CRAFT TF中场线圈导体及内部接头电阻-温度特性研究

我国于2019年启动了国家大科学装置聚变堆主机关键系统综合研究设施(CRAFT)的建设,环向场(Toroidal Field, TF)线圈是聚变堆主机关键系统综合研究设施的重要组成部分.TF线圈绝缘制造采用真空压力浸渍工艺实现,因TF线圈体量巨大,为使线圈绝缘固化时温度均匀,减少绝缘树脂固化热应力,拟采用导体电流加热的方式进行加热.TF中场线圈有三个内部接头,因此需要同时知道导体和内部接头电阻与温度之间的关系,以防内部接头局部过热,导致绝缘固化失败.本文将中场内部接头样件加热到线圈绝缘工艺温度,用直流四线法测量导体和内部接头在不同温度下的电阻,得到在303～443 K温度区间内导体和内部接头电阻-温度关系式.发现相同温度下,导体电阻大于内部接头电阻,同时分析了内部接头铜套以及铬层对电阻的影响.并根据测得的电阻-温度关系式,可以得到在不同温度下超导缆及内部接头产生焦耳热的能力,从而为超导线圈绝缘固化温度控制提供重要的参考依据.     

天然气和二氧化碳转化制合成气的研究：Ⅲ.催化剂抗积炭性能

天然气和二氧化碳转化制合成气的研究Ⅲ．催化剂抗积炭性能史克英，徐恒泳，商永臣，范业梅，徐国林（哈尔滨师范大学化学系，哈尔滨１５００８０）关键词天然气二氧化碳转化，合成气，催化剂，抗积炭性能．在第十届国际催化会议上，催化专家提出了甲烷二氧化碳转化制合成...     

聚甲基乙烯基硅氧烷/炭黑复合体系的电阻弛豫行为

考察了聚甲基乙烯基硅氧烷/炭黑(CB)复合交联体系在恒定压应力作用下以及完全卸载后的导电行为,发现电阻在恒定压应力作用下及完全卸载后均随时间非线性下降,呈现典型的电阻弛豫行为.根据电阻弛豫时间以及最大电阻弛豫幅度,分析了导电网络结构变化与电阻弛豫之间的关联,讨论了炭黑含量对电阻弛豫的影响.结果表明,在恒定压应力2~4MPa下,电阻弛豫具有两个与CB含量无关的弛豫时间,对应不同尺寸导电网络的结构变化.完全卸载后,基体形变回复造成导电网络发生结构弛豫,弛豫时间随CB含量增大而延长.     

Status of cross-flow membrane emulsification and outlook for industrial application

Cross-flow membrane emulsification has great potential to produce monodisperse emulsions and emulsions with shear sensitive components. However, until now, only low disperse phase fluxes were obtained. A low flux may be a limiting factor for emulsion production on a commercial scale. Therefore, the effects of membrane parameters on the disperse phase flux are estimated. Besides, the effects of these parameters on the droplet size and droplet size distribution are qualitatively described. Wetting properties, pore size and porosity mainly determine the droplet size (distribution). Membrane morphology largely determines the disperse phase flux. As an example, industrial-scale production of culinary cream was chosen to evaluate the required membrane area of different types of membranes: an SPG membrane, an -Al₂O₃ membrane and a microsieve. Due to the totally different morphologies of these membranes, the fraction of active pores is 1 for a microsieve and is very low for the other membranes. The choice of the optimal membrane did not depend on the production strategy: either to produce large quantities or to produce monodisperse emulsions, the best suitable was a microsieve with an area requirement of around 1 m². In general, the total membrane resistance should be low to obtain a large disperse phase flux. In contrast, the membrane resistance should be high to obtain monodisperse emulsions when using membranes with a high porosity.     

