Investigation of Simultaneous Generation of Arsenic,Bismuth and Antimony Hydrides Using Inductively Coupled Plasma Optical Emission Spectrometry

Hydride generation from solution containing As(III), Bi(III), and Sb(III) by means of different borane reductants and acids using inductively coupled plasma optical emission spectrometry as a detection system was investigated. The As, Bi, Sb, B, C, H, and N lines as well as the OH and CN molecules were recorded. Their intensities in relation to hydride formation conditions were measured. Effects of the HCl, CH₃COOH, and C₆H₈O₇ acids as well as the NaBH₄, H₃B-NH(CH₃)₂, and H₃B-NH₂C(CH₃)₃ reductants on efficiency of the As, Sb, and Bi hydride generation were investigated and discussed. Influence of hydride generation conditions on plasma was studied.     

平面剪切来流作用下串列布置三圆柱流致运动特性研究

基于四步半隐式特征线分裂算子有限元方法,对Re=100时,剪切来流作用下串列三圆柱体双自由度流致振动问题进行了数值计算. 首先,与现有文献结果进行对比验证该方法的正确性. 然后,着重分析剪切率、固有频率比和折减速度三个关键参数对串列三圆柱体结构流致动力响应及流场特性的影响. 数值计算结果表明:剪切率、固有频率比与折减速度对结构振幅和运动轨迹的影响较大. 随剪切率的增大,上游圆柱最大振幅的变化与单圆柱工况类似. 中下游圆柱最大振幅会增大且会出现双向共振现象,同时,发生共振响应区域会扩大. 随固有频率比的增大,上游圆柱顺流向锁定区间范围会减小,而中下游圆柱双向锁定区间会扩大. 另一方面,均匀来流作用下,结构运动轨迹以"8"字形和不规则形状为主. 随剪切率的增大,锁定区间内运动轨迹会由"8"字形转变为"雨滴"形. 在大剪切率与高固有频率比工况下,中游圆柱体结构运动轨迹会出现"双雨滴"形状. 最后,通过对流场特性的分析,揭示了剪切来流作用下串列三圆柱结构流致运动响应的内在机理.      

高速电梯气动特性研究与风口设计

高速电梯运行时，井道内气压的快速变化会对轿厢运行的稳定性及安全性产生极大影响．为解决上述问题，提出了三种在井道壁面上开风口的设计方案，运用计算流体力学分析软件FLUENT对电梯运行过程中的空气流动状态进行数值仿真，同时改变风口形状以及数量，对井道内风速变化、轿厢所受气动阻力及气动力矩进行分析．分析结果表明，在提出的三种开风口方案中，上下圆形风口为最优，与未开风口时相比，轿厢气动阻力减小22.05 %，侧翻力矩减小29.87 %，俯仰力矩减小18.02 %．最后进行试验验证，表明了开风口方案的有效性，研究结果可为井道风口的设计提供理论依据．     

Investigation of the electrical properties of a new PPV derivative-based on a sandwich structure for opto-electronic applications

The opto-electronic properties of native poly(p-phenylene vinylene) (PPV) were tuned by the confinement of the π-conjugation and the incorporation of a sulphur group as a spacer in order to obtain a blue-green emitting polymer (PPVS). The energy band gap of the PPVS thin film has been measured by UV-vis absorption spectroscopy and evaluated to 2.87 eV. Current-voltage characteristics and impedance spectroscopy measurements performed on sandwich structures [ITO/PPVS/Al] are used to elucidate the conduction mechanisms. The static electrical characterisations showed a space charge limited conduction (SCLC) and a conductivity with low power frequency behaviour characteristic of a hopping transport in disordered materials. The impedance spectra can be discussed in terms of an equivalent circuit model designed as a parallel resistor R_P and capacitor C_P network in series with a resistor R_S. We extract numerical values of these parameters by fitting experimental data. Their evolution with bias voltages has shown that the SCLC mechanism is characterised by an exponential trap distribution.     

