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71.
用溶剂热方法合成了2个新的3d-4f异金属四核簇合物:[Zn2Ln2(salen)2(CO2PyCH2O)2(MeOH)2](ClO4)2·2MeOH(Ln=Dy(1),Tb(2);H2salen=N,N'-双(3-甲氧基水杨基)-1,3-二氨基丙烷;HCO2PyCH2OH=6-羧基吡啶-2-甲醇)。它们是由锌(Ⅱ)Schiff碱构筑模块和6-羧基吡啶-2-甲醇辅助配体组装而成的Zn-Ln2-Zn型簇合物。磁性测量表明稀土离子间存在铁磁性相互作用。Zn2Dy2配合物1在2 000 Oe直流磁场下显示出磁弛豫行为;而Zn2Tb2配合物2不但有磁场导致的磁弛豫行为,而且还具有荧光性质。 相似文献
72.
73.
Dependence of electrical performance on structural organization in polymer field effect transistors 下载免费PDF全文
Emily G. Bittle Hyun Wook Ro Chad R. Snyder Sebastian Engmann R. Joseph Kline Xinran Zhang Oana D. Jurchescu Dean M. DeLongchamp David J. Gundlach 《Journal of Polymer Science.Polymer Physics》2017,55(14):1063-1074
Organic semiconductors (OSCs) are strong contenders for use in printed, flexible electronics. Although organic electronic materials have been studied for many years, the physics of charge transport is still under investigation. This is in part due to variability resulting from the large variety of molecules that can be synthesized and inconsistency in electrical characterization due to device and processing conditions. Molecular ordering in OSCs is known to alter the charge transport characteristics and attention to long range and short range ordering provides clues as to the nature of transport pathways. Here, we study ordered regioregular poly(3‐hexylthiophene‐2,5‐diyl) films carefully prepared to obtain a set of three samples with incrementally increasing order on identical transistor architectures. Ordering was characterized using a variety of short and long range techniques to probe the coherence and number of crystallites formed during processing, and the correlation between these different measures of order are quantified. We observe three changes in transistor behavior that show a shift from non‐ideal to more textbook‐like characteristics with increasing order: reduction of the contact resistance, shift to field‐independent mobility, and a shift from a diode‐like (S‐shaped) to linear response at low lateral fields. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55, 1063–1074 相似文献
74.
In this paper we extend some of our previous works on continua with stress threshold. In particular here we propose a mathematical model for a continuum which behaves as a non-linear upper convected Maxwell fluid if the stress is above a certain threshold and as a Oldroyd-B type fluid if the stress is below such a threshold. We derive the constitutive equations for each phase exploiting the theory of natural configurations (introduced by Rajagopal and co-workers) and the criterion of the maximization of the rate of dissipation. We state the mathematical problem for a one-dimensional flow driven by a constant pressure gradient and study two peculiar cases in which the velocity of the inner part of the fluid is spatially homogeneous. 相似文献
75.
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77.
The universal enveloping C
*-algebra A
of twisted canonical commutation relations is considered. It is shown that, for any (–1,1), the C
*-algebra A
is isomorphic to the C
*-algebra A
0 generated by partial isometries t
i
,t
i
*,i=1,¨,d satisfying the relations
t
i
*
t
j
=
ij
(1–
k<i
t
k
t
k
*), t
j
t
i
=0, ij
and it is proved that the Fock representation of A
is faithful. 相似文献
78.
在 N R/ T 网的基础上,对基于嵌入式关系模型的数据库信息系统的行为,给出了一种形式化的描述方法,并设计了一个变迁点火执行算法 相似文献
79.
Randall Dougherty Greg Hjorth 《Transactions of the American Mathematical Society》1999,351(5):1835-1844
We show that, for , the relation of -equivalence between infinite sequences of real numbers is Borel reducible to the relation of -equivalence (i.e., the Borel cardinality of the quotient is no larger than that of ), but not vice versa. The Borel reduction is constructed using variants of the triadic Koch snowflake curve; the nonreducibility in the other direction is proved by taking a putative Borel reduction, refining it to a reduction map that is not only continuous but `modular,' and using this nicer map to derive a contradiction.
80.
We consider a one-dimensional gas of two kinds of particles with different masses interacting through short range interactions. The system exhibits an extreme form of the Soret effect: when the ends of the system are in contact with thermal baths of different temperatures, there is complete separation of the species. We show how this separation can be well described in the Boltzmann approximation and discuss the origin of this odd behavior. 相似文献