首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1653篇
  免费   206篇
  国内免费   219篇
化学   477篇
晶体学   7篇
力学   903篇
综合类   40篇
数学   214篇
物理学   437篇
  2024年   2篇
  2023年   10篇
  2022年   28篇
  2021年   56篇
  2020年   53篇
  2019年   47篇
  2018年   53篇
  2017年   67篇
  2016年   83篇
  2015年   72篇
  2014年   99篇
  2013年   113篇
  2012年   81篇
  2011年   103篇
  2010年   69篇
  2009年   116篇
  2008年   121篇
  2007年   93篇
  2006年   108篇
  2005年   89篇
  2004年   71篇
  2003年   75篇
  2002年   53篇
  2001年   49篇
  2000年   52篇
  1999年   49篇
  1998年   38篇
  1997年   27篇
  1996年   40篇
  1995年   31篇
  1994年   31篇
  1993年   20篇
  1992年   13篇
  1991年   12篇
  1990年   10篇
  1989年   15篇
  1988年   2篇
  1987年   7篇
  1986年   2篇
  1985年   4篇
  1984年   2篇
  1983年   2篇
  1982年   6篇
  1981年   1篇
  1979年   2篇
  1957年   1篇
排序方式: 共有2078条查询结果,搜索用时 15 毫秒
71.
Synchronization and coherent combining of two pulsed fiber lasers   总被引:1,自引:0,他引:1  
We demonstrate a scalable architecture for coherent combining of pulsed fiber lasers.A new method for generating synchronous pulsed fiber lasers by direct phase modulation is proposed and investigated.It is shown that phase modulated mutually coupled laser array can be a steady synchronous pulsed fiber laser source.The synchronous pulsed fiber lasers are coherently combined with an invariable phase difference of π in adjacent lasers.Neither active phase control nor polarization control is taken in our experiment.  相似文献   
72.
引用1984年尹克震提出的“开关函数的反演公式”,采用伪随机序列技术的思想,提出移位寄存器型时序逻辑网络的一种快速设计方法。  相似文献   
73.
In this work, porous graphite nanofibers (PGNFs) were manufactured as promising catalyst supporter by a physical activation method for direct methanol fuel cells, and Pt nanoparticles were loaded on the PGNFs in order to prepare electrode materials by a chemical reduction method. The pore structures of the Pt/PGNFs were analyzed by N2 adsorption isotherms at 77 K. Electrocatalytic activities of final products were investigated by voltammetry and conductivity measurements in a 1.0 M CH3OH/0.5 M H2SO4. As a result, electrocatalytic activities of Pt/PGNFs were increased in the presence of Pt particles on the PGNFs and with increasing the specific surface area of the carbons.  相似文献   
74.
A new device for studying the dynamic adhesive strength is created. A procedure for determining the dynamic adhesive strength in fiber—polymer systems under impact loading (pull-out technique) is developed. The adhesive strength of the interface of polymer—steel wire joints formed by polymers of different chemical nature (epoxy resin, polysulfone, and polypropylene) is examined. It is shown that the dynamic adhesive strength grows as the loading rate increases for all the systems under investigation and that the relationship between the adhesive strength and the loading rate, , over a wide range of rates can be described by two straight lines corresponding to the quasi-static and impact loading, respectively. When passing from the quasi-static to dynamic loading, the character of scale relations of the adhesive strength does not change.Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 6, pp. 689–700, November–December, 1999.  相似文献   
75.
