全文获取类型
收费全文 | 107970篇 |
免费 | 9304篇 |
国内免费 | 16229篇 |
专业分类
化学 | 85994篇 |
晶体学 | 2834篇 |
力学 | 1851篇 |
综合类 | 1284篇 |
数学 | 13607篇 |
物理学 | 27933篇 |
出版年
2024年 | 188篇 |
2023年 | 1383篇 |
2022年 | 2122篇 |
2021年 | 3606篇 |
2020年 | 3307篇 |
2019年 | 3203篇 |
2018年 | 2564篇 |
2017年 | 3276篇 |
2016年 | 3499篇 |
2015年 | 3186篇 |
2014年 | 4243篇 |
2013年 | 8454篇 |
2012年 | 5913篇 |
2011年 | 6536篇 |
2010年 | 5673篇 |
2009年 | 6953篇 |
2008年 | 6983篇 |
2007年 | 7205篇 |
2006年 | 6370篇 |
2005年 | 5253篇 |
2004年 | 5019篇 |
2003年 | 4385篇 |
2002年 | 6337篇 |
2001年 | 3435篇 |
2000年 | 2959篇 |
1999年 | 2385篇 |
1998年 | 2131篇 |
1997年 | 1759篇 |
1996年 | 1637篇 |
1995年 | 1530篇 |
1994年 | 1441篇 |
1993年 | 1287篇 |
1992年 | 1244篇 |
1991年 | 878篇 |
1990年 | 659篇 |
1989年 | 615篇 |
1988年 | 573篇 |
1987年 | 395篇 |
1986年 | 367篇 |
1985年 | 473篇 |
1984年 | 366篇 |
1983年 | 203篇 |
1982年 | 378篇 |
1981年 | 575篇 |
1980年 | 517篇 |
1979年 | 525篇 |
1978年 | 418篇 |
1977年 | 331篇 |
1976年 | 274篇 |
1973年 | 184篇 |
排序方式: 共有10000条查询结果,搜索用时 140 毫秒
941.
942.
Transverse flow transversely excited (TFTE) CO2 lasers are easily scalable to multikilowatt level. The laser power can be scaled up by increasing the volumetric gas flow
and discharge volume. It was observed in a TFTE CW CO2 laser having single row of pins as an anode and tubular cathode that the laser power was not increasing when the discharge
volume and the gas volumetric flow were increased by increasing the electrode separation keeping the gas flow velocity constant.
The discharge voltage too remained almost constant with the change of electrode separation at the same gas flow velocity.
This necessitated revision of the scaling laws for designing this type of high power CO2 laser. Experimental results of laser performance for different electrode separations are discussed and the modifications
in the scaling laws are presented. 相似文献
943.
A three-dimensional Ising-like model doped with anti-ferromagnetic (AFM) bonds is proposed to investigate the magnetic properties
of a doped triangular spin-chain system by using a Monte-Carlo simulation. The simulated results indicate that a steplike
magnetization behavior is very sensitive to the concentration of AFM bonds. A low concentration of AFM bonds can suppress
the stepwise behavior considerably, in accordance with doping experiments on Ca3Co2O6. The analysis of spin snapshots demonstrates that the AFM bond doping not only breaks the ferromagnetic ordered linear spin
chains along the hexagonal c-axis but also has a great influence upon the spin configuration in the ab-plane.
相似文献
944.
M. Drewsen 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,45(1):125-127
We briefly discuss some possibilities for cooling, identification and spectroscopy of super-heavy element (SHE) ions based
on recent results obtained from studies of atomic and molecular ions in linear rf traps. Since these investigations only relied
on the charge and the mass of the ion of interest, we believe it should be straight forward to adopt most of the techniques
for SHE ion research. 相似文献
945.
Július Korbaš 《Topology and its Applications》2006,153(15):2976-2986
Our main result offers a new (quite systematic) way of deriving bounds for the cup-length of Poincaré spaces over fields; we outline a general research program based on this result. For the oriented Grassmann manifolds, already a limited realization of the program leads, in many cases, to the exact values of the cup-length and to interesting information on the Lyusternik-Shnirel'man category. 相似文献
946.
Polycrystalline perovskite La0.67Ca0.33MnO3 was synthesized by a sol–gel method. Its adiabatic temperature change ΔTad induced by a magnetic field change was measured directly. At 268 K, near its Curie temperature TC, ΔTad of La0.67Ca0.33MnO3 induced by a magnetic field change of 2.02 T reaches 2.4 K. The latent heat Q and magnetic entropy change −ΔSM induced by a magnetic field change were calculated from the temperature dependence of ΔTad and zero-field heat capacity Cp. The maximum values of Q and −ΔSM in La0.67Ca0.33MnO3 induced by a magnetic field change of 2.02 T are 1.85 J g−1 and 6.9 J kg−1 K−1, respectively. The former is larger than the phase transition latent heat of heating or cooling, which is about 1.70 J g−1. 相似文献
947.
