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51.
This paper presents results of studies on dc electrical conductivity and transference number measurements on potassium bromate
(KBrO3) complexed polyvinyl chloride (PVC) films prepared by solution cast technique. Temperature dependence of dc electrical conductivity
and transference number data indicated the dominance of ion type charge transport in these specimens. The magnitude of conductivity
increased with increase in concentration of the salt and temperature. Using this (PVC + KBrO3) electrolyte, solid-state electrochemical cells were fabricated, and their discharge profiles were studied under a constant
load of 100 kΩ. Several cell profiles such as open circuit voltage, short circuit current, power density, and energy density
associated with these cells were evaluated and were reported. The features of complexation of the electrolytes were studied
by X-ray diffraction and Fourier transform infrared spectroscopy.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006 相似文献
52.
E. J. Prime J. Lassen T. Achtzehn D. Albers P. Bricault T. Cocolios M. Dombsky F. Labrecque J. P. Lavoie M. R. Pearson T. Stubbe N. Lecesne Ch. Geppert K. D. A. Wendt 《Hyperfine Interactions》2006,171(1-3):127-134
The range of isotopes available at the TRIUMF Isotope Separator Accelerator (ISAC) facility has been greatly enhanced by adding
a Resonance Ionization Laser Ion Source (RILIS). A large wavelength range is accessible with the fundamental, second and third
harmonic generation of titanium-sapphire laser light. In addition a dedicated laser is available for non-resonant laser ionization.
The first on-line beam 62Ga was delivered in Dec. 2004. In general RILIS improves the intensity, purity and emittance of ion beams. 62Ga and 26Al and Be beams have been delivered so far on-line.
This work was financed by TRIUMF which is federally funded via a contribution agreement through the National Research Council
of Canada. 相似文献
53.
The Li oxides species formed on Li over-deposited V2O5 thin film surfaces have been studied by using X-ray and UV induced photoelectron spectroscopy (XPS and UPS). The photoelectron spectroscopic data show that the Li over-deposited V2O5 system itself is not stable. Further chemical decomposition reactions are taken place even under UHV conditions and lead to form Li2O and Li2O2 compounds on the surface. The formation of Li2O2 causes to arise an emission line at about 11.3 eV in the valence band spectra. 相似文献
54.
M. Battabyal 《Journal of Physics and Chemistry of Solids》2004,65(11):1895-1900
Thermal conductivity (λ) of nanocrystalline La1−xAgxMnO3 (x=0.05, 0.15, 0.25, 0.3) pellets prepared by pyrophoric method is reported between 10 and 300 K. Magnitude of thermal conductivity has been found to be strongly influenced by monovalent (Ag) substitution at the La site. Silver doping in LaMnO3 enhances TC of the system to ∼299 K. Qualitative nature of the temperature variation of thermal conductivity of the silver substituted lanthanum manganites remains closely similar to that for divalent doped systems. Our analysis demonstrates that in La1−xAgxMnO3 also, the mechanism of heat conduction is predominantly by phonons. The contribution of the electronic part is only ∼1% of the total λ. The spin wave contribution is also estimated close to TC, which for all the samples lies within ∼2%. At temperatures below ∼100 K, the measured data have been analyzed using phonon relaxation time method and the strengths of the various phonon scattering processes have been estimated. Our analysis further suggests strong influence of phonon scattering by 2D like defects in the thermal conductivity of monovalent doped lanthanum manganites at low temperatures (<70 K) in the ferromagnetic region. 相似文献
55.
56.
研究了应用于锂二次电池正极的新型高能量密度存贮材料Li(AlxCo1-x)O2 (x=01—05)的磁性.发现Al3+的掺杂可导致Co3+中d电子自旋态发生变化,即有部分d电子进入高自旋态.伴随Co3+中电子状态的改变,材料结构演化也发生了相应变化,表现为c/a比增大明显减缓,较好地解释了材料结构对Vegard定律的正偏离.这对材料的微观结构与性能设计具有重要意义.
关键词:
锂电池材料
Li(AlxCo1-x)O2
磁性
自旋态
结构演化 相似文献
57.
58.
Jin-Mok Hur Chung-Seok Seo Sun-Seok Hong Dae-Seung Kang Seong-Won Park 《Reaction Kinetics and Catalysis Letters》2003,80(2):217-222
The concept of a novel electrochemical reduction process for the treatment of spent nuclear fuels in Li2O-LiCl molten salt was proposed and fresh tests using U3O8 powder were carried out to elucidate the reaction mechanism and verify the feasibility of the process. Electrolysis of Li2O and reduction of U3O8 powder took place simultaneously at the cathode part of the electrolysis cell via a catalytic EC mechanism and the conversion of U3O8 to U metal was more than 99%.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
59.
Frequency dependence of ac conductivity from 1 to 105 Hz and time series of the conductivity at 2 kHz were measured along c-axis of thulium nitrate crystal, Tm(NO3)36H2O at temperatures from 203.15 to 293.15 K. The meta-stability was observed. The frequency spectra of the conductivity were similar to those in disorder system. Aging effect was observed. Non-periodic instability (burst) was found. Non-linear dynamical property was characterized by 1/f noise spectrum, limit cycle in return map and dependence of correlation exponent on embedding dimension. 相似文献
60.