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971.
972.
《Analytica chimica acta》2002,459(2):229-234
The ligand 1,4,8-tri(n-octyl)-1,4,8,11-tetraazacyclotetradecane (L1) containing pendant octyl groups has been synthesised. L1 is a tetraazamacrocycle derived from the well-known cyclam unit, and the Ni2+ and Co2+ complexes, [Ni(L1)]2+ and [Co(L1)]2+, have been isolated and characterised. The ability of the nickel(II) and cobalt(II) complexes to act as anion receptors has been studied by using them as ionophores in membrane-based ion-selective electrodes (ISEs). The PVC membrane containing the complex [Ni(L1)]2+ and 2-nitrophenyloctylether as plasticizer shows a Nernstian response against iodide in a concentration range from 1×10−1 to 4×10−5 M I− with a detection limit of 1.6×10−5 M I− and a slope of 58.6 mV/pI− at pH 7 (25 °C). In comparison, the electrode containing [Co(L1)]2+ as ionophore gave a sub-Nernstian slope and a low lifetime. A comparison between the iodide-selective electrode containing [Ni(L1)]2+ and other reported iodide-selective electrodes is also reported. 相似文献
973.
Tatsuro Ouchi Hidetake Miyazaki Hidetoshi Arimura Fumitaka Tasaka Atsushi Hamada Yuichi Ohya 《Journal of polymer science. Part A, Polymer chemistry》2002,40(10):1426-1432
Amphiphilic AB‐type diblock copolymers composed of hydrophobic poly(L ‐lactide) (PLA) segments and hydrophilic poly(glycolic acid lysine) [poly(Glc‐Lys)] segments with amino side‐chain groups self‐associated to form PLA‐based polymeric micelles with amino surfaces in an aqueous solution. The average diameter of the loose core–shell polymeric micelles for poly(Glc‐Lys) [number‐average molecular weight (Mn) = 1240]‐b‐PLA (Mn = 7000) obtained by a dimethyl sulfoxide/water dialysis method was estimated to be about 50 nm in water by dynamic light scattering measurements. The size and shape of the obtained polymeric micelles were further observed with transmission electron microscopy and atomic force microscopy. To investigate the possibility of applying the obtained PLA‐based polymeric micelles as bioabsorbable vehicles for hydrophobic drugs, we tested the entrapment of drugs in poly(Glc‐Lys) (Mn = 1240)‐b‐PLA (Mn = 7000) micelles and their release with doxorubicin as a hydrophobic drug. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 1426–1432, 2002 相似文献
974.
Alternative Ligands. XXII. Rhodium(I) complexes with Donor/Acceptor Ligands of the Typs Me2PCH2CH2SiXnMe3?n(X = F, Cl, OMe) Donor/acceptor ligand of the type Me2PCH2SiXnMe3?n react with [Rh(CO)2Cl]2 ( 1 ) to give the mononuclear complexes RhCl(CO)(PMe2CH2CH2SiXnMe3?n)2 ( 2-6 , Table 1) with planar geometry of the donor atoms, one exception being Me2PCH2CH2CH2SiCl3, yielding the crystalline RhIII-complex RhCl2(CO)(PMe2CH2CH2SiCl2)(PMe2CH2CH2SiCl3) ( 7 ) by oxidative addition of one of the SiCl bonds to the Rh1 precursor. Structures with Rh → Si interaction between the basic central atoms and the acceptor group SiXnMe3?n could be detected in the isolated products neither spectroscopically nor by X-ray diffraction of the two representatives RhCl(CO)(PMe2CH2CH2SiF3)2 ( 2 ) and RhCl(CO)[PMe2CH2CH2siF3]2 ( 2 ) and RhCl(CO) [PMe2CH2CH2Si(OMe3]2 ( 6 ). The presence of such acid/base adducts in the reaction mixture is indicated for the more acidic acceptor groups SiXnMe3?n byvco values near 1990cm?1, (see Table 3). The complex RhCl(CO)PMe3)(PMe2CH2CH2SiF3 ( 8 ) is obtained by the reaction of RhCl(CO)(PMe3)2 ( 9 ) with Me2PCH2SiF3 and has been identified spectroscopically in a mixture with 2 and 9 . 相似文献
975.
