有限温度下二维Heisenberg铁磁系统的声子衰减

在二维正方Heisenberg铁磁系统的基础上建立了磁振子-声子相互作用模型. 利用松原格林函数理论研究了系统的声子衰减，计算了布里渊区的主要对称点线上的声子衰减曲线. 发现在第一布里渊区，在Δ线上，横向声频支声子无衰减，在Z线上，纵向声频支声子无衰减；横向声频支声子衰减比纵向声频支声子衰减至少大一个数量级，并讨论了各项参数的变化对横向声频支声子衰减与纵向声频支声子衰减的影响. 根据声子衰减与声子寿命的关系，声子衰减与声子态密度的关系，可以讨论横向声频支声子与纵向声频支声子的寿命与态密度. 关键词： 磁振子-声子相互作用 横向声频支声子衰减 纵向声频支声子衰减 声子寿命     

单壁碳纳米管吸附联苯类有机物的荧光光谱分析

利用芳香族化合物对单壁碳纳米管进行了化学修饰,并利用荧光光谱以及时间分辨光谱对修饰后的单壁碳纳米管进行了表征分析.实验发现吸附对三联苯后有1个荧光峰位置发生了蓝移,这说明吸附过程使对三联苯的一些能级分布发生了变化.测量吸附前后对三联苯和蒽甲醇的荧光寿命,发现吸附后的荧光衰减曲线下降趋势更加明显,对曲线进行多指数拟合得出的荧光寿命及其数目发生了变化,分析了可能导致该现象的原因.     

掺铥PLZT透明光电陶瓷的光辐射特性

根据J-O理论研究掺Tm3+的光电陶瓷PLZT的激光潜能，利用Tm3+的420?2000 nm的吸收光谱拟合出了其强度参量，即?2=9.133￡10-21 cm2, ?4=1.529￡10-21 cm2和?6=1.712￡10-21 cm2，进而由强度参量计算了辐射跃迁几率、辐射寿命、荧光分支比和1865 nm荧光峰的受激发射截面等光学参数．     

稀有类铥铋离子辐射光谱的相对论识别

用全相对论多组态自洽场方法,计算了高离化类铥铋原子BiXV的1s、2s、2p-、2p、3s、3p-、3p、3d-、3d、4s、4p-、4p、4d-、4d、4f-、4f、5s、5p-、5p、5d-、5d、5f-、5f、5g-、5g、6s、6p-、6p、6d-、6d、6f-、6f、6g-、6g、7s、7p-、7p、7d-、7d、7f-、7f、7g-、7g、8s、8p-、8p、8d-、8d轨道的2249个精细结构能级和辐射寿命以及其他各种跃迁参数.能级和波长的计算值和实验值符合得好.另外还发现了一些辐射寿命较长的亚稳态能级.     

碳纳米管束中的正电子理论

采用中性原子叠加模型和有限差分方法(SNA-FD)计算了大范围内不同管径的单壁碳纳米管束中的正电子情况，发现对于单壁碳纳米管束，正电子的主要湮没区域，湮没对象和正电子寿命随碳纳米管管径的不同而发生规律性变化.计算得到管径范围在0.8—1.6nm的碳纳米管束的正电子寿命范围为332—470ps，与实验测得的394ps符合较好.     

Studies on thermally induced structural changes in silicon based polymers by positron annihilation

Temperature dependence of positron annihilation lifetime spectra of polysilanes such as, poly(methyl-n-propylsilane) (PMPrS) and poly(di-n-hexylsilane) (PDHS) has been investigated. The τ₃ in PMPrS is seen to increase monotonically around the solid–liquid transition temperature. The transition temperature and free volume are observed to depend on the molecular weight and/or packing of the backbones. For PDHS, a sharp change in τ₃ and I₃ is seen at the solid–solid transition temperature. Free volume radius probability density functions, above and below the transition temperature, are presented in PMPrS and PDHS. Positron studies are complimented by conventional thermal analysis studies.     

The dynamics of asset lifetime under technological change

The variable lifetime of assets is analyzed in a serial replacement problem. Technological change impacts the maintenance cost and new asset cost. The optimal asset lifetime appears to be constant only when both costs decrease with the same rate. We identify cases when the technological change decreases or increases the optimal lifetime.     

Formation mechanism of ethanol-water excimer

The fluorescent spectrum and the excitation spectrum were used to present the cluster molecular structure feature in ethanol-water solutions.Through analyzing the fluorescent characteristics of an excimer,it is proposed that the excimers are formed between the ethanol-water cluster molecules in the excited state and in the ground state.The fluorescent lifetime and the fluorescent intensity decay process give information about the photo-physical and photo-chemical processes of the formation and the dissociation of an excimer.The theoretical calculation and physical analysis coincide with the experimental results.The preliminary conclusion about the structure feature of ethanol-water cluster molecule is that it has a planar one like a sandwich.     

Spectral Decomposition of Intracellular Complex Fluorescent Signals Using Multiwavelength Phase Modulation Lifetime Determination

Lifetime-based spectral decomposition using a frequency-domain phase/modulation technique has been developed on our UV confocal microspectrofluorimeter prototype. Examples of such an application are first given in the case of complex mixtures of three overlapping fluorescent components in solution. Preliminary results concerning cellular potential application are also reported in the case of Snarf-1 pH sensor. Limits and perspectives of such an approach at the subcellular level are discussed in view of future improvement.     

Dy~(3+):ThO_2的选择激发光谱和能级结构

本文首次用熔融法生长了Dy3 + :ThO2 晶体 ,详细研究了其光谱特性。通过 12K下格位选择激发下的发射光谱测量 ,利用晶场理论 ,确定了Dy3 + 在ThO2 中的格位对称性为C3v。列表给出了Dy3 + :ThO2 的晶场能级结构。测量和讨论了 4 F9/ 2 能级的寿命。