Underpotential surface reduction of mesoporous CeO<Subscript>2</Subscript> nanoparticle films

The formation of variable-thickness CeO₂ nanoparticle mesoporous films from a colloidal nanoparticle solution (approximately 1–3-nm-diameter CeO₂) is demonstrated using a layer-by-layer deposition process with small organic binder molecules such as cyclohexanehexacarboxylate and phytate. Film growth is characterised by scanning and transmission electron microscopies, X-ray scattering and quartz crystal microbalance techniques. The surface electrochemistry of CeO₂ films before and after calcination at 500 °C in air is investigated. A well-defined Ce(IV/III) redox process confined to the oxide surface is observed. Beyond a threshold potential, a new phosphate phase, presumably CePO₄, is formed during electrochemical reduction of CeO₂ in aqueous phosphate buffer solution. The voltammetric signal is sensitive to (1) thermal pre-treatment, (2) film thickness, (3) phosphate concentration and (4) pH. The reversible ‘underpotential reduction’ of CeO₂ is demonstrated at potentials positive of the threshold. A transition occurs from the reversible ‘underpotential region’ in which no phosphate phase is formed to the irreversible ‘overpotential region’ in which the formation of the cerium(III) phosphate phase is observed. The experimental results are rationalised based on surface reactivity and nucleation effects.     

Interfacial Assembly of Nanocrystals on Nanofibers with Strong Interaction for Electrocatalytic Nitrate Reduction

One-dimensional fiber architecture serves as an excellent catalyst support. The orderly arrangement of active materials on such a fiber substrate can enhance catalytic performance by exposing more active sites and facilitating mass diffusion; however, this remains a challenge. We developed an interfacial assembly strategy for the orderly distribution of metal nanocrystals on different fiber substrates to optimize their electrocatalytic performance. Using electrochemical nitrate reduction reaction (NO₃⁻RR) as a representative reaction, the iron-based nanofibers (Fe/NFs) assembly structure achieved an excellent nitrate removal capacity of 2317 mg N/g Fe and N₂ selectivity up to 97.2 %. This strategy could promote the rational design and synthesis of fiber-based electrocatalysts.     

CFETR CSMC装配误差下的电磁状态研究

中心螺旋管模型线圈是为了积累中心螺线管线圈设计和制造经验而预研的一套混合超导磁体线圈,该线圈由五大模块组成,高场区采用Nb_3Sn线圈,低场区采用NbTi线圈,可以满足紧凑型聚变装置对低纵横比的要求.然而模型线圈各模块结构复杂、尺寸庞大在装配过程中不可避免的存在装配误差,线圈励磁以后产生的非对称磁场和电磁力将分别影响等离子体的旋转和线圈整体的稳定性.为了详细分析装配误差对线圈磁场和电磁力的影响,选取模型线圈在装配过程中可能出现的典型的装配误差,基于电流丝等效模型计算了NbTi线圈偏置以后Nb_3Sn内外线圈上的磁场和电磁力.计算结果表明,由于装配误差,线圈磁场沿环向呈不均匀分布,轴向电磁力合力不为零;轴向和径向装配误差对线圈磁场和电磁力的影响存在明显的差异;电磁力随着装配误差呈线性增长,当线圈装配误差较大时将引发数倍于线圈自重的电磁力;该研究结果可为偏置状态下模型线圈的耦合场分析和线圈模块的装配方案设计优化提供参考.     

嫦娥一号卫星干涉成像光谱仪电子学设计

介绍了嫦娥一号卫星用于获取矿物光谱信息的干涉成像光谱仪电子学系统设计.概述了电子学系统的技术指标、系统组成、工作模式、外部接口和设计原则,详细描述了焦平面组件设计、视频处理和时序控制组件设计和EMC设计,给出部分正样产品实物照片以及地面实验和在轨飞行图像.各项地面试验和一年的在轨飞行结果表明该设计达到了预定的技术要求.     

光突发交换边缘路由器性能分析

本文详细分析了各种因素对光突发交换边缘路由器的性能的影响.结果显示,不同服务等级的时延要求可以通过控制组装的最大时延得以保证;不同等级数据包长的大范围变动会导致信道分配的不公平性;边缘节点越多,丢包率越高;在总输出容量一定的情况下,增加输出数据信道数可以在获得低的丢包率的同时达到较高的通道利用率,但随着边缘节点数的增加,增加输出信道数对丢包率的改善作用下降.     

KTX 反场箍缩装置装配基准网的创建与分析

介绍了反场箍缩KTX装置主机主要构成部件、安装精度要求以及装配方案。通过建立一个独立于装置之外且可永久保存的装配基准网,以及对坐标系控制网的测量数据分析,确保各部件的安装定位和准确测量。     

On a learning precedence graph concept for the automotive industry

Assembly line balancing problems (ALBP) consist in assigning the total workload for manufacturing a product to stations of an assembly line as typically applied in automotive industry. The assignment of tasks to stations is due to restrictions which can be expressed in a precedence graph. However, (automotive) manufacturers usually do not have sufficient information on their precedence graphs. As a consequence, the elaborate solution procedures for different versions of ALBP developed by more than 50 years of intensive research are often not applicable in practice.Unfortunately, the known approaches for precedence graph generation are not suitable for the conditions in the automotive industry. Therefore, we describe a new graph generation approach that is based on learning from past feasible production sequences and forms a sufficient precedence graph that guarantees feasible line balances. Computational experiments indicate that the proposed procedure is able to approximate the real precedence graph sufficiently well to detect optimal or nearly optimal solutions for a well-known benchmark data set. Even for additional large instances with up to 1,000 tasks, considerable improvements of line balances are possible. Thus, the new approach seems to be a major step to close the gap between theoretical line balancing research and practice of assembly line planning.     

阴离子型层柱材料的插层组装

提出插层组装的概念,论述了阴离子型层状材料经插层组装出结构有序的层柱材料,包括层柱材料插层组装途径、插层组装的客体、插层组装的驱动力以组装客体在层间的定位,以及插层组装的发展前景。     

氢键结合超分子水凝胶的形成与结构调控

近年来,依靠单体单元间可逆和高度取向的非共价作用力形成超分子聚合物(supramolecularpolymer)得到广泛关注[1,2].在溶液中,超分子单体单元之间通过非共价键相互作用,形成三维网络结构并将有机溶剂或水包裹形成超分子凝胶[3,4].相对于聚合物凝胶,超分子凝胶具有以下优点.(1)生