The construction of the three-layer hybrid local self-consistent field/molecular mechanics/self-consistent reaction field method is detailed. This method is specifically devoted to the study of the reactivity of large chemical systems in solution. The solvent, modeled by a polarizable continuum, surrounds the whole solute molecule. Solute–solvent interactions are taken into account by means of the self-consistent reaction field approach. The solute system is treated by both quantum and molecular mechanics, the former being principally applied to the reactive part, i.e., the part undertaking bond forming or breaking, the latter being reserved for the ancillary encumbering groups. The connection between the molecular mechanics and the quantum mechanics part is accomplished by a strictly localized bond orbital that remains frozen within the local self-consistent field framework. As a test system, the asymmetric Diels–Alder reaction between cyclopentadiene and (–)-menthyl acrylate is studied for the first time with steric interactions and electrostatic solvent effects taken into account simultaneously. The results indicate that the coupling of both interactions leads to conclusions that could not have been guessed from separate calculations.Proceedings of the 11th International Congress of Quantum chemistry satellite meeting in honour of Jean-Louis Rivail  相似文献   
76.
Four amino acids and four different hair samples were studied in order to get information about the decomposition of human hair, using combined (TG-MS) and DSC techniques. The thermal stability of the investigated amino acid samples was different. Since they contain identical functional groups (-NH2, -COOH) some common mass/charge units were identified. However, due to their different chemical composition remarkable differences have also been obtained. The results of the investigation of the amino acids were helpful to study the thermal fragmentation of the hair samples. In our experiments, the effect of the heating rates was also studied. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
77.
We describe the implementation of an adaptive umbrella sampling method, making use of the weighted histogram analysis method, for computing multidimensional potential of mean force for chemical reaction in solution. The approach is illustrated by investigating the effect of aqueous solution on the free energy surface for the proton transfer reaction of [H(3)N-H-NH(3)](+) using a combined quantum mechanical and molecular mechanical AM1/TIP3P potential.  相似文献   
78.
The results of FEM investigation of the triaxial stress state in multilayer structural elements subjected to axial and bending loads are presented. The distribution regularities of the stiffness and stresses or strains depending on the geometric and mechanical characteristics of layers and their position in the cross section of beams and bars are examined. The optimization of these elements is carried out using the dependences of the Bareisis—Paulauskas method and the Optim-98 computer program created by the present authors. As the optimization criteria, the strength, stiffness, mass, and cost of the structural elements are considered.  相似文献   
79.
Water diffusion measurements were performed on rabbit Achilles tendons during static tensile loading and tendons in an unloaded state. The apparent diffusion coefficient (ADC) was measured along two directions: parallel and perpendicular to the long axis of the tendon. Tendons were studied after being prepared in two ways: (a) after being stored frozen in phosphate-buffered saline (PBS) and (b) freshly isolated. Statistically significant directional anisotropy was observed in the ADC in all tendons. The ADC was significantly greater in the direction parallel to the long axis of the tendon than in the perpendicular direction. The anisotropy is attributed to the greater restrictions seen by the water molecules in the perpendicular direction and is consistent with the known geometry of the tendon. Storage in PBS caused tendons to swell. This increased the ADC measured along both directions and reduced the anisotropy. The existence of anisotropy in the ADC was not related to the orientation of the specimen in the magnet. The ADC increased along both directions following the application of a 5-N tensile load; the increase was greatest along the perpendicular axis of the tendon. In order to determine whether load-related changes in the ADC reflected changes in interfibrilar spacing, we used electron microscopy to measure load-related changes in fibril spacing. Load-related changes in fiber spacing could not account for the observed changes in the ADC. The increase in ADC caused by loading was attributed to the extrusion of tendon water into a bulk phase along the outside surface of the tendon. In PBS-stored samples, enough fluid was extruded that it could be visualized. The transient response of the ADC to a 5-N tensile load was also studied. The absolute ADC in both directions increased with loading and recovered to baseline upon unloading. The transient changes in ADC, for both loading and unloading, had a mean time constant of approximately 15 min. The magnitude of the load-induced transient ADC changes was comparable to that seen in the static-loading experiments.  相似文献   
80.
根据HCSB-DEMO堆的设计要求,对不同尺寸的聚变堆能产生的聚变功率、中子壁负载和等离子体燃烧时间等进行计算与分析,给出了符合设计要求的堆芯参数。在所选定的堆芯参数条件下进行了零维功率平衡计算分析,给出了3组HCSB-DEMO堆的等离子体初步设计参数。  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号