The Power of Kinetic Inertness in Improving Platinum Anticancer Therapy by Circumventing Resistance and Ameliorating Nephrotoxicity

Even in the modern era of precision medicine and immunotherapy, chemotherapy with platinum (Pt) drugs remains among the most commonly prescribed medications against a variety of cancers. Unfortunately, the broad applicability of these blockbuster Pt drugs is severely limited by intrinsic and/or acquired resistance, and high systemic toxicity. Considering the strong interconnection between kinetic lability and undesired shortcomings of clinical Pt drugs, we rationally designed kinetically inert organometallic Pt based anticancer agents with a novel mechanism of action. Using a combination of in vitro and in vivo assays, we demonstrated that the development of a remarkably efficacious but kinetically inert Pt anticancer agent is feasible. Along with exerting promising antitumor efficacy in Pt-sensitive as well as Pt-resistant tumors in vivo, our best candidate has the ability to mitigate the nephrotoxicity issue associated with cisplatin. In addition to demonstrating, for the first time, the power of kinetic inertness in improving the therapeutic benefits of Pt based anticancer therapy, we describe the detailed mechanism of action of our best kinetically inert antitumor agent. This study will certainly pave the way for designing the next generation of anticancer drugs for effective treatment of various cancers.     

La2O3对沼气重整制氢催化剂Ni/γ-Al2O3的影响

用浸渍法制备了不同La2O3含量的Ni/La2O3/γ-Al2O3催化剂, 用CH4/CO2体积比为1的混合气体模拟沼气, 考察了La2O3对沼气重整制氢催化剂Ni/γ-Al2O3的结构及催化性能的影响. 运用XRD、H2-TPR、BET及TEM等手段对催化剂进行了表征. 结果表明, La2O3对催化剂Ni/γ-Al2O3的影响主要取决于其含量. 载体中La2O3的添加增强了Ni与Al2O3之间的相互作用. 添加适量的La2O3能使催化剂具有更好的可还原性, 并能增加金属Ni的分散性, 抑制反应过程中Ni的烧结, 提高载体对CO2的吸附能力, 从而改善了催化剂的抗积炭性, 使催化剂具有较好的活性及稳定性. 反之, 过量La2O3的掺杂会使催化剂的抗积炭性及活性下降. 当La2O3含量为6%(w)时, 催化剂中Ni晶粒具有较好的分散性、还原性及抗积炭性, 从而使催化剂具有更好的活性及稳定性.     

岩石块体滑动的界面摩擦阻抗时效研究

基于岩石块体摩擦滑动试验反映的特征规律 ,本文分析了岩块随时间滑动的界面阻抗机理 ,并建立粘滑位移弱化时反映滑动界面阻抗时间效应的模型公式阻抗松弛模型。     

Hexacyanoferrate as the Electrochemical Probe for 2-Mercaptobenzothiazole Modified Gold Electrode

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｒａｔｅｏｆｅｌｅｃｔｒｏｎｔｒａｎｓｆｅｒｉｓｍｕｃｈａｆｅｃｔｅｄｂｙｓｅｖｅｒａｌｆａｃｔｏｒｓ，ｓｕｃｈａｓｅｌｅｃｔｒｏｄｅｍａｔｅｒｉａｌ，ｅｌｅｃｔｒｏｄｅｆａｂｒｉｃａｔｉｏｎｔｅｃｈｎｉｑｕｅｓ，ｐｏｌ...     

智能温控表的设计

介绍了一种智能温控表的设计方法、系统构成和软件设计;该智能温控表以STC12C5A60S2单片机为核心,采用高精度PT1000铂电阻作为温度传感器,通过内置的10位A/D转换器采集到电压信号,实现对当前的环境温度采集,将目标温度值与实际温度值经过增量式PID运算得出相应控制量数据,可使得控制的温度稳定在与目标温度误差2℃以内,控制精确高,可靠性好;另外该智能温控表还具有通用性强,可方便连接控制多种加热设备、便于检测和修改的模块化编程、参数可调和使用灵活等优点。     

Force and flow characteristics of an intruder immersed in 3D dense granular matter

The motion of a projectile impact onto a granular target results in both the resistance force exerted on the projectile and rheology of granular media. A horizontal arrangement of cylinder quasistatically and dynamically intruding into granular media under different velocities and angles is simulated using discrete element method. Three distinguished drag force regimes are exhibited, including hydrostatic-like force independent of velocity, viscous force related to velocity, and inertial drag force proportional to the square of velocity. Meanwhile, the influence of penetration angles on drag force is examined for these three regimes, and a force model, which is related to penetration depth and angle, is proposed for quasi-static penetration. Then, flow characteristics of the granular media, such as velocity field, pressure field, packing fraction etc., are traced, and a rheology model of packing fraction and inertial number is established.