全文获取类型
收费全文 | 5682篇 |
免费 | 859篇 |
国内免费 | 454篇 |
专业分类
化学 | 979篇 |
晶体学 | 58篇 |
力学 | 2452篇 |
综合类 | 128篇 |
数学 | 592篇 |
物理学 | 2786篇 |
出版年
2024年 | 15篇 |
2023年 | 61篇 |
2022年 | 161篇 |
2021年 | 169篇 |
2020年 | 217篇 |
2019年 | 152篇 |
2018年 | 146篇 |
2017年 | 230篇 |
2016年 | 253篇 |
2015年 | 200篇 |
2014年 | 342篇 |
2013年 | 346篇 |
2012年 | 311篇 |
2011年 | 372篇 |
2010年 | 243篇 |
2009年 | 283篇 |
2008年 | 305篇 |
2007年 | 344篇 |
2006年 | 306篇 |
2005年 | 295篇 |
2004年 | 298篇 |
2003年 | 274篇 |
2002年 | 214篇 |
2001年 | 188篇 |
2000年 | 152篇 |
1999年 | 172篇 |
1998年 | 154篇 |
1997年 | 116篇 |
1996年 | 105篇 |
1995年 | 77篇 |
1994年 | 72篇 |
1993年 | 60篇 |
1992年 | 69篇 |
1991年 | 62篇 |
1990年 | 53篇 |
1989年 | 40篇 |
1988年 | 33篇 |
1987年 | 13篇 |
1986年 | 10篇 |
1985年 | 16篇 |
1984年 | 5篇 |
1983年 | 7篇 |
1982年 | 13篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 11篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1971年 | 3篇 |
1957年 | 9篇 |
排序方式: 共有6995条查询结果,搜索用时 187 毫秒
161.
Shunbo Yang Zhipeng Meng Yanan Li Rongxin Chen Yazhou Yang Zhengyang Zhao 《Molecules (Basel, Switzerland)》2021,26(4)
‘Orin’ is a popular apple cultivar, which has a yellow-green appearance, pleasant taste, and unique aroma. However, few studies on the fruit quality characteristics of ‘Orin’ apples have been reported before. In this study, changes of the physiological characteristics were measured at different ripening stages, and the soluble sugars and organic acids were determined by high-performance liquid chromatography (HPLC). Volatile compounds were identified using the headspace solid-phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC-MS). During the fruit ripening, the ‘Orin’ apple fruit weight, size, and total soluble solid were gradually increased by contrast with the titratable acidity, and the firmness decreased. The content of four soluble sugars reached the maximum at the 180 days after full bloom (DAFB) stage. Malic acid was measured as the most abundant organic acid in ‘Orin’ apples. Ethyl butyrate, hexyl propanoate, hexyl acetate and butyl acetate belonging to esters with high odor activity values (OAVs) could be responsible for the typical aroma of ‘Orin’ apples. The aim of this work was to provide information on the flavor characteristics of ‘Orin’ apples and promote this apple cultivar for marketing and processing in the future. 相似文献
162.
Hua Lei Meixuan Wu Ying Liu Fan Mo Jiayao Chen Shilong Ji Yan Zou Xiaoping Dong 《中国化学快报》2021,32(7):2317-2321
Photocatalysis technology has been proved to be a potential strategy for removal of organic dyes, however high-power light sources are generally necessary to initiate photocatalytic reaction. In this work, we employed an excellent photocatalyst of Bi2WO6 with visible light harvest and meanwhile an intrinsic ferroelectricity, which realized the efficient degradation of organic dye via the synergetic photopiezocatalysis. Through coupling the illumination by a low-power (9 W) LED and the ultrasonic vibration (120 W) by an ultrasonic cleaner, the nanoflower-like Bi2WO6 composed of ultrathin nanosheets showed a much more enhanced photopiezocatalysis performance for purification of organic dye than the individual photocatalysis and piezocatalysis. Furthermore, the high mineralization efficiency and the good durability of the Bi2WO6 catalyst were demonstrated. The possible mechanism of photopiezocatalysis was finally proposed, where the ultrasound-induced piezoelectric field in Bi2WO6 drove photo-generated electrons and holes to diffuse along opposite directions, consequently promoting the separation efficiency of charge carriers. This work indicates that the synergetic photopiezocatalysis by coupling irradiation and ultrasonic vibration is a promising strategy to purify organic pollutants in wastewater. 相似文献
163.
