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111.
The first synthesis of the fungal natural product (−)-xylariamide A 1 is reported. N,O-Bis(trimethylsilyl)acetamide induced coupling of d-tyrosine with (E)-but-2-enedioic acid 2,5-dioxo-pyrrolidin-1-yl ester methyl ester 5 produced the dechloro natural product 6, which was subsequently monochlorinated using oxone and KCl to yield synthetic 1. (−)-Xylariamide A 1, (+)-xylariamide A 2 and (−)-dechloroxylariamide A 6 displayed no cytotoxic or antimicrobial activity. 相似文献
112.
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113.
Silicon nitride powders were synthesized in an atmospheric-pressure convection-stabilized arc using silicon and ammonia as reactants. The morphology and particle size distributions of the silicon nitride particles were characterized by SEM, TEM, and electron diffraction analyses. The silicon nitride particles collected in the plasma reactor were formed by either gas-condensed phase reactions or chemical vapor reactions. The morphologies of the particles formed by gas-condensed phase reactions consisted of -Si3N4 prisms, -Si3N4 matte, -Si3N4 needles, and spaghetti-like whiskers. For the homogeneously nucleated particles, the morphologies included dendrites, needles, platelets, and amorphous particles. Most of the particles formed were aggregates with particle size distributions ranging from 500 to 1500 Å depending on the location of injection of the reactants. 相似文献
114.
CHANG Nein Chen DAY Huo-Muh CHIU Chih-Tsao CHANG Chi-Peng HSU Lung-Fu Department of Chemistry National Sun Yat-Sen University Kaohsiung Taiwan 《有机化学》1993,(2)
Approaches toward the synthesis of iridoids and 9-isocyanopupukeanane starting from cy-clopentadiene are discussed. 相似文献
115.
116.
The mechanism of the radiation-induced conversion of ammonia to nitrites and nitrates in aerated aqueous solutions has been studied. The formation of the pernitrite ion, O=N-O-O–, was detected at pH 10.5. The kinetics of its formation and decay were studied, andk
form was estimated at (2.3±0.2)·107 L mol–1 s–1. The course of decay obeys first-order kinetics; the rate constant decreases at higher pH. Radiochemical yields of pernitrite, nitrite and nitrate at various pH and initial NH3 concentrations were determined. A mechanism of ammonia oxidation in aqueous solution is proposed.Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 280–283, February, 1993. 相似文献
117.
118.
高效液相色谱法测定水产品中的恶喹酸 总被引:3,自引:0,他引:3
建立了高效液相色谱法测定水产品中恶喹酸残留量的方法。样品用二氯甲烷提取后,除去溶剂,用稀盐酸和正己烷处理,去除残渣中的脂肪,再用二氯甲烷萃取,浓缩至干后用甲醇定容。以0.002mol/L磷酸溶液-乙腈-四氢呋喃(体积比为65:20:15)为流动相,在ODS反相色谱柱上分离后,用荧光检测器测定,外标法定量。方法的线性范围为5-5000ng/mL,线性回归方程为A=9.426c-2.123,相关系数r=0.9988,检出限为1μg/kg,回收率为93.0%-96.0%,相对标准偏差为3.7%-6.2%。 相似文献
119.
Oliveira SC Paiva TC Visconti AE Giudici R 《Applied biochemistry and biotechnology》1998,74(3):161-172
Discrimination between different rival models for describing the inhibitory effect of ethanol both on yeast growth and on
fermentation was studied for a continuous process of alcoholic fermentation in a tower reactor with recycling of flocculating
cells. Models tested include linear, parabolic, hyperbolic, exponential, and generalized nonlinear power-law types. The best
expressions were identified under the criteria that all the kinetic parameters should assume acceptable values in a feasible
range and should result in the best fit of the experimental data. The kinetic parameters were estimated from steady-state
data of several sugar concentrations in feeding stream (S0 = 160, 170, 180, 190, 200 g/L), constant dilution rate (D = 0.2 h-1), recycle ratio (α = 13.6), and temperature (T = 30°C). The best model for the yeast growth was of power-law type, whereas
for the product formation the best model was of linear type. These models were able to reproduce the trends of the process
variables satisfactorily. 相似文献
120.
Corrado Di Natale Manuela Zude-SasseAntonella Macagnano Roberto PaolesseBernd Herold Arnaldo D’Amico 《Analytica chimica acta》2002,459(1):107-117
Visual aspect and aroma are among the most important features of fruit that determine consumer preferences. Electronic nose and spectroscopic techniques have shown positive results in evaluating some basic analytical parameters of fruit and global features such as the cultivar.In this paper, we illustrate and discuss a study aimed at evaluating the improvement derived by the fusion of visible spectra and electronic nose data. These experiments were performed on a population of yellow peaches belonging to two cultivars. Each sample was measured by visible optical spectroscopy and by electronic nose. In addition, a number of reference parameters were also measured by conventional destructive methodologies.Collected data were analysed individually and then fused together in order to classify the two cultivars and to estimate the reference parameters. Data fusion was performed building the outer product matrix for each measurement. The set of matrices was then successively unfolded and analysed by conventional chemometrics tools.Results were improved using outer products, for instance in classification average percentage errors of 25, 10, and 7 for electronic nose, spectra, and outer product, respectively was achieved. Regression analysis provides the evidence of a substantial orthogonal appearance of the datasets, which offer former hidden information on fruit classification. 相似文献