Effects of External Electric Field on Ferroelectric Superlattice with Two Alternating Layers

The effects of the external electric field on the ferroelectric superlattice with two alternating layers have been studied using the transverse Ising model based on the effective-field theory with the differential technique. The hysteresis loops and susceptibility of the system have been given. The stronger the external electric field, the smaller the susceptibility, reflecting that the polarization is weaker.     

4，4′—二偶氮苯重氮氨基偶氮苯与Ag（I）的显色反应及其应用

本文报道了4,4′ -二偶氮苯重氮氨基偶氮苯在Triton X-100存在下与Ag(Ⅰ)的显色反应.在pH10.0的硼砂-氢氧化钠缓冲溶液中,试剂与Ag(Ⅰ)形成1∶1的红色配合物,其最大吸收波长为540nm,表观摩尔吸光系数为7.55×104L*mol-1*cm-1,Ag(Ⅰ)的浓度在0-0.28mg/L范围内符合比耳定律.应用于显影废液和钮扣电池液中Ag的测定,结果令人满意.     

应用自动微分的Newton-PCG算法

一类新的使用符号微分的Newton-PCG型算法在文献[1]和[2]被导出来了。本文建立和研究应用自动微分的相应的Newton-PCG算法，理论分析和数值实验结果显示应用自动微分之后，目标函数的维数或复杂性越大，Newton-PCG算法对Newton法的改进越显著。     

Second-order Nonlinear Optical Properties of a Series of Azulene Derivatives

The first hyperpolarizabilities of a series of novel azulenic-barbituric acid chromophores have been studied by using 12 excitation wavelengths, ranging from 900 to 1907 nm. The dispersion relation of the first hyperpolarizabilities of chromophores holds the same tendency as the experimental results. In addition, the static first hyperpolarizability β0 of molecules was calculated by means of the Sum-Over-States (SOS) expression and the two-level formula respectively. The results show that these molecules possess large static first hyperpolarizabilities and the, β0 value increases as the donor or acceptor strength enhances; the distorted degree of molecules has also an important influence on the β0 value.     

The Isoelectric Point and the Points of Zero Charge of Fe-Al-Mg Hydrotalcite-like Compounds

The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations.     

β-环糊精固定相在色谱中的应用及发展趋势

β-环糊精(β-CD)对客体分子具有良好的手性识别性，广泛应用作色谱固定相等。本文按键载技术、包裹技术等分类介绍了β-CD类固定相近年来在色谱中的应用及发展趋势，并阐述了对手性识别机理的认识。     

r－不可分矩阵的本原指数（Ⅱ）

本文给出了 n阶 r-不可分矩阵的本原指数的上界 ,即任 n阶 r—不可分矩阵 A的本原指数 (A)≤n+(r- ) 2r (1≤ r相似文献   

晶体微观结构的数值计算

晶体微观结构是晶体材料在特定物理条件下其多个能量极小平衔态在空间形成的某种微尺度的规则分布．几何非线性的连续介质力学理论可以用能量极小化原理来解释晶体微观结构的形成，并用Young测度来刻画平衡态各变体在空间的概率分布．定性的理解与定量地分析和计算晶体材料的微观结构对于发展和改进高级晶体功能材料，如形状记忆合金、铁电体、磁至伸缩材料等，有重要的意义．本文回顾了近年来晶体微观结构数值计算方面的最新进展．介绍了计算晶体微观结构的几种数值方法及有关的数值分析结果。     

Magnetic and Crystalline Microstructures of Fe-Pt-B Nanocomposite Ribbons

We investigate magnetic and crystalline microstructures of melt-spun (Fe0.675Pt0.325)100-xBx (x=12, 14, 16, 18,20) nanocomposite ribbons after optimal thermal treatment using a magnetic force microscope. The magnetic microstructures are characterized by darker spots adjacent to brighter ones in a sub-micro scale and in random distribution. It is found that the strength of the exchange coupling interaction between the crystals in the 10-100 nm scale, implied by the maximum value (δM)max of the Henkel plot, could be roughly described by the ratio of the average width of the magnetic spots w^- to the average crystal size D^- for the ribbons. Moreover, we find that the intrinsic coercivity jHc of the ribbons is sensitive to their crystal sizes, and the smaller D^-, the higher jHc. Finally, by using roughness analysis, the curve of the root mean square values (δФ)rms of the phase shift of the magnetic force images versus the boron content x is obtained, which is qualitatively consistent with that of the magnetization σ12 kOe of the ribbons versus x.