为了对地面目标雷达与红外特性测试的各类数据进行统一规范化管理,使其高效应用,分析各类数据的特性及其处理方式,构建了目标特性数据库管理系统;数据库的整体设计中,在数据头和数据文件方案基础上增加了自动跟随数据表编号的路径生成方法,结合了接口式的运作结构,模块化的数据库功能和层次化的数据表结构设计思路;数据库的编制基于Access数据库管理软件和VC++编程软件,通过ADO数据库访问技术加以实现,详细描述了ADO接口的编程步骤,并对本接口不同指针的入库频率和提取效率进行了对比择优;在运行中,提出了主、副数据库移植性管理方法;工作实践验证了目标特性数据库管理系统的可靠性和高效性,为地面目标特性的测试与分析提供了良好的数据支撑。 相似文献
164.
如何实现高精度的测量是现代制造业及微电子技术领域的热点问题之一. 基于微纳米测头的三坐标测量机是当前实现高精度测量的重要手段. 随着测量尺寸的减小, 常用的纳米/微纳尺度的测头与待测表面之间形成静态接触, 其表面相互作用成为了影响其测量精度和可靠性的关键因素之一. 本文基于一种触发式振动测头, 研究了其动力学模型, 并通过对测头纳米尺度表面相互作用的理论分析及数值模拟, 确立了测头振动参数与表面相互作用之间的关联. 实验研究表明, 参数优化后的谐振微纳测头能有效抑制表面作用带来的干扰, 提高测量精度. 相似文献
165.
Vocal fold nodules (VNs) in children are benign, bilateral lesions occurring on the mid-membranous vocal folds. Repetitive phonotraumatic behavior leading to chronic vocal fold injury and repair is frequently cited as the primary etiology; however, specific behavioral characteristics may predispose some children toward intense and potentially phonotraumatic voice use, thereby contributing secondarily to VN formation. The purpose of this case-control study was to determine whether children with VNs possess unique behavioral characteristics that may predispose them to VN development. Parents of 26 children with VNs (20 boys, 6 girls, mean age=7.2 years, SD=2.5 years), and 29 vocally normal, medical controls (22 boys, 7 girls, mean age=6.7 years, SD=2.4), completed the Childhood Behavior Checklist (CBCL/4-18, Achenbach, 1991), a standardized parent-rating scale with strong psychometric properties. No significant between-group differences were detected on any of the behavior problem syndrome scales. Group differences approached significance for the individual items "screams a lot" and "teases a lot" (VN group > Controls). The VN group scored significantly higher than the controls on the "Social Scale," a compilation of positive ratings of the child's social activity, frequency of contacts with friends, behavior with others, and behavior by themselves. Observed outcomes were consistent with previous characterizations of children with VN as "outgoing" or "extroverted" but were not consistent with other claims that this population may be at risk for "aggressive," "attentional," or "impulsive" behavior problems. 相似文献
166.
In order to improve the particle collection efficiency of the electrostatic precipitator (ESP), a transverse plate ESP with bipolar discharge electrodes is proposed. The simulations of the velocity distribution have shown that when the inlet velocity is 1 m/s, within the range of 40 mm from electrode plate, the average velocities of windward side and leeward side are less than 0.7 m/s and 0.3 m/s respectively. It is clear that the velocity near the collection electrode plate of this bipolar ESP is much lower than that of the ordinary ESP at the same inlet velocity. This low velocity can lead to higher efficiency for fine dust collection due to the less dust re-entrainment in ESP. It is also found that the average velocities are getting lower when the distance between plates electrodes are greater than 150 mm in accordance with the simulations. The voltage current characteristics of the bipolar ESP are superior to the ordinary ESP. The pressure drop of the bipolar ESP is about 30% higher than that of the ordinary one. The dust penetration of the bipolar ESP is about 54% less than that of the ordinary ESP when the sintering dust with 25.405 μm mass median diameter is used as the test particulate under the condition of the electric field from 2.1 kV/cm to 3.2 kV/cm and the velocity from 1.0 m/s to 1.5 m/s. 相似文献
167.
