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91.
Experimental investigations of superconductivity effects in single-phase and multiphase Bi2Sr2CaCu2O8 single-crystals have been carried out at 142 GHz frequency by means of the standing wave profile method [1]. Josephson harmonic generation has been observed to be responsible for the appearence of additional peaks on the standing wave profile of the open dielectric resonator loaded with a properly orientated multiphase high-Tc superconductor specimen. This leads to the conclusion that most of the Josephson junctions in multiphase crystals are located in certain crystallographic planes. The investigations of temperature dependencies showed that sharp resonant peaks of conductivity observed earlier [2] at 60 GHz could also be observed at 142 GHz.  相似文献   
92.
In this short note we present results on the existence of several classes of travelling, non-periodic solutions of the complex Ginzburg-Landau equation. First we give a very short introduction to the G-L equation and show its importance in nonlinear stability theory. We then study the G-L equation with complex coefficients and establish the existence of a 2-parameter family of quasi-periodic solutions and two different types of one-parameter families of heteroclinic orbits; all members of these families travel with a well-defined wave-speed. The heteroclinic solutions correspond to (travelling) soliton-like localized structures which connect different (stable) periodic patterns. Mathematically, these families of travelling solutions (quasi-periodic and heteroclinic) are continuations into the complex case of the stationary solutions of the real G-L equation.  相似文献   
93.
 Some comb-like polythiiranes with PEO side chains were prepared from the corresponding macromonomers. These new materials are amphiphiles and act as surfactants. Their surface tension and interfacial tension are measured and studied in this paper on account of their structures. The lowering of surface tension measured in polymers bearing methyl terminal group in PEO side chains, are in the same range as these observed with polymers of identical structures but different main chains. An increase of the hydrophobic units in the main chain, obtained in copolymers with methylthiirane does not significantly modified the surface tensions. Better lowering is afforded with structures bearing large alkyl groups as terminal group of PEO side chains. On the contrary, some of these macro-molecules with an optimized EO content largely lower the water/xylene surface tension. The main interest of these new materials is their very low cmc and the stabilization of L1-type microemulsions. Received: 20 May 1997 Accepted: 25 November 1997  相似文献   
94.
One to three endothermal peaks atributted to melting of bulk and interfacial water were observed by DSC in the regenerated cellulose — water system. The profiles of thermal effects depend on water content, time of conditioning, film pretreatment and the conditions applied during the preceding freezing-thawing cycles. The occurrence might be deduced of melting-crystallisation processes. A large amount of non-freezable strongly bounded water was also detected. Although cellulose absorbs water quickly after immersion, the structural changes consisting on ordering of polymer fraction occur during further conditioning due to increase in strength of water binding. Using the membranes in the separation module at 90°C causes weakening of these bonds. Differences between interaction of particular cellulose films with water can be detected during the first, the second and the third heating. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
95.
The dynamics of the Josephson tunnel junction is approximately described by a perturbed sine-Gordon equation. The Josephson tunnel junction is thus a convenient experimental solid state device for the study of solitons and solitonlike phenomena. The physical manifestation of the soliton is a propagating magnetic flux quantum ( 0=h/2e=2.064×10–15 V sec). Basic properties of the soliton and its relation to observable experimental quantities (zero field steps, microwave radiation, etc.) are reviewed. Recent direct measurements of the actual soliton profile are also mentioned.  相似文献   
96.
原油乳状液稳定性和破乳研究进展   总被引:14,自引:0,他引:14  
本文从控制乳状液稳定性的一些因素-界面膜、界面张力、双电层、空间位阻、固体粒子、液晶、油相溶解度、连续相粘度等方面综述了有关乳状液稳定性的一些研究进展。对国内外有关原油乳状液的破乳研究也做了综述。同时,介绍了应用于乳状液稳定性研究的新的实验技术和仪器。  相似文献   
97.
何义娟  李克丽  李倩  张鹏  艾萍  袁黎明 《色谱》2019,37(4):383-391
万古霉素和替考拉宁都属于糖肽类的大环抗生素,具有立体的环状结构和多个手性中心,是两种常见的手性识别材料,广泛应用于对映体的色谱手性分离分析。该文以万古霉素和替考拉宁为手性选择剂,哌嗪为单体,4,4'-二苯基甲烷二异氰酸酯(MDI)、1,6-己二异氰酸酯(HDI)和2,4-甲苯二异氰酸酯(TDI)为交联剂,通过界面聚合反应形成网状层包裹硅胶载体的方法制得6种高效液相色谱手性固定相,用于分离外消旋化合物,并与MDI直接交联万古霉素和替考拉宁在硅胶表面所得固定相进行了比较。结果表明,利用"网包法"和直接交联法制备的手性柱与商品万古霉素和替考拉宁柱之间具有互补性,均对不同的外消旋体有不同程度的拆分。  相似文献   
98.
The growth ofBacillus amyloliquefaciens in the aqueous two-phase system, made up of polyethylene glycol, dextran, and water, was investigated. Generally,Bacillus partitions in the dextran phase, but the magnitude of the separation depends largely on the overall composition of polymers in the phase system. The kinetics of growth ofBacillus amyloliquefaciens was studied in the polyethylene glycol-rich continuous phase, dextran-rich dispersed phase, and in the mixed phase. From the kinetic data it appears that increasing the overall polymer composition causes the cells to adsorp at the interface. On the other hand, partition measurements indicate that increasing polymer concentrations make the cell partitioning more one-sided. This anomaly is explained by studying the interfacial adsorption of cells via dynamic surface tension measurements.  相似文献   
99.
Asbestos fibers, of the chrysotile variety, were coated with a thin polyamide film by an in situ polycondensation technique. Ionomer-based composites were prepared containing the so-modified asbestos fibers in a random in-plane orientation; results of testing the tensile properties of these asbestos/polyamide/ionomer composites are presented. Parameters investigated comprise the asbestos content in the composite and the polyamide content deposited on asbestos. A significant improvement in the tensile performance was established, especially at the intermediate polyamide content of 3.4 phr. The behavior is discussed in terms of possible interactions between the phases present in the composite material.  相似文献   
100.
郭荣  魏逊  刘天晴 《中国化学》2005,23(4):393-399
In the system of SDS/n-C5H11OH/n-C7H16/H2O with the weight ratio of SDS/n-C5H11OH/H2O system at5.0/47.5/47.5, the upper phase of the system was W/O microemulsion, and the lower phase was the bicontinuous microemulsion. When the n-heptane content was less than 1%, with the increase of the n-heptane content, the capacitance (Co, Cod) in the upper phase (W/O) dropped, the capacitance (CB1, CBld) in the lower phase (BI) raised. At the same time, the W/O-BI inteffacial potential (ΔE), capacitance (Ci), and charge-transfer current (ict) decreased.After the n-heptane content reached 1%, with the increase of the n-heptane content, ΔE, Ci and ict demonstrated no significant change.  相似文献   
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