Extension of the Method of Moments in Nonlinear Free Radical Polymerization

The method of moments is a simple, efficient method simulating polymerization processes. Its use is said to be limited in nonlinear free radical polymerizations with branching or crosslinking due to the assumptions needed. Here, moment equations are derived without assuming steady state, one radical per molecule, or a statistical distribution of connections. Equations are valid up to the gel point. The bulk solution is formally identical to the pseudo kinetic approach by Tobita and Hamielec if moments of dead polymer are replaced by the sum of dead and life polymers. The method relies on analytical solutions of the moments of the molecular weight distributions (MWD) of instantaneous primary chains. In emulsion polymerization compartmentalization of radicals complicates the calculation. An alternative approximation of these MWDs is presented. The present extension allows nonlinear free radical polymerization to be readily included in the computer based design and optimization of polymerization processes and to check more detailed calculations of the MWD.

     

结合àtrous算法与Retinex算法的医学图像增强

提出结合àtrous算法与Retinex算法的医学图像增强.方法在二进小波理论基础上,利用推广的二维àtrous算法对医学图像进行处理,对经过多级分解后的医学图像的低频利用连续非线性函数增强,而对分解后的多个高频采用改进的Retinex算法进行增强;最后,对增强后的低频和高频进行重构.经过反复仿真试验结果表明:方法在去除噪声的同时更好地保留了图像边缘特征,增强了图像细节信息和凸显图像的轮廓,并克服对比度下降的不足,较好地去除光晕现象,视觉效果好,层次感更丰富.     

一类奇异非线性多重调和方程存在正整解的充分必要条件

研究一类奇异非线性多重调和方程?~mu=f(|x|,u,|▽u|)u~(-β),给出了方程存在正的径向对称整体解的充分必要条件和解的性质.     

不同类型专利对经济增长影响的实证研究

文章考察三种不同类型专利对经济增长的影响,结合广东省1985-2014年最新数据,通过Matlab、Excel软件对数据进行图像模拟,并根据函数理论、计量经济学理论,创造性地构建一种多元非线性计量模型。进一步地,运用所得模型进行实证分析,结果显示发明专利在经济增长中产生的影响远大于实用新型专利和外观设计专利,论证了原创性创新在现阶段广东省经济转型升级中的核心作用。     

天然气稳态运行优化的混合整数模型及其算法

天然气稳态运行优化问题的难点在于网络结构复杂、规模大、目标函数及约束高度非线性.针对其混合整数非线性规划模型,基于网络约简和线性化技术,建立了线性近似模型,并提出一种新的求解算法.将新算法用于优化我国西部天然气管网系统,结果表明所提算法是有效的.     

非线性半定规划的逐次线性化柔性惩罚法

针对非线性不等式约束半定规划问题提出一种新的逐次线性化方法, 新算法既不要求罚函数单调下降, 也不使用过滤技巧, 尝试步的接受准则仅仅依赖于目标函数和约束违反度, 罚函数中对应于成功迭代点的罚因子不需要单调增加. 新算法或者要求违反约束度量有足够改善, 或者在约束违反度的一个合理范围内要求目标函数值充分下降, 在通常假设条件下, 分析了新算法的适定性及全局收敛性. 最后, 给出了非线性半定规划问题的数值试验结果, 结果表明了新算法的有效性.     

Solitons and other solutions to a new coupled nonlinear Schrodinger type equation

In this paper, the first integral method combined with Liu's theorem is applied to integrate a new coupled nonlinear Schrodinger type equation. Using this combination, more new exact traveling wave solutions are obtained for the considered equation using ideas from the theory of commutative algebra. In addition, more solutions are also obtained via the application of semi-inverse variational principle due to Ji-Huan He. The used approaches with the help of symbolic computations via Mathematica 9, may provide a straightforward effective and powerful mathematical tools for solving nonlinear partial differential equations in mathematical physics.     

Second‐Order Nonlinear Optical Dendrimers and Dendronized Hyperbranched Polymers

Abstract : Second‐order nonlinear optical (NLO) dendrimers with a special topological structure were regarded as the most promising candidates for practical applications in the field of optoelectronic materials. Dendronized hyperbranched polymers (DHPs), a new type of polymers with dendritic structures, proposed and named by us recently, demonstrated interesting properties and some advantages over other polymers. Some of our work concerning these two types of polymers are presented herein, especially focusing on the design idea and structure–property relationship. To enhance their comprehensive NLO performance, dendrimers were designed and synthesized by adjusting their isolation mode, increasing the number of the dendritic generation, modifying their topological structure, introducing isolation chromophores, and utilizing the Ar‐Ar^F self‐assembly effect. To make full use of the advantages of both the structural integrity of dendrimers and the convenient one‐pot synthesis of hyperbranched polymers, DHPs were explored by utilizing low‐generation dendrons as big monomers to construct hyperbranched polymers. These selected works could provide valuable information to deeply understand the relationship between the structure and properties of functional polymers with dendritic structures, but not only limited to the NLO ones, and might contribute much to the further development of functional polymers with rational design.