Atmosphere pressure uniform plasma has the broad application prospect in the industrial field. Using hollow needle cathode - plate anode device excited by direct-current voltage, a uniform and stable glow discharge is generated at atmospheric pressure in ambient air with argon used as working gas. The influence of the experimental parameters (including gas flow rate and the gas gap width) on discharge has been investigated by optical method. It can be found that a glow-discharge plasma column can bridge the two electrodes. The plasma column is uniform, and no filaments can be discerned. Near the plate electrode, the diameter of the plasma column is largest of all positions. The maximal diameter of the plasma column increases with increasing the discharge current or the gas flow rate. Through electrical method, the voltage-current characteristic has been investigated. It has been found that the discharge voltage decreases with increasing the current which is similar with the characteristic of glow discharge in low pressure. It increases with increasing the gas gap width or the gas flow rate. By analyzing the optical emission spectrum scanning from 330 to 450 nm emitted from the direct-current glow discharge, the molecular vibrational temperature and the intensity ratio of spectral lines I-391.4/I-337.1 have been investigated as functions of the gas flow rate and gas gap width. Results indicate that both the vibrational temperature and the intensity ratio of spectral lines I-391.4/I-337.1 decrease with increasing the gas flow rate or the gas gap width. In addition, the molecular vibrational temperature and the intensity ratio of spectral lines I-391.4/I-337.1 have been investigated in spatial resolution along the direction of gas flow(plasma column axial), and give a qualitative analysis as well. It is found that the vibrational temperature and the average electron energy increase with increasing the distance from the hollow needle cathode. These results are important to the industrial applications of glow discharge. 相似文献
168.
利用水热法制备了菊花状的氧化锌纳米棒,并进行表征,将纳米氧化锌掺入纳米金刚石中配制成电泳液,超声分散后电泳沉积到钛衬底上,再经热处理后进行场发射特性的测试.结果表明:未掺混的金刚石阴极样品的开启电场为7.3V/μm,在20V/μm的电场下,场发射电流密度为81μA/cm2;掺混后阴极样品的场发射开启电场降低到4.7~6.0V/μm,在20V/μm电场下,场发射电流密度提高到140~158μA/cm2.原因是纳米ZnO掺入后,增强了涂层的电子输运能力、增加了有效发射体数目,提高了场增强因子β,而金刚石保证了热处理后涂层与衬底的良好键合,形成了欧姆接触,降低了场发射电流的热效应.场发射电流的稳定性随掺混ZnO量的增加而下降,要兼顾场发射电流密度及其稳定性,适量掺入ZnO可有效提高纳米金刚石的场发射性能. 相似文献
169.
170.
Stefan Bilbao Olivier Thomas Cyril Touzé Michele Ducceschi 《Numerical Methods for Partial Differential Equations》2015,31(6):1948-1970
This article is concerned with the numerical solution of the full dynamical von Kármán plate equations for geometrically nonlinear (large‐amplitude) vibration in the simple case of a rectangular plate under periodic boundary conditions. This system is composed of three equations describing the time evolution of the transverse displacement field, as well as the two longitudinal displacements. Particular emphasis is put on developing a family of numerical schemes which, when losses are absent, are exactly energy conserving. The methodology thus extends previous work on the simple von Kármán system, for which longitudinal inertia effects are neglected, resulting in a set of two equations for the transverse displacement and an Airy stress function. Both the semidiscrete (in time) and fully discrete schemes are developed. From the numerical energy conservation property, it is possible to arrive at sufficient conditions for numerical stability, under strongly nonlinear conditions. Simulation results are presented, illustrating various features of plate vibration at high amplitudes, as well as the numerical energy conservation property, using both simple finite difference as well as Fourier spectral discretizations. © 2015 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 1948–1970, 2015 相似文献