Rapid separation and simultaneous quantitative determination of 13 constituents in Psoraleae Fructus by a single marker using high‐performance liquid chromatography with diode array detection

Psoraleae Fructus is one of the most popular traditional Chinese medicines. Coumarins, flavonoids, and meroterpenes are the main contributors to the biological activity of Psoraleae Fructus. In this study, a new method for the quality control of Psoraleae Fructus was developed, through the quantitative analysis of multicomponents by single marker with diode array detector. Thirteen components, including psoralenoside, isopsoralenoside, psoralen, isopsoralen, psoralidin, neobavaisoflavone, bavachin, corylin, isobavachalcone, corylifol A, bavachinin, bavachalcone, and bakuchiol were rapidly separated and identified within 12 min by the newly developed method. The feasibility and reliability of this method were corroborated. The method was also compared to the external standard method and detection by corona charged aerosol detector. The results of percent difference (%) and cos (θ) have shown that there were no significant differences observed between the quantitative analysis of multicomponents by single marker and external standard method analyses; psoralen and isopsoralen were undetectable with the corona charged aerosol detector due to their but the sensitivity for all the compounds except bakuchiol detected by corona charged aerosol detector are higher than those obtained by diode array detector. In addition, the newly method developed was applied to the quality evaluation of Chinese patent medicines containing Psoraleae Fructus.     

Directly‐coupled‐column ultra‐fast liquid chromatography with diode array detection method for the rapid quantification of allergenic disperse dyes in water preconcentrated by magnetic solid‐phase extraction

A directly‐coupled‐column ultra‐fast liquid chromatography coupled with diode array detection method for the determination of 12 allergenic disperse dyes in river water at sub‐ppb levels has been developed and successfully validated. The analytical method is based on the use of two different reversed‐phased columns connected through a two‐position switching valve. A baseline separation was achieved by proper selection of stationary phases, mobile phases, and the use of a gradient elution in both dimensions. Furthermore, an easy‐to‐handle magnetic solid‐phase extraction procedure was developed for the preconcentration of 12 allergenic disperse dyes from river water. An enrichment factor of 100 times was obtained. The results showed excellent performance in terms of trueness (76.8–99.0%), precision (intraday: 2.2–8.0%, interday: 3.3–8.2%), and sensitivity (limits of determination, 0.027–1.46 μg/L). Twenty real samples collected from the outfalls in the Yaojiang, Yongjiang and Fenghuajiang estuary were analyzed, and three of the studied compounds were found in one collected sample (12.6 μg/L for disperse blue 7, 11.6 μg/L for disperse blue 106, and 0.22 μg/L for disperse blue 3).     

Interaction of elastic waves with a periodic array of collinear inplane cracks

A boundary integral equation method is applied to the study of the interaction of plane elastic waves with a periodic array of collinear inplane cracks. Numerical results are presented for the dynamic stress intensity factors. The effects of the wave type, wave frequency, wave incidence angle, and crack spacing on the dynamic stress intensity factors are analyzed in detail. The project supported by the Committee of Science and Technology of Shanghai and Tongji University     

利用线弹簧模型计算含表面裂纹的板壳结构的复合型应力强度因子

本文将线弹簧模型推广应用于复合型应力强度因子的计算。将复合型线弹簧单元与ADINA程序相联接,便得到分析复杂结构物(特别是诸如管节点一类的空间相贯体结构)中所含表面裂纹的复合型应力强度因子程序。算例表明:该方法具有较高的计算效率而又能满足工程分析的精度要求。     

Determining stress intensity factors in orthotropic composites from far-field measured temperatures

We demonstrate the ability to determine stress intensity factors in orthotropic materials directly from measured temperatures away from the crack and using far-field expressions for the stresses. This is advantageous, recognizing that recorded thermoelastic data can be very unreliable near the tip of a crack. In addition to singular terms that govern in the immediate vicinity of the crack tip, the present series expressions for the stresses contain higher-order finite terms. Little measured input information is needed and data acquisition positions can be selected largely at the user's discretion.     

压荷载下类岩石材料中的锯齿形裂纹分析

针对类岩石材料的复杂性和非均质性，特别是材料中一些强度相对较弱的晶界的存在等，对形状较为复杂的两种锯齿形裂纹：内张型滑动裂纹和单翼滑动裂纹的应力强度因子进行了分析．结合经典的滑动裂纹模型，讨论了裂纹起裂角、侧压以及翼裂长度等对应力强度因子的影响．分析的结果为进一步研究类岩石材料的断裂损伤机理提供了理论基础．     

压-剪复合应力波作用下材料动态断裂韧性研究

提出亚微秒单脉冲应力波载荷作用下Ⅱ型裂纹的平板冲击实验技术 .加载率为dK dt～ 10 8MPa·m1 2 ·s-1.实验中由锰铜应力片和弹性波理论分别测定和计算了压应力 ;通过微观分析确定了动态裂纹的平均扩展长度 ;引进等效应力强度因子 ,用动态断裂理论确定了 6 0 #钢的动态断裂韧性KⅠd和KⅡd ;建立了亚微秒冲击载荷作用下确定材料动态断裂韧性的方法     

三维间断位移法及强奇异和超奇异积分的处理方法

从积分方程Somigliana等式出发,导出三维状态下单位位错集度的基本解.在此基础上,建立了边界积分方程,并给出了其离散形式.对强奇异和超奇异积分,采用了Hadamard定义的有限部分积分来处理.最后,给出了计算裂纹应力强度因子的算例,并与解析解进行了比较,证实了该方法的有效性.     

孔压静力触探(CPTU)测试成果影响因素及原始数据修正方法探讨

孔压静力触探(CPTU)是20世纪80年代在国际上兴起的新型原位测试技术,因其诸多优点,目前在欧美诸国已得到广泛应用。由于探头规格、技术标准和操作程序的差异,影响CPTU测试成果的因素很多,而且其影响程度也各不相同。根据前人的研究成果,对CPTU测试成果的影响因素进行了分析总结,以期在CPTU资料整理和应用中引起重视。最后,简要论述了考虑诸多影响因素的原始数据修正方法。     

大空间三向组合平板网架研究

利用中心节点、交叉梁、三角形拉杆和空心板所构成承力单元的组合以及内部支承柱的自由布置,本文提出了一种新型大空间三向组合平板网架结构。相关的TDGS分析系统针对原型试验取得了较好的模拟效果。通过引入柱的局部影响区域这一全新概念,系统总结了加入内部支承柱前后网架结构的内力和变形规律,进而为进一步的工程应用提供了可行性建议。