| 微铂电极上1-酰基二茂铁动力学参数的测定 |
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| 引用本文： | 季斌,邰子厚,鞠.微铂电极上1-酰基二茂铁动力学参数的测定[J].无机化学学报,1996,12(3):260-266. |
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| 作者姓名： | 季斌 邰子厚 鞠 |
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| 作者单位： | 南京大学配位化学国家重点实验室, 配位化学研究所, 南京210093,南京大学配位化学国家重点实验室, 配位化学研究所, 南京210093,南京大学配位化学国家重点实验室, 配位化学研究所, 南京210093,南京大学配位化学国家重点实验室, 配位化学研究所, 南京210093 |
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| 基金项目： | 国家自然科学基金,江苏省自然科学基金 |
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| 摘 要： | 本文合成并研究了１－酰基二茂铁在ＣＨ２Ｃｌ２中的伏安行为，测定了它们在ＣＨ２Ｃｌ２中不同支持电解质浓度时的扩散系数，并分明用Ｚ．Ｇａｌｕｓ和Ｋ．Ａｏｋｉ方法计算了两种状态下的电子迁移速率常数。讨论了取代基的诱导效应和共轭效应及其链长对１－酰基二茂铁的动力学性质的影响以及支持电解质及其浓度等因素对伏安曲线的影响。
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| 关 键 词： | 微电极 酰基二茂铁 循环伏安法 扩散系数 |
| 收稿时间： | 9/2/1995 12:00:00 AM |
DETERMINATION OF KINETIC PARAMETERS OF 1-ACYLFERROCENE AT A PLATINUM MICROELECTRODE |
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| Ji Bin,Tai Zihou,Ju Huangxian and Li Chun.DETERMINATION OF KINETIC PARAMETERS OF 1-ACYLFERROCENE AT A PLATINUM MICROELECTRODE[J].Chinese Journal of Inorganic Chemistry,1996,12(3):260-266. |
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| Authors: | Ji Bin Tai Zihou Ju Huangxian and Li Chun |
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| Institution: | Strue Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry Nanjing Univercity, Nanjing 210093,Strue Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry Nanjing Univercity, Nanjing 210093,Strue Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry Nanjing Univercity, Nanjing 210093 and Strue Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry Nanjing Univercity, Nanjing 210093 |
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| Abstract: | A series of derivatives of fcrroccnc, 1-acylferrocene(FcX)were synthesized and their diffusion coefficient in dichloromethane solution at different concentrations of the electrolyte were determined by cyclic voltammetry. The electron transfer rate constant of FcX in differ-
cnt condition also calculated by methods of Z.Galus and K. Aoki respectively.The influence of both resonance and inductive effects as well as the length of alkyl chain, the concentration of the electrolyte on the voltammograms were discussed in detail. |
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| Keywords: | microelectrode 1-acylferrocene cyclic voltammetry diffusion coefficient electron transfer |
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