象山港黄墩支港菲律宾蛤仔种群COI和ITS1基因序列特征及遗传多样性分析

为了解象山港黄墩支港菲律宾蛤仔种质资源的遗传多样性现状, 采用COI和ITS1分子标记对该种群进行了基因序列特征和遗传多样性分析. 结果表明 在该种群30个个体中扩增得到的COI基因序列长度均为709bp, ITS1序列长度范围在693~729bp(共有746个位点). COI基因序列的位点中有670个保守位点(占94.50%)、39个变异位点(占5.50%); ITS1序列的位点中有保守位点671个(占89.95%)、变异位点62个(占8.31%)和缺失/插入位点13个(占1.74%). COI基因序列的保守性高于ITS1序列. 在COI基因序列中碱基(A+T)的占比(65.84%)高于(C+G), 而ITS1序列中则是碱基(A+T)占比(37.59%)低于(C+G). COI和ITS1序列的遗传距离分析均显示群体内遗传分化不明显. 基于COI基因序列和ITS1序列构建的遗传进化树显示 各科贝类分别相聚, 象山港菲律宾蛤仔位于帘蛤科的分支中, 其COI序列与杂色蛤进化关系最近. 遗传进化树中各种贝类的聚类关系与传统分类学结果相一致, 可作为分类的参考. COI和ITS1序列的平均核苷酸差异数分别为5.497和6.549, 核苷酸多样性指数分别为0.00775和0.00973, 单倍型数目分别为21和28, 单倍型多样性分别为0.963和0.993, 根据COI和ITS1两个序列计算得到的菲律宾蛤仔象山港群体单倍型多样性均大于0.5, 核苷酸多样性指数均大于0.005, 表明该种群遗传多样性丰富, 并处于稳定状态. 本研究结果补充了菲律宾蛤仔遗传多样性方面的研究资料, 并可为象山港菲律宾蛤仔种质资源保护和遗传育种提供理论基础.     

Dynamics of ellipsoidal cavities in fluid

A mathematical model of the hydrodynamics of free closed surfaces in a fluid is expounded. It is used for studying the dynamics of ellipsoidal cavities during their development. The model is based on a system of differential equations that accounts for the influence exerted on the dynamics of cavities by various perturbations such as gravity, surface tension, viscosity, and geometrical features of the cavity. Solving this system makes it possible to determine the hydrodynamic characteristics of the flow around the cavity and to plot cavity shapes depending on time and flow regimes. Characteristic features of the development of such cavities under gravity and surface tension are established __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 2, pp. 24–31, February 2006.     

Influence of the coupling of mechanical and thermal fields on the amplitude-frequency characteristics of a cylinder

A dynamic boundary-value problem of coupled thermoelasticity for a finite cylinder with mixed boundary conditions is solved. The problem is reduced to a system of four singular integral equations solved by the mechanical-quadrature method. A numerical experiment is conducted to obtain amplitude-frequency characteristics for finite cylinders with different cross sections. The effect of thermoelastic coupling on stress distribution is assessed __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 10, pp. 86–95, October 2006.     

双螺杆转子的受力分析

从双螺杆转子螺旋曲面的参数方程出发，利用空间解析几何理论将转子三维螺旋面坐标映象为对应不同压力腔的二维积分区域，在整个积分区域积分可以计算作用在双螺杆压缩机，双螺杆泵螺旋面转子上的力和力矩。本文以一种双螺杆泵的转子为例，利用本方法进行了受力分析，解析出转子受力，力矩随转子转角的变化关系。     

二维系统传递矩阵法

以薄板横向振动的振动特性问题为例提出了二维系统传递矩阵法. 从质点和无质量梁的传递 矩阵出发，建立了按列排列的薄板子结构的传递矩阵. 用二维系统传递矩阵法获得了整个板 的总体传递方程，从而可得到板在任意一种边界条件下的特征方程. 数值求解了两种情况下 薄板横向振动的固有振动特性. 计算结果表明，用该方法可用于研究类似薄板的二维系统的 动力学问题，且无需建立系统的总体动力学方程.