepare from natural and readily available starting materials, biodegradable, and renewable. 相似文献
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《Green Chemistry Letters and Reviews》2013,6(4):487-533
Abstract Deep eutectic solvents (DES) and glycerol have been successfully employed as efficient catalysts/reaction media in the synthesis of N-aryl phthalimide derivatives from phthalic anhydride and primary aromatic amines. The DES prepared from choline chloride and malonic acid proved to be an efficient catalyst whereas glycerol and the DES of choline chloride and urea played a dual role of catalyst and solvent. These mixtures are biodegradable, nontoxic, and cost-effective thereby providing a good industrial alternative to conventional methods. These methods gave products in moderate to high yields with good recyclability of catalyst/solvent at least up to five consecutive runs. 相似文献
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Yuntao Dai Jaap van Spronsen Geert-Jan Witkamp Robert Verpoorte Young Hae Choi 《Analytica chimica acta》2013
Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids (ILs) and deep eutectic solvents, thus, have been paid great attention to replace current harsh organic solvents and have been applied to many chemical processing such as extraction and synthesis. However, current ionic liquids and deep eutectic solvents have still limitations to be applied to a real chemical industry due to toxicity against human and environment and high cost of ILs and solid state of most deep eutectic solvents at room temperature. Recently we discovered that many plant abundant primary metabolites changed their state from solid to liquid when they were mixed in proper ratio. This finding made us hypothesize that natural deep eutectic solvents (NADES) play a role as alternative media to water in living organisms and tested a wide range of natural products, which resulted in discovery of over 100 NADES from nature. In order to prove deep eutectic feature the interaction between the molecules was investigated by nuclear magnetic resonance spectroscopy. All the tested NADES show clear hydrogen bonding between components. As next step physical properties of NADES such as water activity, density, viscosity, polarity and thermal properties were measured as well as the effect of water on the physical properties. In the last stage the novel NADES were applied to the solubilization of wide range of biomolecules such as non-water soluble bioactive natural products, gluten, starch, and DNA. In most cases the solubility of the biomolecules evaluated in this study was greatly higher than water. Based on the results the novel NADES may be expected as potential green solvents at room temperature in diverse fields of chemistry. 相似文献
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针对实验方案设计题的得分率分析和教学现状,基于课程标准、教材、真题和文献研究,构建“阿司匹林的制备和提纯”深度学习主题模型。通过设计制备和提纯阿司匹林的实验方案,构建实验方案设计的思维模型,并以制备七水合硫酸锌为例内化思维模型,在解决真实、复杂的问题过程中实现核心知识结构化,生成指向深度学习的主题式复习教学流程。 相似文献