Microwave-Assisted Synthesis and Characterization of Polyurethanes from TDI and Starch

In this work, a microwave-assisted method was developed to prepare polyurethanes from starch or maltodextrin and tolylene-2,4-diisocyanate (TDI). As compared to conventional heating, this new synthetic procedure saves energy, significantly reduces reaction time, and yet entails product yields that are comparable to those of the conventional heating procedure. The reaction products were characterized with NMR, FT-IR, thermogravimetric analysis, and scanning electron microscopy. From these analyses, the polyurethanes made with the conventional and microwave methods are shown to be similar in chemical structure and physical morphology. Furthermore, the ¹H and ¹³C NMR spectra of the starch polyurethanes have been fully assigned for the first time.     

Functional Monomers and Polymers. LX. Effects of Counterions on the Structure of Cu(II)-Polyvinylimidazole and Cu(II)lmidazole Complexes in Aqueous Solution

The effect of counterion types on the structure of Cu(II) complexes of imidazole and poly-4(5)-vinylimidazole in aqueous solution was studied by spectroscopic and electron spin resonance (ESR) techniques. Visible and ESR spectra of both complexes in aqueous solution containing NaClO₄, KNO₃, KC1, and KBr showed only a slight change from each other in the presence of different counterions. On the other hand, the frequency of the center of absorption band in the visible region (λ_max) and ESR parameters of the complex in aqueous solution did not correspond to those reported for its crystalline state, and in addition, those of the polymeric Cu(II) complex were different from those of the low molecular weight Cu(II) complex. It was proposed that in aqueous solution, water molecules are coordinated to the axial position of the complex where counterion molecules are present in the crystalline state, and that the structure of the polymeric Cu(II) complex is different from that of the low molecular weight Cu(II) complex due to steric hindrance of the polymeric ligand.     

基于线阵TDI-CCD器件的扫描成像系统设计

提出了由步进电机控制振镜运转,基于线阵TDI-CCD相机的扫描成像设计方案.通过研究线阵TDI-CCD器件的结构与工作原理,得到对振镜扫描速率和相机行扫描速率进行同步的方法,实现了空间位置配准.采用EC-11相机进行成像实验,扫描成像系统输出了可辨别的图像.     

IR研究聚氨酯预聚反应的活化能

在滴定分析判断聚乙二醇（ＰＥＧ）和２，４－二甲苯二异氰酸酯（ＴＤＩ）预聚反应为一级反应的基础上，用ＩＲ分析ＰＥＧ和ＴＤＩ预聚反应过程中ＮＣＯ基的定量变化，结合Ａｒｒｈｅｎｉｕｓ经验式得ＰＥＧ入ＴＤＩ预聚反应的表观活性能Ｅα＝８６．９ｋＪｍｏ６－２，为研究其预聚反应的历程奠定基础。     

肝素杂化材料的制备及抗凝血性质的初步研究

以甲苯二异氰酸酯(TDI)中的-NCO基与纳米金属氧化物表面的羟基发生反应,得到改性纳米金属氧化物,并使其与肝素钠(Heparin)进行接枝反应生成肝素杂化材料,结合红外、热重、扫描电镜(SEM)等表征方法,确定纳米金属氧化物确实接枝到了肝素钠的表面。通过对体外凝血时间和复钙时间的测定,来初步研究肝素杂化材料的抗凝血性质。结果表明：肝素杂化材料的抗凝血时间和复钙时间均比肝素钠的要短,表明它的抗凝血性比肝素钠的抗凝血性要弱一些;但比纳米金属氧化物和空白组的抗凝血时间和复钙时间要长,说明肝素杂化材料的抗凝血性与其相比则有明显的提高。     

Kőnig’s edge-colouring theorem for all graphs

We show that the maximum degree of a graph G$G$ is equal to the minimum number of ocm sets covering  G$G$, where an ocm set is the vertex-disjoint union of elementary odd cycles and one matching, and a collection of ocm sets covers   G$G$ if every edge is in the matching of an ocm set or in some odd cycle of at least two ocm sets.     

高速多光谱 TDI CCD 成像电路系统

为实现多光谱TDI CCD的高速高信噪比成像,利用可空间应用的多光谱TDI CCD传感器研制出了高性能成像电路系统。该系统以现场可编程门阵列（ FPGA）为核心逻辑单元,带有RS422外围通信控制接口,并采用CAMERALINK接口输出图像数据。系统具有动态推扫成像的能力,可同时输出全色和彩色两种模式的图像数据。利用灰度条纹的靶标对传感器的3个多光谱（ R、G、B）感光区标定白平衡,利用彩色条纹的靶标对系统进行成像测试,在驱动频率为15 MHz的情况下,系统单片CCD输出的图像数据率达到1.2 Gbps。试验结果表明,获取全色图像的信噪比达到了53.56 dB,各多光谱图像的信噪比较高的也在40 dB以上,满足空间对地高分辨多光谱遥感成像的技术指标要求,对高速空间多光谱遥感相机的研制具有借鉴意义。     

TDICCD亚像元技术应用于小相对孔径光学系统

TDI CCD器件和亚像元成像技术都是实现相机小型化的有效途经,TDI CCD器件和亚像元成像技术结合应用于小相对孔径光学系统具有重要的应用价值.就成像系统需要满足Nyquist频率处静态传函≥0.2条件对系统进行了分析、讨论,并就设计中引入信噪比指标提出了一点建议.     

基于TDI-CCD的高速小目标交汇测量系统

介绍了TDI CCD图像传感器的工作原理和成像特点 ,提出了基于TDI CCD的交汇测量系统 ,初步分析了该交汇系统行扫描速率和目标运动速率的同步控制问题。同一般线阵CCD组成的交汇测量系统相比较 ,TDI CCD构成的交汇测量系统能够提高探测灵敏度、扩大动态探测范围、增大信噪比 ,从而大大提高系统对目标的捕获几率。同时亦可减小照明光源的亮度及功耗。对大靶面、高速小目标物体运动轨迹的精密测量具有重要意义。     

航天TDI-CCD相机的MTF和像质分析

TDI- CCD相机在航天遥感中得到了越来越广泛的应用 ,但航天 TDI- CCD相机的像移是难以完全消除的或是不可避免的。推导和分析了 TDI- CCD相机的像移以及各种像移的 MTF表达式 ;参照美国国家图像解释分级标准( NIIRS) ,分析了像移量对像质的影响。结果表明 :当采用 96级延迟积分的 TDI- CCD器件时 ,同步误差只有小于 2 % ,成像质量才能得到保证 ,这与滚筒式扫描成像实验结果相吻合