t—BuNO二聚体在不同溶剂中裂解机理的研究

本文利用＾１ＨＮＭＲ，ＵＶ－Ｖｉｓ方法，研究了ｔ－ＢｕＮＯ二聚体在有机溶剂及水溶液中的裂解反应产物，分析了其反应的动力学，提出了在非极性的有机相中ｔ－ＢｕＮＯ二聚体为均裂反应，而在极性的水相中为均裂和异裂同时进行的竞争反应。     

Determination of the rate of rapid lipid transfer induced by poly(ethylene glycol) using the SLM Fourier transform phase and modulation spectrofluorometer

Rate constants were determined for the transfer of the fluorescent lipid probe 1-palmitoyl-2-[[2-[4-(6-phenyl-trans-1,3,5-hexatrienyl)phenyl]ethyl] oxy]carbonyl]-3-sn-phosphatidylcholine (DPHpPC) between large, unilamellar extrusion vesicles composed either of dipalmitoyl phosphatidylcholine (DPPC) or of DPPC mixed with a small amount (0.5 mol%) of lyso phosphatidylcholine (Lyso PC). Transfer of the lipid probe in the presence of varying concentrations of poly(ethylene glycol) (PEG) was monitored using the SLM 48000-MHF Multi-Harmonic Fourier Transform phase and modulation spectrofluorometer to collect multifrequency phase and modulation fluorescence data sets on a subsecond time scale. The unique ability of this instrument to yield accurate fluorescence lifetime data on this time scale allowed transfer to be detected in terms of a time-dependent change in the fluorescent lifetime distribution associated with the lipid-like DPHpPC probe. This probe demonstrates two short fluoresence decay times (ca. 1.1–1.4 and 4.3–4.8 ns) in a probe-rich environment but a single long lifetime (ca. 7 ns) in a probe-poor environment. A simple two-state model for initial lipid transfer was used to analyze the multifrequency data sets collected over a 4-s time frame to obtain the time rate of change of the concentrations of donor and acceptor probe populations following rapid mixing of vesicles with PEG. The ability to measure fluorescence lifetimes on this time scale has allowed us to show that the of rate of lipid transfer increased dramatically at 35% PEG in both fusing and nonfusing vesicle systems. These results are interpreted in terms of a distinct interbilayer structure associated with intimate bilayer contact induced by high and potentially fusogenic concentrations of PEG.     

Synthesis of aromatic poly(thioether ketone)

Aromatic poly(thioether ketone)s were prepared by the direct polycondensation of aromatic dicarboxylic acids with aryl compounds containing ether or sulfide structures using phosphorus pentoxide/methanesulfonic acid (PPMA) as a condensing agent and solvent. Polycondensation proceeded smoothly and produced aromatic poly(thioether ketone)s with inherent viscosities up to 0.73 dL/g. The synthesis of substituted aryl ketones by the reaction of substituted benzoic acids with aryl compounds in PMMA was studied in detail to demonstrate the feasibility of the reaction for polymer formation. The thermogravimetry of the aromatic poly(thioether ketone)s showed a 10% weight loss in air and nitrogen at around 450 and 460°C, respectively. © 1992 John Wiley & Sons, Inc.     

聚丙烯微孔膜的等离子体接枝聚合改性

利用拉伸时的晶型转变致孔特性,从β晶相聚丙烯经单向或双向拉伸制得了新型聚丙烯微孔膜、用等离子体接枝聚合技术接上了亲水性聚合物如聚丙烯酸、聚丙烯腈等。研究了等离子体处理时间、单体性质对得到的亲水膜的亲水性、离子/溶质渗透性的影响。发现接枝聚丙烯酸的双向拉伸膜对Na~+、Mg~(++),尿素有较大的渗透性,并具有优良的形状稳定性。     

Directional crystallization and self-assembling initiated by mechanical shock or electron beam in nanocrystalline Co-C and Fe-C films

We investigated iron and cobalt films with 20% carbon concentration with nanocrystalline structure. One of the aims of this work is to analyze the physical nature of high-speed structural self-assembling as often happens in explosive crystallization processes in these films.     

Mechanism of the thermal decomposition of nitrates from graphite furnace mass spectrometry studies

A basically new mechanism of the thermal decomposition of solids is proposed to explain the mass spectral observations of gaseous molecules of CoO, CuO, Cu₂O, NiO, PbO and Mg(OH)₂ during the low-temperature decomposition of the anhydrous and hydrated nitrates of these metals. The mechanism consists of two stages: congruent gasification of all reaction products irrespective of their saturated vapor pressure and subsequent condensation of the low-volatility species (oxides and hydroxides). The partial pressures of these species at the appearance temperatures calculated from this theory for the first stage of the process (1–50 mPa) are in agreement with the detection limits of the quadrupole mass spectrometers used in these experiments. The proposed mechanism is supported by other available data obtained by thermal analysis.     

Exact groups and Fell bundles

Kirchberg and Wasserman's Theorem, according to which a group is exact if and only if its reduced C*-algebra is exact, is extended to the context of Fell bundles. Received: 31 December 2000 / Revised version: 7 August 2001 / Published online: 4 April 2002     

分段函数的分类及分离型分段函数与初等函数之间的关系

将分段函数划分为连结型分段函数 ,分离型分段函数和它们的组合形式三种类型 ,得到了分离型分段函数是初等函数的充分必要条件 ,完整地解决了分离型分段函数与初等函数之间的关系 ,并且给出了初等函数在其任一截取集上的限制函数 (截取函数 )仍然是初等函数的结果     

Chemical imaging in biology and medicine using ion microscopy

The ability to quantitatively map the distribution of elements on the micrometer scale and smaller with high sensitivity and isotopic discrimination is unique to ion microscopy. The information contained in ion images can be crucial to the study of the solid state, where chemical heterogeneity is often directly related to observed behavior. The tools of digital image processing allow the extraction of quantitative information from the image data. These techniques coupled with improved instrumentation for the detection of ion images drastically increase the problem solving capabilities of the ion microscope. The use of such methods and instrumentation in the ion microscopic analyses of cell cultures and tissues of biological and biomedical relevance will be discussed.