稀磁半导体Zn1-xFexO纳米颗粒的光谱研究

利用水热法制备了Zn1-xFexO(x=0,0.01,0.05,0.10和0.20)纳米稀磁半导体材料。由X射线衍射图谱的结果表明,制备的Zn1-xFexO样品为纤锌矿结构,没有金属铁等第二相出现;高分辨透射电子显微镜的结果表明,形貌为分散性良好的纳米颗粒,晶格清晰;拉曼光谱结果表明(E2High)峰位向高频移动,半高宽宽化,峰强减弱;光致发光光谱结果表明,随着Fe离子的掺入,紫外峰向低能移动,光致发光光谱发生了猝灭现象;UV-Vis光谱可看出,光学带隙减小,发生了红移现象。这些结果表明Fe3+成功替代Zn2+进入到ZnO晶格。     

Sb，In，P掺杂对SnO2薄膜透明导电性能的影响

采用溶胶凝胶（Sol-Gel）技术制备了SnO2：（Sb，In）透明导电薄膜，优化了制备工艺参数，获得了最佳制备条件．研究表明，4％的铟掺杂有效地改善了薄膜的内部结构，使得紫外-可见光的透过率显著增加；7％的锑掺杂释放出了更多的栽流子，使薄膜的方块电阻降低，2％的磷掺杂因准连续杂质能带的形成进一步提高了薄膜的电导率．Sb、In、P的掺入使得SnO2薄膜的紫外-可见光的透过率达83％，方块电阻达38Ω。     

Dynamical spin susceptibility of the d–p model in the over doping region

Dynamical spin susceptibility χ^s(q,ω) of the d–p model in the over doping region is investigated by using the auxiliary boson technique. It includes higher order terms of the 1/N-expansion within the random phase approximation (RPA) of the local vertex, where frequency dependence of the quasi-particle interaction is taken into account. The incommensurate spin fluctuation is obtained due to the nesting effect in the low energy region (ωω^*), whereas the commensurate one in the high energy region (ωω^*), the characteristic energy ω^* is estimated to be about 30 meV. Both of the spin–lattice relaxation rate 1/T₁ and the spin–spin relaxation rate 1/T_g monotonically increase as T decreases, while the spin Knight shift K is almost independent of T.     

掺杂石英系单模光纤对BSBS频移的影响

报道了对几种掺杂SiO₂石英系单模光纤的背向受激布里渊散射(BSBS)谱的实验结果,结果表明其布里渊散射斯托克斯频移主要取决于纤芯的掺杂材料和浓度,进一步分析证明了光纤掺杂后将主要通过调制杨氏模量的变化,从而导致BSBS频移量减小.     

Growing kinetics and structural characterization of oxide film formed on La-doped Co-40Cr alloy

The isothermal and cyclic oxidizing kinetics of Co-40Cr alloy and its lanthanum ion-implanted samples were studied at 1000℃ in air by thermal-gravity analysis (TGA). Scanning electronic microscopy (SEM) and transmission electronic microscopy (TEM)) were used to examine the oxidized film's morphology and the structure after oxidation. Secondary ion mass spectrum (SIMS) method was used to examine the binding energy change of chromium caused by La-doping and its in?uence on formation of Cr2O3 film. Laser Raman spectrum was used to examine the tress changes within oxidized films. It was found that lanthanum implantation remarkably reduced the isothermal oxidizing rate of Co-40Cr and improved the anti-cracking and anti-spalling properties of Cr2O3 film. The reasons were that the implanted lanthanum reduced the grain size and internal stress of Cr2O3 oxide, increased the high temperature plasticity of oxidized film. Lanthanum mainly existed in the outer surface of Cr2O3 film in the forms of fine La2O3 and LaCrO3 spinel particles.     

Structural studies on fullerenes

Amongst the other physical properties, the structure of fullerene solids, and the structural transformations with temperature, pressure and doping have all evoked considerable interest and during the last two years tremendous progress has been made in this area. This paper provides a brief review of the studies on the structural properties of pristine and doped fullerenes. The results of our own investigations are also presented.     

Synthesis and Characterization of TiO2 Doped ZnO Microtubes

以氯化锌和硫酸钛为原料,通过湿化学法成功制备了钛掺杂氧化锌微米管. 以粉末X射线衍射仪、场发射扫描电子显微镜、光致发光系统对样品进行了表征. 结果表明,未经掺杂的氧化锌微管具有良好的六方中空结构. 在TiO₂/ZnO比率小于5%时,钛掺杂和未掺杂氧化锌管具有相近的尺度,外表光滑,近于圆柱形. 当TiO₂/ZnO比率大于5%时,生成一种由ZnO, Ti₃O₅和TiO组成的多相混合物. 钛掺杂氧化锌在光催化降解甲基橙溶液效果明显.     

Origin of the 330 nm absorption band and effect of doping Yb in LiYF4 crystals

The electronic structures of LiYF₄ (YLF) crystals containing F color center (YLF-F) and Yb doped YLF crystals (Yb³⁺:YLF, Yb²⁺:YLF) are systematically studied within the framework of the density functional theory. The calculated results indicate that the 330 nm absorption band originates from the F center in YLF crystals. Thus the doping of Yb³⁺ can weaken the 330 nm absorption band by competing with F vacancies in capturing free electrons arising after γ-irradiation and change to Yb². By analyzing the lattice relaxation and the electronic structure of YLF containing Yb²⁺, we can reasonably believe that once Yb²⁺ is formed in YLF crystal, its compensating hole will turn out to be shared by two F⁻ nearest to Yb²⁺ forming a diatomic fluoride molecular ion () perturbed by Yb²⁺, or to say V_F color center. According to the molecular-orbital linear combination of atomic orbital (MO-LCAOs) theory, compared to the alkali halides, e.g. LiF, the in V_F center in LiYF₄ peaks at about 340 nm, which is in agreement with the experimental results.     

Low-temperature and ambient-pressure synthesis and shape evolution of nanocrystalline pure, La-doped and Gd-doped CeO2

Nanocrystalline cuboidal ceria has been synthesized by low-temperature hydrothermal reaction of cerium nitrate hexahydrate with hexamethylene tetramine. The particles have been doped with La and Gd by adding aqueous solution of the nitrate salts of the metals to the reaction mixture. The pure and doped particles are cubic in crystal structure and 10-25 nm in size. The pure and La-doped ceria are cuboidal in morphology, whereas the Gd-doped particles are irregular in shape. High-resolution TEM imaging and image simulation indicates that atomic level steps are present on the particle surfaces. The particles are faceted parallel to the {1 1 1} and {1 0 0} crystallographic planes and a continuous switching takes place between the two possible surface facets. It appears that the surface energies of the {1 1 1} and {1 0 0} facets are quite similar in magnitude and the interplay of surface energy determines the particle shape. Chemically sensitive imaging and spectroscopy shows that the dopants are homogeneously distributed within the particles and that the oxidation state of Ce is a mixture of +3 and +4. No preferential segregation either of the dopant or the oxidation state was observed. However, since the facet switching does depend on the chemistry of the dopant, there must be an affect on the atomic scale.