Studies on the Structure and Properties of Cordierite Synthesized by Talc-Magnesite

Homogeneous cordierite has been synthesized at low cost by talc-magnesite and coal gangue as the main raw materials. The mechanism of synthesizing cordierite under such a com- posing system of raw materials, and the effect of temperature on the crystal cell parameters and microstructure and thermal expansion coefficient of cordierite crystal have been studied via testing methods of XRD, SEM, etc. The result shows that the homogeneous cordierite can be synthesized by the systematic composing materials of “talc-magnesite—coal gangue—talc” with heat pre- servation at 1350 ℃ for 1 h; as the keeping time is prolonged, Al3+ and Mg2+ in cordierite crystal are replaced by a few impurity ions such as Fe3+, Fe2+, etc., and the crystal cell parameters of cordierite present an increase trend; as the high-temperature heat preservation is prolonged, the content of glassy phase in the sample is increased, its density is improved, and its thermal expansion coeffi- cient presents an increase trend.     

新的酰胺型开链冠醚的合成与性质

Simon在70年代开发了一类酰胺型开链冠醚,能选择性配位碱土金属离子并可作为中性载体制备离子选择性电极.由于酰胺型开链冠醚易于制备,因此受到人们广泛地重视.Vgtle等提出的“末端基”概念为开链冠醚的合成、设计起了重要的指导作用.前文报道2-甲氧基-1-氨甲基萘与三甘醇二碘化物在无水碳酸钠存在下于乙腈中反应得到双手臂的套索冠醚与碘化钠的配合物.X射线衍射晶体结构分析表明萘环上的甲氧基中的氧原子参加了与钠离子的配位,生成了扭曲的六边形双锥结构配合物.因此2-甲氧基-1-氨基萘可以作为开链冠醚的“末端基”.开链冠醚的合成路线是:     

Thermal coefficient of linear expansion of non-crystalline chalcogenides in the As-S-Se-Te-I system

The object of the paper is an investigation of the glasses of the (As₂S₃)_x(AsSe_0.5Te_0.5I)_100-x. type for 65≤;x≤;95, using methods of thermomechanical analysis. Values of the thermal coefficients of linear expansion in solid and visco-plastic phase were determined. it was shown that introducing arsenic-sulfide in glass-matrix AsChI, i.e. (AsSe_0.5Te_0.5I), leads to an increasing stability of these glasses. The characteristic temperatures of softening Tg and the temperature of the beginning of deformation t_w increase by increasing content of As₂S₃. The analytical forms of dependence of four significant physical values α_g, α_l, Tg, Tw, as a function of As₂S₃ content in the structure of glasses were fitted. This revised version was published online in July 2006 with corrections to the Cover Date.     

LiCoO2中锂离子固相扩散系数随循环次数的变化

The solid diffusion coefficient of lithium-ion in LiCoO₂ cathode material has been investigated by the capacity intermittent titration technique (CITT) at different voltages and at different charge/discharge cycles. By SEM, XRD and FTIR techniques, the structure of LiCoO₂ was studied before and after charge-discharge cycles, and the relationship between solid diffusion coefficient and crystal structure was further discussed. CITT results show that the value of Li⁺ solid diffusion coefficient of LiCoO₂ is about 10^-12 cm²·s^-1. During the whole charge-discharge cycles, the Li⁺ solid diffusion coefficient decreased within the voltage of 4.0～4.3 V, which is attributed to the change of the structure of LiCoO₂.     

WS2 超细粉体的固相法合成

WS2 超细粉体的固相法合成;WS2;固相反应;过硫系数;高能球磨;粒度     

Freezing temperatures and densities of solutions of some hydrocarbons and sodium oleate inN-methylacetamide. Evidence for a solvophobic interaction

The freezing temperatures and densities (at 31°C) of solutions of octane, nonane, decane, 3,3-diethylpentane, and sodium oleate inN-methylacetamide (NMA) have been measured. The molality of the freezing solution was calculated from the density. The solubilities of octane, nonane, and decane inN-methylacetamide are also reported. Apparent molal volumes calculated from the densities are close to the values in the pure hydrocarbons and are not strong functions of the concentration. This indicates the absence of any unusual packing effect. The calculated free energies of transfer of the hydrocarbons from pure hydrocarbon to NMA solution are much less negative than the corresponding values for water, showing that the bulk solvophobic interaction inN-methylacetamide is smaller than in water. This is consistent with the freezing temperatures of sodium oleate which show that micelles do not form below 0.1 mole-kg^–1. The osmotic coefficients of the hydrocarbons calculated from the freezing temperatures showed negative deviations from ideality that were larger for the hydrocarbons with the higher molecular weights. Two estimates of the pairwise solvophobic interaction inN-methylacetamide indicate that it is also smaller than in water. The solvophobic effect in this solvent does not include the large entropy and enthalpy effects found in aqueous solutions.     

Diffusion in organic solvents: Interdiffusion coefficient of 1,1,2,2-tetrabromoethane

Interdiffusion coefficient have been measured for 1,1,2,2-tetrabromoethane in 21 organic solvents in order to ascertain the influence of shape, size, viscosity, nature and degree of branching, of the solvent molecules on transport properties. None of the existing correlations for diffusion in binary liquid systems appear to fit all the experimental data. Steric effects due to the solvent molecules are shown to be very important in the interpretation of the diffusion process.     

Averaged molecular weight of complex mixtures as determined by rapid measurements of diffusion

Summary The concept of a diffusion-averaged molecular weight, M_d is presented, and M_d is defined for polydisperse samples. It is shown via oligostyrene mixtures that M_d can be determined in 20 minutes with common chromatographic equipment. If M_d is measured and M_n or M_w is known, the polydispersity can be obtained.     

微铂电极上1-酰基二茂铁动力学参数的测定

本文合成并研究了１－酰基二茂铁在ＣＨ２Ｃｌ２中的伏安行为，测定了它们在ＣＨ２Ｃｌ２中不同支持电解质浓度时的扩散系数，并分明用Ｚ．Ｇａｌｕｓ和Ｋ．Ａｏｋｉ方法计算了两种状态下的电子迁移速率常数。讨论了取代基的诱导效应和共轭效应及其链长对１－酰基二茂铁的动力学性质的影响以及支持电解质及其浓度等因素对伏安曲线的影响。