JRQ and JPA irradiated and annealed reactor pressure vessel steels studied by positron annihilation

The paper is focused on a comprehensive study of JRQ and JPA reactor pressure vessel steels from the positron annihilation lifetime spectroscopy (PALS) point of view. Based on our more than 20 years’ experience with characterization of irradiated reactor steels, we confirmed that defects after irradiation start to grow and/or merge into bigger clusters. Experimental results shown that JPA steel is more sensitive to the creation of irradiation-induced defects than JRQ steel. It is most probably due to high copper content (0.29?wt.% in JPA) and copper precipitation has a major impact on neutron-induced defect creation at the beginning of the irradiation. Based on current PALS results, no large vacancy clusters were formed during irradiation, which could cause dangerous embrittlement concerning operation safety of nuclear power plant. The combined PALS, small angle neutron scattering and atomic probe tomography studies support the model for JRQ and JPA steels describing the structure of irradiation-induced clusters as agglomerations of vacancy clusters (consisting of 2–6 vacancies each) and are separated from each other by a distribution of atoms.     

Externally applied stress sign and film elastic properties effects on brittle film fracture

Rectangular stainless steel samples with TiN film deposited on the front lateral surface were loaded in three-point bending to the maximum normal strain of 6%. Scanning electron microscopy showed that vertical cracks appeared in the tension zone when the tensile strain exceeded 1.5%, while horizontal cracks appeared in the compression zone when the compressive strain exceeded –2.9%. Film cracks in the compressive zone originate from the tensile stress imposed by the plastically deformed substrate due to the Poisson’s expansion. Taking plastic deformation and Poisson’s expansion of the substrate in compression into account, theoretical analysis of normal stress distribution along the cracked film segment in compression is presented. Substrate strain and film elastic properties affect film cracking in the compressive zone. At larger compressive strain, some transverse cracks along with buckling cause the film spallation. The presented method is useful for studying brittle film fracture with variable strain levels in a single sample.     

高能火花光源激发钢铁和铜合金中铝的看谱分析

采用高能火花光泊激钢铁和铜合金试样,借以进行铝的看谱分析,研究了在高能火花光源激发下光谱出现和其强度变化的规律以及以５６９．６５ｎｍ光谱区域的干扰情况。从而制 钢铁和铜合金中铝的看谱分析方法,并将其应用于生产实践中获得了令人满意的结果。是一种既经济简便及快速实用的分析测定方法 。     

钢闸门支承滑道摩擦随时间变化的研究

研究了胶木、油尼龙和铜塑固体自润滑复合材料（ＴＳ－７０）３种平面滑动钢闸门支承滑道的摩擦时间效应,介绍了胶木和ＴＳ－７０滑道摩擦时间效应的原型试验结果,用粘着理论解释胶木与油尼龙滑道摩擦时间效应强、ＴＳ－７０滑道摩擦时间效应弱的原因在于粘弹性材料的蠕变大,引起实际接触面积增大,粘弹性材料的剪切模量的时间效应也大,使界面剪切强度增大。     

络合吸附波极谱法测定稀土钢中微量稀土

研究了在ｐＨ９．２－ｐＨ９．５的ＮＨ３０Ｎａ２Ｂ４Ｏ７介质中,稀土与百里香酚酞的络合物极谱波,波高与镧量在４．０×１０＾－７－３．６×１０＾－６ｍｏｌ／Ｌ范围内成线性关系。方法已用于稀土钢中微量稀土的测定。     

Tensile testing of microsamples

Structural analysis has advanced rapidly to the point where lack of knowledge about the local inhomogeneity and anisotropic nature of the materials prevents the accurate prediction of the behavior; models can incorporate local material properties provided they can be experimentally determined. Conventional tensile techniques are unable to test speciments from submillimeter-sized regions, and micro-hardness measurements do not reveal directional variations. A system has been developed to perform tensile tests on microsamples that are 3.1 mm long with a gage cross section that is 0.2 mm square. The volume of the test region is roughly 500,000 times smaller than a standard half-inch diameter specimen. Tensile stress-strain curves are measured, and the yield strength, ultimate strength, modulus and elongation are calculated for each sample. Samples cut from the weld metal of undermatched welds in HY-100 plate showed a large variation in properties from the center of the weld to the outer edge, as well as anisotropy at some locations. The average mechanical properties of a group of microsamples cut from the outer region of the weldment compared favorably with measurements made using full-sized specimens; the variation in the microsample measurements reflect local variations in the material that are not measured with full-sized specimens.     

45~#碳钢表面激光铬镍合金化及其耐磨性的研究

作者利用1.1kW CO_2激光器对45~#碳钢表面进行了激光铬镍合金化处理。通过对合金层的成分和相组织分析,以及对合金层和基体的硬度与耐磨性的研究认为,激光铬镍合金化层的组织是胞状枝晶,其相组成为马氏体加残余奥氏体。测试结果表明,合金层的显微硬度是45~#碳钢基体的2～3倍,耐磨性也明显地比基体材料的好。     

钢结构斜隅支撑体系弹塑性计算方法研究

钢结构斜隅支撑体系是一种新型结构体系。与一般的纯框架和中心支撑框架体系不同,该体系综合了延性好、抗侧移刚度大的特点。在遭遇罕遇地震荷载作用下,结构通过隅撑的弯曲屈服耗能,保证其他主要构件不受损伤,使得震后修复较为容易且费用较低。但此类结构复杂的非线性分析在一定程度上阻碍了其推广与应用。本文经过力学分析推导,结合有限元方法和塑性铰理论提出了一种简化计算分析模型。采用该模型,整个求解过程仅涉及少量的线性计算,不涉及迭代,可以有效地简化斜隅支撑结构在侧向荷载作用下的弹塑性受力分析。算例表明,该计算方法建模合理,运算速度快。同时,计算结果稳定、可靠,与有限元分析程序得出的结果具有较好的一致性。     

Mössbauer study of the annealing effect on low‐alloyed steels

Structural analyses of Fe-Cr and Fe-Cr-Ni low‐alloyed steels before and after annealing at 600^○C using Mössbauer spectrometry, X‐ray diffraction and scanning electron microscopy are reported. At the received state, the two steels present a fine bainitic microstructure with equal hardness. From Mössbauer analysis, two iron sites are identified as substitutional by Cr, Mo, Ni atoms and as insertional by carbon in bainitic ferrite. Both sites are locally deformed by residual stresses. The presence of small quantities of retained austenite and ε carbide has been observed. Annealing for one hour at 600^○C causes a decrease in hardness for both steels with a decrease of retained austenite. After longer time of annealing, precipitation of (Fe,Ni)₂₃C₆ occurs in the Fe-Cr-Ni steel and increases hardness.     

X射线荧光光谱扩展基本参数法测定不锈钢中的多种成分

针对多种类不锈钢多元素成分解析问题,应用X射线荧光光谱分析软件UniQuant,采用扩展基本参数法对多元不锈钢、双相不锈钢进行光谱干扰校正和基体校正,重新设定和优化多元不锈钢基体元素的测试条件,计算背景因子、杂质因子、谱线灵敏度系数和光谱重叠系数,测定Si、Mn、S、P、Ni、Cr、Cu、Mo、V、Al、Ti、Nb、Co、Ta、Fe的相对标准偏差在0.04%~3.8%,Ca、Zr、W、As、Sb、Sn的相对标准偏差在5.4%~20.3%,未知样品检测值与认定值比对结果相当理想,Ni、Cr的平均偏差小于0.05%,可以用很少标准样品实现各类型不锈钢多元素成分准确检测,检测范围宽,适用性好。