石墨薄片弯曲度的高分辨率电子显微镜研究

报道了一种用高序石墨在乙醇、水或乙醇 水混合溶液中超声波处理产生的碳样品．高分辨率电子显微镜揭示出大量具有总角度为θ₀（±30℃）倍数的弯曲石墨片存在．显微镜检查表明，弯曲是通过原子晶格平面的偏转而成的．基于石墨的对称轴结构和在sp²石墨网络中类-sp³线缺陷的形成，讨论了石墨片弯曲的可能解释. 关键词：     

18 MeV质子辐照对TiNi形状记忆合金R相变的影响

 研究了用HZ-B串列加速器的18MeV质子辐照对TiNi形状记忆合金R相变的影响，辐照在奥氏体母相状态下进行。示差扫描量热法（DSC）表明，辐照后R相变开始温度T^s_R和逆马氏体相变结束温度T^f_A随辐照注量的增加而降低。当注量为1.53×10¹⁴/cm²时，T^sR和T^f_A分别下降6K和13K，辐照未引起R相变结束温度T^s_R和逆马氏体相变开始温度T^f_A的变化。表明辐照后母相(奥氏体相)稳定。透射电镜（TEM）分析表明辐照后没有引起合金可观察的微观组织变化。辐照对R相变开始温度T^s_{R和逆马氏体相变结束温度Af的影响可能是由于质子辐照后产生了孤立的缺陷团，形成了局部应力场，引起晶格有序度的下降所造成的。}     

一平板带有圆柱形凸起的未屏蔽平板线中的TEM波及其传输特性

利用保角变换,给出一平板带有圆柱形凸起疤的未屏蔽平板线内TEM波的分布规律,绘制其横截面上的场结构图,给出平板间场强与圆柱形截面在原点处的切线与x轴正向的夹角α的变化关系及数据,得到该传输线的最大传输功率将因平板上圆柱形凸起的出现而减小的结论.     

控制沉淀法制备不同形貌的碳酸钙超细粉

本文报道了一种成功合成了不同形貌的碳酸钙（CaCO3）超细粉的简单方法,可以获得包括链状、片状、棒状、球形、斜方、以及中空球形的超细碳酸钙粉末。产品用粉末X射线衍射（XRD）、扫描电镜（SEM）、透射电镜（TEM）进行了表征和检测。文中对影响产品具晶型和形貌的主要因素进行了讨论,以期有助于理解碳酸钙超细粉的成核与生长机理。     

Synthesis,Spectroscopic Characterization,Thermogravimetric and Biological Activity Evaluation of Te(Ⅳ),Se(Ⅳ),V(Ⅲ),Nb(Ⅴ),Ta(Ⅴ)Complexes With Indole-3-Acetic Acid Plant Hormone Ligand

Te(Ⅳ), Se(Ⅳ), V(Ⅲ), Nb(Ⅴ) and Ta(Ⅴ) complexes of indole-3-acetic acid (IAAH) ligand were synthesized, characterized by elemental analysis and various spectroscopic techniques like, IR, 1H-NMR, X-ray powder diffraction, UV-Visible, thermogravimetry analysis, magnetic measurements, molar conductance and surface morphology using SEM. All the synthesized complexes of IAAH ligand have 1∶2 stoichiometry of the types [Te(IAA)₂(NH₃)₂]·2Cl (Ⅰ), [Se(IAA)₂(NH₃)₂]·2Cl (Ⅱ), [V(IAA)₂(NH₃)(Cl)] (Ⅲ), [Nb(IAA)₂(Cl)₃] (Ⅳ), and [Ta(IAA)₂(Cl)₃] (Ⅴ). Spectral analysis indicates octahedral geometry for the Te(Ⅳ), Se(Ⅳ) and V(Ⅲ) complexes, whereas both Nb(Ⅴ) and Ta(Ⅴ) have a seven-coordination. The bonding sites are the oxygen atoms of carboxylate group for the deprotonated indole-3-acetic acid (IAA) ligand. The thermogravimetry analysis studies gave evidence for the presence of other coordinated molecules (Cl or NH₃) in the composition of IAA complexes, which were further supported by IR and micro analytical measurements. The higher molar conductance data of tellurium and selenium (Ⅳ) complexes reveal that these chelates are electrolytes, while low conductivity values for the vanadium(Ⅲ), niobium and tantalum(Ⅴ) chelates indicated a non-electrolytes. To test the antibacterial property of the five complexes in this study, four bacterial strains Klebsiella (G-), Escherichia coli (G-), Staphylococcus aureus (G+) and Staphylococcus epidermidis (G+) were used in the investigation. The effects of the five complexes in the cytotoxicity of Caco-2 and Mcf-7 human cancer cell lines were studied Neutral red uptake assay for the estimation of cell viability/cytotoxicity protocol.     