The conditions of formation and some properties of yttrium and lanthanide benzohydroxamates were studied.
Simultaneous TG-DTG-DTA studies under non-isothermal conditions were carried out in air atmosphere in the temperature range
20-1000°C. The IR spectra and X-ray patterns of some thermal decomposition products were recorded.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
976.
trans-RhCl(CO)(TPPTS)2 (TPPTS=tris(m-sulfonatophenyl)phosphine) has been intercalated into Zn-Al layered double hydroxides (LDHs) by the method of ion exchange. The structure, composition and thermal stability of the composite material have been characterized by powder X-ray diffraction, Fourier transform infrared and 31P solid-state magic-angle spinning nuclear magnetic resonance spectroscopy, elemental analysis, thermogravimetry, and differential thermal analysis. The geometry of trans-RhCl(CO)(TPPTS)2 was fully optimized using the PM3 semiempirical molecular orbital method, and a schematic model for the intercalated species has been proposed. The thermal stability of trans-RhCl(CO)(TPPTS)2 is significantly enhanced by intercalation, which suggests that such materials may have prospective application as the basis of a supported catalyst system for the hydroformylation of higher olefins. 相似文献
977.
JiangBinXIA FuYouLI ShuMingYANG ChunHuiHUANG 《中国化学快报》2004,15(5):619-622
Composite nanoporous electrode SnO2/TiO2 was fabricated for the dye sensitized solar cell (DSSC) with N3 (Cis-Ru). After introducing of TiO2, the open-circuit photovoltage (Voc) was higher than that of the pure SnO2 electrode, while short-circuit photocurrent (Isc) was varied with the ratio of the TiO2. Appropriate content of the TiO2 can be beneficial to the efficiency of the solar cell, and it gives negative impact on the composite electrode when the content of TiO2 is higher. 相似文献
978.
Benchmarking of ruthenium initiators for the ROMP of a norbornenedicarboxylic acid ester 总被引:1,自引:0,他引:1
Sandra Demel Wolfgang Schoefberger Christian Slugovc Franz Stelzer 《Journal of molecular catalysis. A, Chemical》2003,200(1-2):11-19
The kinetic study of ring-opening metathesis polymerization (ROMP) of a diester functionalised norbornene derivative, (±)-exo,endo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid diethyl ester, with a series of ruthenium benzylidene complexes revealed the applicability of these initiators for well defined polymerization reactions. Values for the rate of initiation as well as the rate of propagation of the initiators were determined and correlated to the molecular weight and polydispersity of the isolated polymers. As the only initiator providing an entry to virtually monodisperse polymers the classical “first generation Grubbs-catalyst” was identified, while N-heterocyclic carbene based initiators polymerized with a rate of propagation much higher than the rate of initiation yielding polymers with a broader molecular weight distribution. 相似文献
979.
Thanner H. Krempl P. W. Selic R. Wallnöfer W. Worsch P. M. 《Journal of Thermal Analysis and Calorimetry》2003,71(1):53-59
Quartz-homeotypic gallium (ortho-) phosphate, GaPO4, is of special interest for resonator applications asking for temperature compensated cuts with higher electro-mechanical coupling than quartz and operational temperatures up to 970°C. The crystal microbalance technique, well known for quartz (QCM) which can be used only at moderate temperatures, can now be extended to much higher temperatures using GaPO4 crystals, benefiting from all three advantages mentioned above. Two different experiments were done to demonstrate the advantages of a crystal microbalance based on GaPO4. First, the GaPO4 resonator was used for film thickness determination and compared with a commercial QCM. This experiment demonstrated that the measuring range can be extended by using GaPO4 resonators instead of quartz. The second experiment demonstrates the possibility for thermogravimetric analysis up to 720°C by using a new concept for resonator mounting.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
980.
Xiaoxia WangYongmin Zhang 《Tetrahedron》2003,59(23):4201-4207
N-Acylbenzotriazoles, when treated with samarium diiodide in THF, undergo self-coupling reaction to afford 1,2-diketones in good to excellent yields; while when treated with samarium diiodide in CH3CN, they undergo ring-opening reaction to afford 1-acylamido-2-alkyl (or aryl) benzimidazoles in reasonable to good yields. A plausible mechanism was suggested. 相似文献