全文获取类型
收费全文 | 9398篇 |
免费 | 1203篇 |
国内免费 | 1082篇 |
专业分类
化学 | 3970篇 |
晶体学 | 91篇 |
力学 | 1470篇 |
综合类 | 54篇 |
数学 | 261篇 |
物理学 | 5837篇 |
出版年
2024年 | 19篇 |
2023年 | 100篇 |
2022年 | 162篇 |
2021年 | 188篇 |
2020年 | 250篇 |
2019年 | 235篇 |
2018年 | 230篇 |
2017年 | 271篇 |
2016年 | 364篇 |
2015年 | 421篇 |
2014年 | 427篇 |
2013年 | 1144篇 |
2012年 | 603篇 |
2011年 | 808篇 |
2010年 | 506篇 |
2009年 | 587篇 |
2008年 | 549篇 |
2007年 | 582篇 |
2006年 | 499篇 |
2005年 | 430篇 |
2004年 | 400篇 |
2003年 | 347篇 |
2002年 | 338篇 |
2001年 | 285篇 |
2000年 | 224篇 |
1999年 | 179篇 |
1998年 | 217篇 |
1997年 | 161篇 |
1996年 | 139篇 |
1995年 | 151篇 |
1994年 | 119篇 |
1993年 | 125篇 |
1992年 | 103篇 |
1991年 | 93篇 |
1990年 | 55篇 |
1989年 | 55篇 |
1988年 | 61篇 |
1987年 | 41篇 |
1986年 | 34篇 |
1985年 | 33篇 |
1984年 | 27篇 |
1983年 | 9篇 |
1982年 | 24篇 |
1981年 | 24篇 |
1980年 | 8篇 |
1979年 | 19篇 |
1976年 | 5篇 |
1974年 | 5篇 |
1973年 | 9篇 |
1972年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
针对VO2薄膜在微测辐射热计上的应用,采用射频反应溅射法,在室温下制备氧化钒薄膜;研究了氧分压对薄膜沉积速率、电学性质及成分的影响.通过调节氧分压,先获得成分接近VO2的非晶化薄膜,再在400℃空气中氧化退火,便可制得高电阻温度系数,低电阻率的VO2薄膜,电阻温度系数约为-4%/℃,薄膜方块电阻为R□为100—300kΩ;薄膜在室温下沉积,400℃下退火的制备方法与微机电加工(micro electromechanic
关键词:
二氧化钒
电阻温度系数
氧分压
射频反应溅射法 相似文献
12.
More than 250 rotationally resolved vibrational bands of the A2B2-X2A1 electronic transition of 15NO2 have been observed in the 14 300-18 000 cm−1 range. The bands have been recorded in a recently constructed setup designed for high resolution spectroscopy of jet cooled molecules by combining time gated fluorescence spectroscopy and molecular beam techniques. The majority of the observed bands has been rotationally assigned and can be identified as transitions starting from the vibrational ground state or from vibrationally excited (hot band) states. An exceptionally strong band is located at 14 851 cm−1 and studied in more detail as a typical benchmark transition to monitor 15NO2 in atmospheric remote sensing experiments. Standard rotational fit routines provide band origins, rotational and spin rotation constants. A subset of 177 vibronic levels of 2B2 vibronic symmetry has been analyzed in the energy range between 14 300 and 17 250 cm−1, in terms of integrated density and using Next Neighbor Distribution. It is found that the overall statistical properties and polyad structure of 15NO2 are comparable to those of 14NO2 but that the internal structures of the polyads are completely different. This is a direct consequence of the X2A1-A2B2 vibronic mixing. 相似文献
13.
14.