DESIGN AND CONTROL OF SOAP-FREE HYDROPHILIC-HYDROPHOBIC CORE-SHELL LATEX PARTICLES WITH HIGH CARBOXYL CONTENT IN THE CORE OF THE PARTICLES

Soap-free hydrophilic-hydrophobic core-shell latex particles with high carboxyl content in the core of the particles were synthesized via the seeded emulsion polymerization using methyl methacrylate(MMA),butyl acrylate(BA), methacrylic acid(MAA),styrene(St)and ethylene glycol dimethacrylate(EGDMA)as monomers,and the influences of MMA content used in the core preparation on polymerization,particle size and morphology were investigated by transmission electron microscopy,dynamic light scattering and conductometric titration.The results showed that the seeded emulsion polymerization could be carried out smoothly using "starved monomer feeding process" when MAA content in the core preparation was equal to or less than 24 wt%,and the encapsulating efficiency of the hydrophilic P(MMA-BA-MAAEGDMA) core with the hydrophobic PSt shell decreased with the increase in MAA content.When an interlayer of P(MMAMAA -St)with moderate polarity was inserted between the P(MMA-BA-MAA-EGDMA)core and the PSt shell,well designed soap-free hydrophilic-hydrophobic core-shell latex particles with 24 wt%MAA content in the core preparation were obtained.     

辐射式核电磁脉冲模拟器TEM喇叭天线

针对辐射式核电磁脉冲模拟器采用TEM喇叭天线作为辐射天线时低频辐射能力有限的问题,对板型和线型两种基本形式的TEM喇叭天线进行了分析。在采用线型TEM喇叭天线以减轻模拟器重量的基础上,在天线末端采用螺旋线结构,并增加屏蔽板回路,构造了一种新型TEM喇叭天线。结果表明:与普通线型TEM喇叭天线相比,该新型天线较大地提高了低频辐射性能,可使近场波形脉宽提高7ns左右,峰值场强提高了1kV/m左右;通过增大螺旋线半径和提高螺旋线密度可以提高峰值场强,增加近场波形脉宽;通过屏蔽板回路可以降低反射波纹的波峰从而改善近场波形。     

Transverse mode transition and LG01-mode generation in an end-pumped Nd：YV04 laser

A laser-diode end-pumped Nd：YVO4 crystal laser is demonstrated to emit the first-order Laguerre- Gaussian （LGm） mode with 502-mW laser power and 22% slope efficiency. Tile LGm-mode is lased only when the pumping area locates in the central part of the laser crystal＇s front surface, and thereafter the symmetrical LGm-HGol-TEM00 mode transition happens when laser crystal is moved laterally inside several-tens-micron area. The possible mechanism responsible for the phenomenon of symmetrical mode transition is also discussed.     

TEM喇叭天线辐射机理分析和优化设计

在频域和时域研究了TEM喇叭天线的辐射机理。在频域,高频信号激励的TEM喇叭表现为口径天线的辐射特性,具有良好的方向性;低频信号激励的TEM喇叭可视作偶极子天线,具有全向辐射特性;在时域,脉冲激励的TEM喇叭天线辐射场由四个子波叠加构成,在不同方向上,各个子波的波形和相对时序不同,导致不同方向上辐射场波形也不相同。根据辐射机理研究结果,提出了一种TEM喇叭天线末端加载设计并给出了其优化设计方法,有效地改善了天线主轴辐射性能,提高了辐射因子和天线效率。     

在非影像区沉积铜的研究

本文用透过射电子显微镜和Ｘ射线光电子能谱仪对非影像区沉和积铜的机理进行了研究。结果表明在影像区的银丝经过氯金酸溶液处理后，由原来的连续缠绕状变为细小颗粒，非影像区的明胶能将Ａｕ＾３＾＋还原。还原过程是一个两步反应。第一步生成Ａｕ＾＋，这一步在室温下为快反应。明胶对Ａｕ＾＋有较高的络合能力；第二步生成金质点，在Ｘ射线作用下，Ａｕ＾＋能迅速地被还原为金质点。被络合的Ａｕ＾＋和部分被还原的金质点作为物理