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61.
电势和浓度通过能斯特方程相互计算时,计算结果受对方数值误差的影响。本文通过误差传递和实例研究了这种影响。结果表明:浓度误差对电势计算值的影响小,而电势误差对浓度计算值的影响大;这种现象在电子转移数较多、电势较大时更加显著。浓度为计算目标时需要重视数值误差的影响,所以代入能斯特方程的电势值应该有足够精度,或者避免使用能斯特方程,而是通过平衡常数进行计算。电势为计算目标时,浓度误差的影响较小,因此可以通过近似手段估算浓度,然后代入能斯特方程,既简化计算,又保证精度。 相似文献
62.
Partial ionization cross section experiments have been carried out recently at the University of Innsbruck for three types of hydrocarbons, i.e. acetylene, ethylene and propene. Cross section data fits are generated and compared to the compilation of earlier experimental data summarized in the online database HYDKIN [www.hydkin.de]. New data fits are brought into a suitable form to be incorporated into the database. In order to illuminate underlying dissociation mechanisms the energy dependence of branching ratios above energies of 20 –30 eV is reviewed in light of the present results (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
63.
In this note, we present some results concerning the chromatic index, the total chromatic index, the adjacent vertex distinguishing chromatic index and the adjacent vertex distinguishing total chromatic index for double graphs. In particular, we study the double graphs of class 1 and of type 1. 相似文献
64.
A simple model for a set of integrate-and-fire neurons based on the weighted network is introduced. By considering the neurobiological phenomenon in brain development and the difference of the synaptic strength, we construct weighted networks develop with link additions and followed by selective edge removal. The network exhibits the small-world and scale-free properties with high network efficiency. The model displays an avalanche activity on a power-law distribution. We investigate the effect of selective edge removal and the neuron refractory period on the self-organized criticality of the system. 相似文献
65.
Based on the general theory of dislocation and kink, we have constructed the three kink models corresponding to the 1/2 (111){011} and 1/2 (111){112} edge dislocations (EDs) in bcc Fe using the molecular dynamics method. We found that the geometric structure of a kink depends on the type of ED and the structural energies of the atom sites in the dislocation core region, as well as the geometric symmetry of the dislocation core and the characteristic of the stacking sequence of atomic plane along the dislocation line. The formation energies and widths of the kinks on the 1/2 (111){011} and 1/2 (111){112} EDs are calculated, the formation energies are 0.05eV and 0.04eV, and widths are 6.02b and 6.51b, respectively (b is the magnitude of the Burgers vector). The small formation energies indicate that the formation of kink in the edge dislocation is very easy in bcc Fe. 相似文献
66.
67.
Oleg Bogopolski 《Geometriae Dedicata》2002,94(1):63-89
Let T be a closed surface. It is proven that any decomposition of 1(T,x) into an amalgamated product (or, more generally, into the fundamental group of a finite graph of groups) with f.g. edge group(s) is almost geometric. A problem of H. Zieschang is solved and the edge rigidity property is investigated. 相似文献
68.
用于投影显示的分色合色膜系的消偏振设计 总被引:3,自引:3,他引:0
由于斜入射时,光学薄膜存在一定的偏振效应,将产生S-和P-偏振光的光谱分离.在Philips棱镜系统中,分色合色膜系通常分色时对S-光应用,合色时则对P-光应用.从提高光能利用率、减少杂散光和增加系统对比度等因素综合考虑,要求分色合色膜系的S-和P-偏振光的分离尽可能小.新设计方法采用宽带法布里-珀罗薄膜干涉滤光片中心波长两侧的干涉带作为长波通或短波通截止滤光片,可实现S-和P-偏振分量的分离几乎为零. 相似文献
69.
Luy B Kobzar K Skinner TE Khaneja N Glaser SJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,176(2):282-186
For a desired range of offsets, universal rotations of arbitrary flip angle can be constructed based on point-to-point rotations of I(y) with half the flip angle. This approach allows, for example, creation of broadband or bandselective refocusing pulses from broadband or bandselective excitation pulses. Furthermore, universal rotations about any axis can be obtained from point-to-point transformations that can easily be optimized using optimal control algorithms. The construction procedure is demonstrated on the examples of a broadband refocusing pulse, a broadband 120(x) degrees rotation and a z-rotation with offset pattern. 相似文献
70.
G Budak 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,88(4):525-532
The X-ray absorption jump factor and jump ratio of Gd, Dy, Ho and Er were measured with a Si(Li) detector by attenuation, with Gd, Dy, Ho and Er foil, a Compton peak produced by the scattering of the Am-241 Gamma rays. Al was chosen as secondary exciter. The experimental absorption jump factors and jump ratios are compared with the theoretical estimates of WinXcom (Radiat. Phys. Chem. 60 (2001) 23), McMaster (Compilation of X-ray cross sections UCRL-50174, 1969; Sec. II. Rev. I), Broll (X-ray Spectrom 15 (1986) 271), Hubbel and Seltzer (NISTIR (1995) 5632) and Budak (Radiat. Meas. accepted for publication). The present results constitute the first measurement for this combination of energy and elements, and good agreement is obtained between experiment and theory. 相似文献