Q. Sun Q. Wang X.G. Gong V. Kumar Y. Kawazoe 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(1):77-81
We report results of the atomic and electronic structures of Al7C cluster using ab initio molecular dynamics with ultrasoft pseudopotentials and generalized gradient approximation. The lowest energy structure is
found to be the one in which carbon atom occupies an interstitial position in Al7 cluster. The electronic structure shows that the recent observation [Chem. Phys. Lett. 316, 31 (2000)] of magic behavior of Al7C- cluster is due to a large highest occupied and lowest unoccupied molecular orbital (HOMO-LUMO) gap which makes Al7C- chemically inert. These results have further led us to the finding of a new neutral magic cluster Al7N which has the same number of valence electrons as in Al7C- and a large HOMO-LUMO gap of 1.99 eV. Further, calculations have been carried out on (Al7N)2 to study interaction between magic clusters.
Received 28 July 2001 相似文献
15.
S. Meenakshi B.K. Godwal I. Orgzall S. Tkachev 《Journal of Physics and Chemistry of Solids》2006,67(8):1660-1667
We report the results of an X-ray diffraction study of CdAl2Se4 and of Raman studies of HgAl2Se4 and ZnAl2Se4 at room temperature, and of CdAl2S4 and CdAl2Se4 at 80 K at high pressure. The ambient pressure phase of CdAl2Se4 is stable up to a pressure of 9.1 GPa above which a phase transition to a disordered rock salt phase is observed. A fit of the volume pressure data to a Birch-Murnaghan type equation of state yields a bulk modulus of 52.1 GPa. The relative volume change at the phase transition at ∼9 GPa is about 10%. The analysis of the Raman data of HgAl2Se4 and ZnAl2Se4 reveals a general trend observed for different defect chalcopyrite materials. The line widths of the Raman peaks change at intermediate pressures between 4 and 6 GPa as an indication of the pressure induced two stage order-disorder transition observed in these materials. In addition, we include results of a low temperature Raman study of CdAl2S4 and CdAl2Se4, which shows a very weak temperature dependence of the Raman-active phonon modes. 相似文献
16.
The molding processes of polymer melts involve geometrically complex dies. Such dies are usually tapered or streamlined to achieve a maximum output rate under conditions of laminar flow. The model of a generalized second-grade fluid of power-law type is used and the results obtained are illustrated by examples of convergent flows in conical and wedge-shaped dies. 相似文献
17.
18.
A new speckle shearing interferometer with simple setup is proposed. The interferometer can be converted easily from a speckle referenced speckle pattern interferometer into a speckle shearing interferometer and vice versa. A beamsplitter and a mirror are used to generate the shear. The amount of shear can be adjusted by simply rotating the mirror. The costs involved are low and it is particularly useful for fast inspection in non-destructive testing of structural integrity. Both the theoretical studies of the method of measurement and the experimental results are presented. 相似文献
19.
用经验赝势方法计算了体ZnSe以及ZnSe/GaAs单异质结系统中ZnSe外延层г、X、L等特殊对称点导带底能量随压力的变化。结果表明,同Si、Ge、GaAs等半导体材料不同,ZnSe的X点导带底具有正的压力系数,但比г点的压力系数小,这是ZnSe材料以及ZnSe基异质结构材料发生直接禁带向间接禁带的转变时所需转变压力较大的根本原因。研究了ZnSe/GaAs异质结构中晶格失配造成的应变对外延层г、X、L对称点压力系数的影响,表明这种晶格失配造成的应变可以极大地减小ZnSe外延层材料由直接禁带向间接禁带的转变压力。 相似文献
20.
A. B. Mitkevich 《Mechanics of Composite Materials》2005,41(6):497-504
Errors in the programs of winding pressure vessels can lead to an asymmetric reinforcement structure, which affects the equilibrium
shape of their domes and the tension in the left and right families of filaments. In this paper, equations determining the
equilibrium shape of the domes, the tension in filaments, and the shear stresses between layers are obtained. Examples with
winding trajectories in the form of geodesics and constant-deviation lines are considered. It is found that, for pressure
vessels, in the absence of external torque, the tension levels in filaments of the left and right families differ considerably.
It is also revealed that, for actual friction coefficients in winding, the shear stresses taken up by the binder are insignificant.
__________
Translated from Mekhanika Kompozitnykh Materialov, Vol. 41, No. 6, pp. 743–752, November–December, 2005. 相似文献