全文获取类型
收费全文 | 2054篇 |
免费 | 524篇 |
国内免费 | 138篇 |
专业分类
化学 | 1033篇 |
晶体学 | 17篇 |
力学 | 50篇 |
综合类 | 21篇 |
数学 | 107篇 |
物理学 | 1488篇 |
出版年
2024年 | 3篇 |
2023年 | 12篇 |
2022年 | 27篇 |
2021年 | 57篇 |
2020年 | 50篇 |
2019年 | 50篇 |
2018年 | 46篇 |
2017年 | 79篇 |
2016年 | 104篇 |
2015年 | 93篇 |
2014年 | 155篇 |
2013年 | 145篇 |
2012年 | 124篇 |
2011年 | 158篇 |
2010年 | 124篇 |
2009年 | 142篇 |
2008年 | 174篇 |
2007年 | 163篇 |
2006年 | 151篇 |
2005年 | 133篇 |
2004年 | 115篇 |
2003年 | 84篇 |
2002年 | 105篇 |
2001年 | 53篇 |
2000年 | 66篇 |
1999年 | 56篇 |
1998年 | 47篇 |
1997年 | 40篇 |
1996年 | 28篇 |
1995年 | 25篇 |
1994年 | 14篇 |
1993年 | 16篇 |
1992年 | 14篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 10篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 7篇 |
1983年 | 1篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有2716条查询结果,搜索用时 31 毫秒
121.
Min‐kyoung Ham Ji HoYouk Yong‐Ku Kwon Young‐Je Kwark 《Journal of polymer science. Part A, Polymer chemistry》2012,50(12):2389-2397
A photoinitiation process was investigated to develop a rapid and well‐controlled RAFT polymerization method applied to vinyl acetate (VAc) using methyl (ethoxycarbonothioyl)sulfanyl acetate (MESA) and bis(2,4,6‐trimethylbenzoyl)phenylphosphine oxide as the RAFT agent and photoinitiator, respectively. MESA was selected as the photochemically inert RAFT agent to minimize photolysis of the thiocarbonylthio groups during polymerization. Poly(vinyl acetate) with a prespecified well‐controlled molecular weight (MW) and a narrow MW distribution was successfully synthesized. The polymerization reaction proceeded as a living polymerization and was remarkably rapid compared with approaches that use thermally initiated processes with a very short induction period. A detailed kinetic study of the mechanism underlying the polymerization reaction, however, revealed that the chain ends containing xanthate moieties were not perfectly stable upon UV‐irradiation, and they generated radicals via homolytic cleavage. This reaction appeared to proceed by a combination of a degenerative transfer RAFT mechanism and a dissociation‐combination mechanism. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
122.
为了实现对基于自由摆的平板的控制,建立了基于自由摆的平板控制系统.首先分析平板的控制转角与自由摆转角的关系,推导出关系式,再对控制单元、反馈单元进行分析比较给出方案,采用32位LPC2138(ARM7)处理器为平板控制系统的中央控制单元,实现由高精度电位器测量出摆动角度后由步进电机控制的平板在周期摆动中做相应反馈调整,然后在现有器件的基础上编制出控制软件,在设备上进行调试,最后对系统的精度进行分析并进行实际测量.测量结果表明激光笔在摆动中照射在靶板上的光斑偏离基准线最大0.89cm,基本满足对平板的控制要求. 相似文献
123.
The exact Wigner function of a parametrically excited quantum oscillator in a phase-sensitive amplifying/attenuating reservoir is found for initial even/odd coherent states. Studying the evolution of negativity of the Wigner function we show the difference between the “initial positivization time” (IPT), which is inversely proportional to the square of the initial size of the superposition, and the “final positivization time” (FPT), which does not depend on this size. Both these times can be made arbitrarily long in maximally squeezed high-temperature reservoirs. Besides, we find the conditions when some (small) squeezing can exist even after the Wigner function becomes totally positive. 相似文献
124.
Higher-order effects on self-similar parabolic pulse in the microstructured fibre amplifier 下载免费PDF全文
By considering higher-order effects, the properties of self-similar parabolic pulses propagating in the microstructured fibre amplifier with a normal group-velocity dispersion have been investigated. The numerical results indicate that the higher-order effects can badly distort self-similar parabolic pulse shape and optical spectrum, and at the same time the peak shift and oscillation appear, while the pulse still reveals highly linear chirp but grows into asymmetry. The influence of different higher-order effects on self-similar parabolic pulse propagation has been analysed. It shows that the self-steepening plays a more important role. We can manipulate the geometrical parameters of the microstructured fibre amplifier to gain a suitable dispersion and nonlinearity coefficient which will keep high-quality self-similar parabolic pulse propagation. These results are significant for the further study of self-similar parabolic pulse propagation. 相似文献
125.
126.
ErS+-doped phosphor-tellurite glass for broadband short-length Er3+-doped fiber amplifier (EDFA) is fabricated and characterized. The differential value (△T) of onset crystalline temperature (Tx) and glass transition temperature (Ts) is 206°C. 相似文献
127.
128.
129.
利用平均反转率迭代算法计算掺镱双包层光纤放大器分布泵浦方式下的稳态速率方程组,并采用遗传算法对分布泵浦功率的大小和每段光纤长度同时进行优化。评估函数中引入了每段光纤中最高温度的标准方差,以确保每段光纤中的最高工作温度是相同的。通过优化,7段泵浦的最高温度和标准方差分别为126.34 ℃和1.95 ℃ ,8段泵浦条件下的最高温度和标准方差分别为119.76 ℃和2.12 ℃。而未经优化的7段泵浦的最高温度和标准方差分别为147.12 ℃和21.37 ℃,8段泵浦条件下的最高温度和标准方差分别为139.95 ℃和20.83 ℃。计算结果表明:泵浦方式的优化降低了最高温度和标准方差,实现了光纤中温度分布的均匀性,并且通过增加泵浦段数可以进一步降低最高温度和平坦温度分布。 相似文献
130.
Under small-signal assumption, equivalent noise figure normalized by fiber nonlinearities (NENF) of bi-directionally pumped distributed fiber Raman amplifiers (BiDFRA) is derived. Amplified spontaneous Raman scattering noise and double Rayleigh scattering noise are both included. The relation between NENF and Raman gain, forward Raman gain percentage is investigated under different polarization factor and Rayleigh scattering coefficient. It agrees well with numerical simulation results. Based on the analytical expression, the optical signal-to-nose ratio (OSNR) improvement of hybrid pre-BiDFRA/erbium-doped fiber amplifier (EDFA) compared with sole EDFA is studied. It is shown that there is an optimum Raman gain and forward Raman gain percentage to maximize the OSNR improvement. Finally, some guidelines on BiDFRA design are proposed. 相似文献