复合磁性纳米NiFe2O4的制备及光谱特性

用微乳液化学剪裁方法制备了明胶包裹的复合纳米NiFe2 O4 。将明胶和亚铁盐以及镍盐制成凝胶 ,使该凝胶状反应物在微乳液的胶束中剪裁成微粒 ,再被还原 化合 成核长大。生成的微粒处于明胶蛋白分子的包裹之中。用XRD ,TEM ,EDS ,IR等测试表明 :微粒为明胶包裹球形纳米微粒。微球的平均粒径为 10～10 0nm ,单个微粒的粒径 3 3～ 4 6nm。每个复合微球中约有 3～ 2 2个NiFe2 O4 粒子。NiFe2 O4 复合微粉的比饱和磁化强度σs=36 31× 10 3 4π(A·m- 1 ·g- 1 ) ,矫顽力Hc=6 75 0A·m- 1 ,剩磁Br=4 39× 10 3 4π(A·m- 1 ·g- 1 )。     

Er~(3+),Yb~(3+)共掺杂的NaYF_4荧光粉的制备及下转换发光研究

采用高温固相法合成了Er3+、Yb3+共掺杂的NaYF4荧光粉。XRD测量数据表明合成的样品为纯相。测量了样品的激发谱和发射谱,证明377 nm的紫外光通过量子剪裁的形式将能量传递给一个Yb3+,发射一个975 nm的红外光子,再从4F9/2能级跃迁到基态发射一个红外光子。测量了377 nm激发下,监测541 nm的发光寿命曲线,计算得到最大的量子效率为126.35%。通过监测Yb3+的975 nm的近红外发射,证明了Er3+的4F7/2和2H11/2能级通过下转换的形式将吸收的485 nm和519 nm的能量传递给Yb3+。这种将Er3+在可见光波段的多种光子能量传递给Yb3+发射975 nm的近红外光子的思想在以前的研究中从未被提出。     

ErP5O14非晶中从0秒到稳态的粒子数变化过程和发光强度

分别对五磷酸盐非晶材料(ErP5O14)在979.3,803.8,521.8,450.0,405.5和378.5nm等光激发下所有能级的动力学过程在改进能量传递理论前后进行了数值模拟比较。结果发现,应用改进后的能量传递速率进行计算模拟的结果才是合理的,其中在521.8,450.0和378.5nm光激发ErP5O14非晶时,4I 13/2→4I 15/2和4I 11/2→4I 15/2跃迁的相对荧光强度的比值分别是979.3nm光激发的2.11倍,2.82倍和2.99倍,均存在有效的4I 13/2→4I 15/2跃迁的红外量子剪裁效应。该研究对于提高锗太阳能电池的转换效率具有潜在的应用前景。     

ErP5O14非晶玻璃的红外量子剪裁

研究了Er_1.0P₅O₁₄铒非晶玻璃的红外量子剪裁现象. 从吸收谱和激发光谱的计算比较中肯定了Er_1.0P₅O₁₄非晶 玻璃的1537.0 nm红外荧光为多光子量子剪裁荧光. 从Er_1.0P₅O₁₄非晶玻璃的可见和红外荧光发射光谱中发现激发²H_11/2, ⁴G_11/2和⁴G_9/2能级所导致的⁴I_13/2→⁴I_15/2量子剪裁红外荧光很强;基于自发辐射速率、无辐射弛豫速率和能量传递速率等参数的计算,对其量子剪裁机理进行了分析.发现起源于基态的强下转换能量传递{²H_11/2→⁴I_9/2,⁴I_15/2→⁴I_13/2},{⁴G_11/2→⁴I_13/2, ⁴I_15/2→²H_11/2},{⁴G_9/2→⁴F_7/2,⁴I_15/2→⁴I_13/2}和{⁴G_9/2→⁴I_13/2, ⁴I_15/2→²H_11/2}是导致Er_1.0P₅O₁₄非晶玻璃具有强的三光子和四光子量子剪裁红外荧光的原因.研究结果对改善太阳能电池效率有一定意义.     

High power dual-wavelength tunable fiber laser in linear and ring cavity configurations

We describe and compare the performances of two crucial configurations for a tunable dual-wavelength fiber laser, namely, the linear and ring configurations. The performances of these two cavities and the tunability in the dual-wavelength output varied from 0.8 to 11.9 nm are characterized. The ring cavity provides a better performance, achieving an average output power of 0.5 dBm, with a power fluctuation of only 1.1 dB and a signal-to-noise ratio (SNR) of 66 dB. Moreover, the ring cavity has minimal or no background amplified spontaneous emission (ASE).     

PROGRESSIVE DAMAGE ARREST MECHANISM IN TAILORED LAMINATED PLATES WITH A CUTOUT

This study addresses the effectiveness of a simple stiffness tailoring concept to delay damage initiation, control damage progression, and improve residual strength in tensile-loaded composite plates with a central circular cutout. The tailoring concept is to simply reposit all axially oriented （0°） material into regions near the edge of the plate away from the cutout. This tailoring is done in a way so as not to affect the weight of the plate. This accomplishes several beneficial changes in the way that the plate resists loading with no increases in material cost or weight. Lowering the axial stiffness of the laminate surrounding the cutout lowers the stress concentration. Increasing the axial stiffness near edges of the plate attracts loading away from the vicinity of the cutout to further lower stresses in the critical cutout region. This study focuses on in-plane response including damage progression and residual strength as a function of the degree of tailoring and cutout size. Strength and stiffness properties typical of IM7/8551-7 preperg material were assumed and a modified version of the Hashin failure criteria was used to identify the local damage. Results show that tailoring can significantly increase the damage initiation load and the residual strength. In some cases, observed evidence shows that tailoring performs as a damage arrest mechanism.     

一种基于数字全息技术的盲音频水印算法

提出了一种基于数字全息技术的盲音频水印算法.水印图像经随机相位调制形成物光波,该物光波的傅里叶变换与参考光波发生干涉,形成傅里叶变换全息图.再利用离散余弦变换的能量压缩能力,通过量化算法把降维的水印,即傅里叶变换全息图嵌入音频信号中,在水印提取过程中不需要原始音频信号的参与.仿真实验表明,该算法对低通滤波、噪音干扰特别是剪裁具有一定的稳健性.     

从玻尔假说到发光原理

光是电磁波,发光即产生电磁波或光辐射,发光物理是发光材料创新设计和应用的理论基础.本文从玻尔假说出发,通过分析真空中和非真空中的孤立原子的能级和各类跃迁阐述发光的基本原理,通过分析非孤立原子激发态的能量传递阐述量子剪裁发光和上转换发光物理机制,通过介绍与发光有关的诺贝尔奖让学生了解该领域的最新进展,实现大学物理教学中从基础到前沿的跨越.     

加入WTO后我国稀土发光材料面临的机遇和挑战

对加入WTO后,我国在量子剪裁和真空紫外光谱（PDP）,发白光LED,稀土掺杂玻璃和光纤,长余辉荧光粉及稀土有机荧光材料等方面所面临的机遇和挑战进行评述。     

有机金属烯烃配位聚合催化剂

有机金属烯烃配位聚合催化剂具有高催化活性和良好的分子剪裁性,通过调节催化剂的微结构,如配体的取代基?配位原子以及配位中心的电子与立体环境等,可以在分子层次上实现烯烃聚合物的分子设计与组装;实现聚合物物理性质的调控,从而得到各种具有新型功能和立体异构的聚合物。本文综述了金属烯烃聚合催化剂研究进展,并展望该领域的发展趋势。