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81.
光子晶体的原理与应用 总被引:1,自引:0,他引:1
光子晶体是一种在微米、亚微米等光波长量级上折射率呈现周期性变化的介质材料,它使某些频率范围内的光子态密度大大降低.甚至完全形成光子禁带.本文介绍了光子晶体的原理、制备及应用. 相似文献
82.
冲击载荷下剪切断裂研究 总被引:1,自引:0,他引:1
利用Hopkinson压杆技术对单边平行双裂纹试样倒向加载,在较大的加载率范围,对Ti6Al4V钛合金和40CrNiMoA两种材料的动态剪切断裂行为进行了研究.实验结果表明:存在两类韧性剪切断裂模式,即常规的韧性剪切型断裂和绝热剪切断裂.常规剪切型断裂模式的断裂韧性KⅡd随加载率的提高而增大,而绝热剪切型的断裂韧性KⅡd则随加载率的提高而减小,并且,当加载率增大至某一临界值时,常规的韧性剪切断裂模式将转变为绝热剪切断裂破坏模式. 相似文献
83.
On the basis of critical comparison of experimental and theoretical values of the E parameter and investigation of the retardation effect of oxygen on the evaporation rate of ZnO, CdO and HgO, it was concluded that the dissociative evaporation of ZnO and HgO proceeds with releasing of atomic oxygen (O) as a primary product of decomposition. By contrast, the mechanism of dissociative evaporation of CdO corresponds to the equilibrium reaction with releasing of molecular oxygen (O2) as a primary product of decomposition. As was shown, this difference in mechanisms is not related with interatomic OO distances in these oxides. From the analysis of crystal structure for 12 different oxides, which evaporate with releasing of atomic oxygen, and for 13 compounds, which evaporate with releasing of molecular oxygen, it was revealed that the first mechanism is observed for all oxides with the cubic crystal structure. It was proposed that a decisive role in this difference belongs to a local symmetry in the position of O atoms. 相似文献
84.
85.
在相对碰撞平动能为 0 .0 5eV的分子束实验条件下 ,研究了亚稳态CO(a) +NO(X)的E E传能通道 .通过测量和分析交碰区的传能发射光谱 ,在 780和 860nm处观测到了NO(b -a)跃迁Ogawa带的△v =+ 4和△v =+ 3序的发射光谱 .从而首次在实验上直接证实了传能过程中第四通道的存在 (CO (a) +NO(X)→CO (X) +NO(b) ) .这一通道的发现解释了前人测量到的在CO(a)与NO(X)碰撞传能过程中CO(a)的猝灭速率远大于NO(A ,B)生成速率的实验结果 ,并进一步证实了这一“经典”E E传能体系为电子交换机理的传能观点 相似文献
86.
T. Tsuneta T. Toshima K. Inagaki T. Shibayama S. Tanda S. Uji M. Ahlskog P. Hakonen M. Paalanen 《Current Applied Physics》2003,3(6):473-476
We succeed in synthesizing NbSe2 nanotubes along with nanofibers by chemical vapor transportation. They are stable crystalline systems and can be synthesized reproducibly in a nearly equilibrium reacting process. We have investigated these nanosize structures of NbSe2 by transmission electron microscopy and electron diffraction. Both of the structures have a similar size of 100–200 nm in diameter. While nanotubes consist of rolled-up NbSe2 layers, nanofibers are a pile of thin flat layers. We propose a mechanism of the formation of NbSe2 nanotubes and nanofibers on the basis of deseleniditive transition from a NbSe3 fiber-shaped crystal. We also measured electrical resistance of the nanofibers with conductive atomic force microscopy and demonstrated that the material show metallic behavior at room temperature. 相似文献
87.
Chongyi Wan Shiming Liu Rongqing Tan Jin Wu Jinwen Zhou Yan Lv Yanning Yu Hua Yang 《Optics & Laser Technology》2004,36(8):2389-649
A high average power, high-repetition-rate TEA CO2 laser employing printed-circuit-board preionizer is described. The power scaling of this preionization configuration has been demonstrated. The average output power reaches 3.6 kW at pulse repetition rate of 180 pps. Furthermore, the scaling-up ability of the rotating spark gap as high-voltage switch for high-average-power gas laser has been validated. 相似文献
88.
掺Perylene的PVK薄膜荧光谱及发光机理 总被引:1,自引:1,他引:0
用高荧光效率的有机染料芘(perylene)掺杂聚乙烯咔唑(PVK),其荧光光谱与芘的发射光谱基本一致,而且亮度比纯芘发光提高十多倍,说明发光主要来自芘分子,并在PVK和perylene之间存在十分有效的能量传递或电荷转移过程,荧光谱强度随掺杂浓度的变化关系说明存在一个最佳的掺杂浓度比.分析PVK和perylene之间可能发生的能量转移过程,认为从PVK到perylene这种能量转移与实验不符;分析PVK和perylene薄膜的光致发光过程,认为从(PVK+)→(perylene+)和从(PVK-)→(p 相似文献
89.
U.Deva Priyakumar 《Tetrahedron letters》2004,45(12):2495-2498
A novel preference for planar tetracoordination was observed over the conventional tetrahedral arrangement in a new series of C5H2, C5H4, C5H41+/2+ and related compounds. The stability of these molecules is assessed with the ring-opening barriers, HOMO-LUMO gap, singlet-triplet energy differences and nucleus independent chemical shift values. 相似文献
90.
V. B. Kobychev N. M. Vitkovskaya I. L. Zaitseva B. A. Trofimov 《Journal of Structural Chemistry》2004,45(6):940-944
The profiles of reactions leading to pyrrole anion N-adducts with CO2 and CS2 have been studied by the ab initio (RHF/6-31+G*, MP2/6-31+G*) and density functional (B3LYP/6-31+G*) methods. Addition of the pyrrole anion to the carbon disulfide molecule is accompanied by the appearance of a minimum corresponding to a pre-reaction complex. The transformation of the complex to the N-pyrrolyldithiocarboxylate anion occurs via a low activation barrier, which is due to repolarization of the C=S bonds. The profile of the reaction leading to the pyrrole anion N-adduct with CO2 does not contain any intermediate stationary points throughout the whole route from reagents to products.Original Russian Text Copyright © 2004 by V. B. Kobychev, N. M. Vitkovskaya, I. L. Zaitseva, and B. A. Trofimov__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 6, pp. 990–993, November–December, 2004. 相似文献