原子转移自由基聚合法制备超大孔聚合物微球

以甲基丙烯酸缩水甘油酯为单体(GMA)、乙二醇二甲基丙烯酸酯(EDMA)为交联剂,采用原子转移自由基聚合法(ATRP)制备了PGMA-EDMA大孔聚合物微球,采用傅里叶变换红外光谱、扫描电子显微镜及压汞法对PGMA-EDMA微球进行了表征.研究结果表明,原子转移自由基聚合法制备的PGMA-EDMA微球的孔径尺寸及比表面积均大于普通自由基聚合法(CFRP)制备的PGMA-EDMA;ATRP法制备的PGMAEDMA微球的颗粒尺寸(100~400 nm)明显小于CFRP法制备的PGMA-EDMA微球的颗粒尺寸(1000 nm).PGMA-EDMA(ATRP)的微球粒径尺寸分布优于PGMA-EDMA(CFRP).因此PGMA-EDMA(APRP)微球在快速蛋白分离纯化方面有潜在的应用前景.     

Discrete weighted Hardy inequalities with different kinds of boundary conditions

This paper studies the weighted Hardy inequalities on the discrete intervals with four different kinds of boundary conditions. The main result is the uniform expression of the basic estimate of the optimal constant with the corresponding boundary condition. Firstly, one-side boundary condition is considered, which means that the sequences vanish at the right endpoint (ND-case). Based on the dual method, it can be translated into the case vanishing at left endpoint (DN-case). Secondly, the condition is the case that the sequences vanish at two endpoints (DD-case). The third type of condition is the generality of the mean zero condition (NN-case), which is motivated from probability theory. To deal with the second and the third kinds of inequalities, the splitting technique is presented. Finally, as typical applications, some examples are included.     

Absorption of sound at a surface exposed to flow and temperature gradients

In noise abatement using porous or fibrous materials, accurate determination of the surface impedance representing the absorber is decisive for simulation quality. The presence of grazing flow and non-homogeneous ambient temperature influence the reaction of the absorber and may suitably be included in a modified “effective” surface impedance. In this paper, this approach is applied to a generic case representative for the engine bay of a heavy truck, where porous shields suppress the radiated noise, e.g. during a pass-by noise test. The change in the absorption is determined numerically by solving the wave propagation through a layer of varying temperature and flow adjacent to the impedance surface for different angles of incidence. The study shows significant impact of both flow and temperature, especially for materials with low absorption. The diffuse field absorption coefficient is also derived and although the effect is less pronounced in this case, it is still important in lower frequencies and in the frequency range typical for IC engine noise. The proposed numerical method is shown to be accurate and efficient for determination of the effective impedance and moreover not limited to thin boundary layers.     

胡椒碱的提取、纯化及其抗癌活性的研究

本文利用溶剂法提取胡椒果中的胡椒碱成分,通过重结晶法纯化活性胡椒碱,并对其纯度和抗癌活性进行表征。结果表明,经分离纯化得到的胡椒碱纯度高达99.94%,并具有良好的抗癌效果。此外,运用密度泛函理论中B3LYP方法对胡椒碱的几何结构、相对能、热力学分布进行优化计算,建立和分析了胡椒碱的理论模型。所建立的能量最低的稳定胡椒碱理论模型符合热力学分布结果。     

分子印迹固相萃取联用高效液相色谱分离测定海水中的膝沟藻毒素GTX1,4

采用分子印迹技术,以鸟嘌呤核苷为虚拟模板,本体聚合,合成GTX1,4的分子印迹聚合物(MIP).傅里叶红外变换光谱(FT-IR)和扫描电子显微镜(SEM)的结果显示,MIP具有分布均匀、大小均一的孔穴.平衡吸附实验表明,分子印迹聚合物(MIP)比非分子印迹聚合物(NIP)具有更高的结合容量,对膝沟藻毒素GTXI,4有更好的选择性.用MIP填充固相萃取小柱(MISPE),以0.1 mol/L乙酸溶液为淋洗液,甲醇-水(95∶5,V/V)溶液为洗脱液时回收率最高,达到85.0％.用优化后的淋洗洗脱条件测定微小亚历山大藻和塔玛亚历山大藻藻液中的GTX1,4,分别为1.10和0.99 μg/L,RSD分别为3.3％和4.4％,说明本方法具有较好的检测限和较高的测定精密度.     

FPSO船与低充水率下LNG液舱晃荡耦合运动的数值模拟

应用数值模拟方法对FPSO船舶运动与LNG液舱晃荡耦合问题进行了研究.这种全耦合问题的研究基于开源平台OpenFOAM开发的船舶与海洋工程水动力CFD求解器——naoe-FOAM-SJ-TU进行计算.液舱内部流场与外部流场同时求解.采用带有两个LNG液舱的FPSO船作为对象进行数值模拟,船舶放开3个自由度运动,并在90°浪向的规则波中进行模拟.液舱充水率为20％～20％,低于船外自由水面高度.这种低充水率的液舱会大大减少船舶的横摇运动,并且舱内的流体情况较为复杂.考虑了4种不同的入射波频率下船舶的运动,与实验结果进行了对比.数值模拟结果与实验结果对比吻合良好,验证了数值求解方法的可靠性.还对大波高情况下带有低充水率LNG液舱的船舶运动进行了数值模拟分析.在船舶运动与液舱晃荡全耦合情况下,观察到了液舱内流体的剧烈晃荡和舱壁的脉冲压力.     

Separation performance of polydopamine-based cucurbit[7]uril stationary phase for capillary gas chromatography

Polydopamine(PDA) coating, a nature-inspired polymer, has attracted great attention in many areas due to its high adhesion strength and stability on almost all types of substrate surfaces. This work presents the first example of using PDA coating as a column pretreatment method in capillary gas chromatography(GC) and its employment in the column fabrication of cucurbit[7]uril(CB7) stationary phase. The fabricated PDA-CB7 column exhibited weakly polar nature and had advantages over CB7 column without PDA for the separations of some critical analytes in GC. This work demonstrates the advantage and potential of using PDA as a facile column pretreatment method in capillary GC column fabrication.     

Optimality conditions for nonsmooth mathematical programs with equilibrium constraints,using convexificators

In this paper, we deal with constraint qualifications, stationary concepts and optimality conditions for a nonsmooth mathematical program with equilibrium constraints (MPEC). The main tool in our study is the notion of convexificator. Using this notion, standard and MPEC Abadie and several other constraint qualifications are proposed and a comparison between them is presented. We also define nonsmooth stationary conditions based on the convexificators. In particular, we show that GS-stationary is the first-order optimality condition under generalized standard Abadie constraint qualification. Finally, sufficient conditions for global or local optimality are derived under some MPEC generalized convexity assumptions.     

A new nonlinear scalarization function and applications

In this paper, a new nonlinear scalarization function, which is a generalization of the oriented distance function, is introduced. Some properties of the function are discussed. Then the function is applied to obtain some new optimality conditions and scalar representations for set-valued vector optimization problems with set optimization criteria. In terms of the function and the image space analysis, some new alternative results for generalized parametric systems are derived.     

Characterizing optimal wages in principal-agent problems without using the first-order approach

The analysis of the principal-agent problem usually requires the classical first-order approach (FOA). However, the validity of the FOA makes restrictive assumptions on the problem under consideration such as the convexity of the distribution function condition. The main aim of this paper is to compute the optimal wages and characterize a closed form solution to the risk-neutral principal-agent problem with limited liability constraints. The development in this paper mainly invokes certain techniques in the semi-infinite programming rather than the FOA.