Let D be a simply laced Dynkin diagram of rank r whose affinization has the shape of a star (i.e., D4,E6,E7,E8). To such a diagram one can attach a group G whose generators correspond to the legs of the affinization, have orders equal to the leg lengths plus 1, and the product of the generators is 1. The group G is then a 2-dimensional crystallographic group: G=Z??Z2, where ? is 2, 3, 4, and 6, respectively. In this paper, we define a flat deformation H(t,q) of the group algebra C[G] of this group, by replacing the relations saying that the generators have prescribed orders by their deformations, saying that the generators satisfy monic polynomial equations of these orders with arbitrary roots (which are deformation parameters). The algebra H(t,q) for D4 is the Cherednik algebra of type C∨C1, which was studied by Noumi, Sahi, and Stokman, and controls Askey-Wilson polynomials. We prove that H(t,q) is the universal deformation of the twisted group algebra of G, and that this deformation is compatible with certain filtrations on C[G]. We also show that if q is a root of unity, then for generic t the algebra H(t,q) is an Azumaya algebra, and its center is the function algebra on an affine del Pezzo surface. For generic q, the spherical subalgebra eH(t,q)e provides a quantization of such surfaces. We also discuss connections of H(t,q) with preprojective algebras and Painlevé VI. 相似文献
948.
Xiujie Li Weiping Zhang Shenglin Liu Xiuwen Han Longya Xu Xinhe Bao 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):94-99
The interfacial interaction of Mo species with the HBeta zeolite was studied by multinuclear MAS NMR, XRD and N2 adsorption. As proved by the quantitative 27Al MAS NMR, this interaction is so strong as to dealuminate the framework of HBeta, and leads to a new peak appearing at −14 ppm, which indicates the formation of crystalline Al2(MoO4)3. This can also be detected by XRD measurements when the Mo loading is as high as 9.0 wt.%. The corresponding quantitative 29Si and 1H MAS NMR spectra show that the amount of silanols and Brønsted acidic sites decrease obviously with increasing Mo loading. This also reveals an interaction between Mo species and HBeta support through an oxygen bridge resulting from condensation with the hydroxyls on the support. At higher Mo loadings, the interaction is so strong that it results in an extraction of aluminum from the zeolite framework, and subsequently appearance of Al2(MoO4)3 and loss of Brønsted acidic sites. These can be correlated to the low catalytic activity of Mo/HBeta in metathesis of ethylene and 2-butylene to propylene. 相似文献
949.
Panagiota G. Fragouli Hermis Iatrou Nikos Hadjichristidis Takuro Sakurai Akira Hirao 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):614-619
3‐Miktoarm star copolymers, 3μ‐D2V, with two poly(dimethylsiloxane) (PDMS) and one poly(2‐vinylpyridine) (P2VP) arm, were synthesized by using anionic polymerization–high vacuum techniques and (chloromethylphenylethyl)methyl dichlorosilane, heterofunctional linking agent, with two SiCl groups and one CH2Cl group. The synthetic strategy involves the selective reaction of the two ? SiCl groups with PDMSOLi living chains, followed by reaction of the remaining chloromethyl group with P2VPLi. Combined molecular characterization results (size exclusion chromatography, membrane osmometry, and 1H NMR spectroscopy) revealed a high degree of structural and compositional homogeneity. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 614–619, 2006 相似文献
950.
R. Riva J. Rieger R. Jrme PH. Lecomte 《Journal of polymer science. Part A, Polymer chemistry》2006,44(20):6015-6024
This paper aims at reporting on the synthesis of a heterograft copolymer by combining the “grafting onto” process based on atom transfer radical addition (ATRA) and the “grafting from” process by atom transfer radical polymerization (ATRP). The statistical copolymerization of ε‐caprolactone (εCL) and α‐chloro‐ε‐caprolactone (αClεCL) was initiated by 2,2‐dibutyl‐2‐stanna‐1,3‐dioxepane (DSDOP), followed by ATRA of parts of the chlorinated units of poly(αClεCL‐co‐εCL) on the terminal double bond of α‐MeO,ω‐CH2?CH? CH2? CO2‐poly(ethylene oxide) (PEO). The amphiphilic poly(εCL‐g‐EO) graft copolymer collected at this stage forms micelles as supported by dynamic light scattering (DLS) and transmission electron microscopy (TEM). The unreacted pendant chloro groups of poly(εCL‐g‐EO) were used to initiate the ATRP of styrene with formation of copolymer with two populations of randomly distributed grafts, that is PEO and polystyrene. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6015–6024, 2006 相似文献