多元周期函数的一类逼近及逼近阶估计

本文讨论了多元周期函数的一类逼近,得到一个稠密性的充要条件并构造出适当的逼近函数,给出了逼近阶的精确估计．     

聚芳醚酮环状低聚物的基质辅助激光解吸电离质谱表征

采用基质辅助激光解吸电离飞行时间质谱(MALDI-TOF-MS)技术分别对2种合成的聚芳醚酮环状低聚物进行了分析研究 ,并讨论了低聚物中不同聚合度离子组分的分布规律。实验结果表明MALDI-TOF-MS是分析环状低聚物直观、准确、快速的分析工具。     

Influence of Short-Chain Alcohols on the Micellization Parameters of Sodium Dodecyl Sulfate (SDS)

The influence of short-chain alcohol on the aggregation behavior of Sodium Dodecyl Sulfate (SDS) is investigated within a wide range of alcohol concentration by potentiometric technique. It is observed that aggregation behavior of SDS is a function of alcohol concentration. Variation of micellization parameters are studied in a wide range of alcohol concentration and the trend of changing of micellization parameters have been investigated. The variations of micellization parameters show several regularities. Finally, the relationships between these regularities and alcohol-surfactant interactions have been explained.     

衍射效应诱导涡旋光束的偏振度变化

基于惠更斯-菲涅耳衍射原理以及部分相干光的相干与偏振的统一理论,研究了衍射效应诱导部分相干涡旋光束的偏振度变化.通过理论分析与数值计算表明,部分相干涡旋光束经圆孔衍射后偏振度将发生变化,在衍射场中光束的偏振度分布情况与入射光束的相干度、入射光束的拓扑电荷数、衍射孔径的大小等因素有关.     

大气湍流对部分相干电磁平顶光束传输的影响

基于相干性和偏振性统一理论,采用Rytov相位结构函数平方近似推导出了部分相干电磁平顶光束在湍流大气中传输的偏振度、相干度和光谱强度公式,并研究了湍流对其传输特性的影响.研究表明,偏振度和相干度与源光谱的带宽无关.大气湍流使得不同阶数的部分相干电磁平顶光束的偏振度经长程传输后均趋于其初始值.大气湍流使得部分相干电磁平顶光束与电磁高斯一谢尔模型光束相干度的差别减小,并导致相干度的振荡和相位奇异现象消失.大气湍流使得相干性较好的部分相干电磁平顸光束的光谱跃变现象消失.     

端丙烯酸酯基超支化聚(酯-胺)的结构分析及光固化

近年来 ,具有树枝状结构的超支化聚合物因其独特的物理化学性质而得到广泛关注[1,2 ] .超支化聚合物主要采用 3种途径合成 ,( 1 )ABn(n >2 )型及潜ABn 型单体的聚合 ;( 2 )由A2 与Bn 型单体直接聚合 ;( 3)先由特定的单体对原位形成ABn型中间体后再聚合 .其中后两种方法可直接采用商业化原料 ,因此更具有实用价值 .目前 ,基于途径 ( 2 )已合成出超支化聚酰胺[3 ] 、聚醚[4] 、聚酰亚胺[5] 和共轭聚合物[6] 等 ,但该途径容易生成凝胶化产物 ,通过控制反应物浓度、在凝胶点之前停止反应等 ,可得到溶解型超支化产物 .由于超支化聚合物具有低…     

羟丙基三甲基氯化铵壳聚糖制备的可控性研究

用壳聚糖与缩水甘油三甲基氯化铵反应制备羟丙基三甲基氯化铵壳聚糖,所得产物的结构受壳聚糖分子量和脱乙酰度、反应温度、反应时间、壳聚糖与缩水甘油三甲基氯化铵投料比的影响。实验结果表明：随着反应温度升高,羟丙基三甲基氯化铵壳聚糖的取代度增加,在70～80℃达最大;反应时间增加,取代度增加,产物分子量降低。缩水甘油三甲基氯化铵与壳聚糖比例达3：1前取代度随比例升高而增加。脱乙酰度和分子量越大的壳聚糖其季铵盐取代度越高。控制反应温度在30～90℃,反应时间3～10h,投抖比为1：1～4：1,可以得到取代度15％～909／6,分子量1万到100万的羟丙基三甲基氯化铵壳聚糖。     

关于一种形象化的计算方法

对量子力学中的一种常见计算进行了形象化的改进处理．     

Thermodynamic determination of solvation potentials of various metal chlorides by (1,4-dioxane + water) mixtures through EMF measurements

The EMF data of different metal chlorides (2:1 electrolytes) were obtained by using a cell [M_X Hg|MCl₂ (m)|AgCl–Ag] at two temperatures. Stock solutions of metal chlorides (CoCl₂, CuCl₂ and ZnCl₂) were prepared by weight in 1,4-dioxane–aqueous mixtures. There was a significant change in the EMF values with change of metal chloride, its concentration and solvents composition. The standard electrode potential (E°) values of the above cell were calculated from the measured EMF of these mixtures. The standard thermodynamic functions (ΔG°, ΔH° and ΔS°) and respective transfer parameters of MCl₂ from water to 20, 45 and 70% dioxane–water mixtures were also evaluated. Equilibrium dissociation constants (K₁ and K₂) as well as the degrees of dissociation (α₁ and α₂) were obtained by iterative procedures. The data were analyzed in terms of solute–solvent interactions depending on standard and transfer thermodynamic parameters and mean activity coefficients (γ_±) of electrolytes.     

Properties of connected graphs having minimum degree distance

The degree distance of a connected graph, introduced by Dobrynin, Kochetova and Gutman, has been studied in mathematical chemistry. In this paper some properties of graphs having minimum degree distance in the class of connected graphs of order n and size m≥n−1 are deduced. It is shown that any such graph G has no induced subgraph isomorphic to P₄, contains a vertex z of degree n−1 such that G−z has at most one connected component C such that |C|≥2 and C has properties similar to those of G.For any fixed k such that k=0,1 or k≥3, if m=n+k and n≥k+3 then the extremal graph is unique and it is isomorphic to K₁+(K_1,k+1∪(n−k−3)K₁).