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排序方式: 共有409条查询结果,搜索用时 531 毫秒
1.
本文针对一类非饱和土壤水流问题,提出了基于二次插值的特征差分格式,得到了严谨的L2模误差估计.并作了数值试验,指明方法的有效性. 相似文献
2.
Infrared and nuclear magnetic resonance (NMR) spectroscopies have been applied for quantitative comparison on unsaturated bonds in tetrafluoroethylene (TFE)-propylene (P)-vinylidene fluoride (VdF) terpolymers. These spectroscopies have led to consistent results while they are based on completely different principles. It is shown that the absolute concentration can be evaluated from NMR measurements. The behavior of unsaturation has been discussed in terms of after-treatment such as wet and dry treatments. The result obtained here can give the important information to improve the performance of fluoroelastomer based on TFE-P-VdF terpolymers. 相似文献
3.
Haim Gvirtzman Mordeckai Magaritz Eugenia Klein Arie Nadler 《Transport in Porous Media》1987,2(1):83-93
Cold stage Scanning Electron Microscopy (SEM) with a rapid cooling technique makes it possible to investigate the water phase within unsaturated porous media. It is thought that this technique preserves the main features of the micromorphology of the water menisci as it exists in the liquid phase in soils. Saddle-shaped elements, as well as pendular rings of water, were observed with concave and convex curvatures of the water-air interface. The hydraulic conductivity of an unsaturated soil may be inferred from SEM photographs. Observations of isolated water menisci indicate the existence of an immobile water domain. The surface geometry of the water menisci was analyzed quantitatively and surface tension and capillary pressure were determined. 相似文献
4.
A series of unsaturated polyesters based on phthalic anhydride (PHA), maleic anhydride (MA), ethylene glycol (EG), diethylene glycol (DG), triethylene glycol (TG), propylene glycol (PG), styrene (Sty) and acrylonitrile (AN) were prepared. The molecular weights of the prepared polyesters were determined by end-group analysis. The effect of the structure of the resin on its curing behavior has been investigated. On the basis of the experimental study, the following were concluded: (1) The maximum curing temperature (Tmax) is related to the molecular weight of the glycol incorporated in these castings. In this context the Tmax was found to decrease with increasing the molecular weight. Meanwhile the time to peak temperature tmax was increasing. (2) The higher the percentage of AN in the crosslinking monomer system, the slower a resin cures. (3) The values of Tmax were found to be influenced to a large extent by the percentage of AN. 相似文献
5.
Melvin Keith Carter 《Journal of molecular catalysis. A, Chemical》2003,200(1-2):191-203
Catalytic air oxidation of the aliphatic hydrocarbons n-decane, hexanes, gasoline and diesel fuel was conducted at ambient temperature with novel iron catalysts. The concentration of n-decane in water was reduced from 1.42 g in 100 ml to 0.07 g in 100 ml in 5 h at room temperature forming carbon monoxide and water by means of intermediate aldehydes. Results of FT–IR and GC–MS analyses demonstrated formation of aldehydes and unsaturated alcohols. Carbon monoxide was detected on catalyst residues and in the vapor phase. The indicated catalytic reaction mechanisms are discussed. 相似文献
6.
以二(苯腈)-二氯化钯为催化剂,在固液相转移条件下,通过芳卤与N,N-二乙基丙烯酰胺发生偶联反应,生成了E式α,β-不饱和酰胺。碘代芳烃的偶联产率较高,从而建立了简便的2E-不饱和酰胺立体选择合成法。 相似文献
7.
Principal component analysis (PCA) is applied to 32 disubstituted unsaturated compounds (Y–CH2–X): cyanides, oximes and propenes; bearing 12 -substituents: F, Cl, Br, I, OMe, OEt, SMe, SEt, NMe2, NEt2, Me, and Et. The experimental 13C chemical shifts for the -carbon and functional carbon atoms are correlated with theoretically derived molecular properties, i.e. partial charges, electronegativity, hardness, dipole moments and the nuclear repulsion energies. In the first PCA, the clustering of these three classes of organic compounds occurred mostly because of the chemical shifts and partial charges, and also of the dipole moments, hardness and electronegativity parameters as confirmed by loading graph. A strong grouping is observed in the second PCA, showing the chemical shift dependence on the type of heteroatom substituents. Therefore, sulfur, nitrogen, oxygen and neutral groups exhibit four types of C-13 SCS influences, indicating that the heteroatom (Y) properties play a significant role on the effects on chemical shifts. The -halogenated compounds represent a very heterogeneous group due to possible orbital interactions between the functional group and the substituent. The third PCA shows the grouping of F, Cl, Br and I derivatives, confirming the second PCA results that same halogen presents the same or very similar effects on the chemical shifts. 相似文献
8.
Behzad Zeynizadeh 《中国化学会会志》2005,52(3):525-530
α,β‐Unsaturated aldehydes and ketones were reduced readily and exclusively to their corresponding allylic alcohols with NaBH4 and catalytic amounts of titanyl acetylacetonate at room temperature. Reduction reactions were carried out in CH3CN or THF. This reducing system was also efficient for the reduction of α‐diketones and acyloins to their corresponding vicinal diols in CH3CN. 相似文献
9.
Poly(methyl acrylate)-b-poly(5,6-benzo-2-methylene-1, 3-dioxepane) (PMA-b-PBMDO) was synthesized by two-step atom transfer radical polymerization (ATRP). Firstly, ATRP of methyl acrylate (MA) was realized using ethyl α-bromobutyrate (EBrB) as initiator in the presence of CuBr/2,2'-bipyridine. After isolation, poly(methyl acrylate) withterminal bromine (PMA-Br) was synthesized. Secondly, the resulting PMA-Br was used as a macromolecular initiator in theATRP of BMDO. The Structure of block copolymer was characterized by ~1H-NMR spectroscopy. Molecular weight andmolecular weight distribution were determined on a gel permeation chromatograph (GPC). 相似文献
10.
Hideo Kurosawa 《Journal of organometallic chemistry》2004,689(24):4511-4520
This review summarizes the author’s contributions to the field of chemistry of group 10 metal complexes containing unsaturated hydrocarbon ligands, with a brief introduction showing how his research subject has shifted from mononuclear type to multinuclear type complexes. New structure and reactivity trends in the multipalladium complexes with bridging allyl and allenyl/propargyl ligands, as well as bridging conjugated polyene molecules are discussed in terms of some unique bonding features of these complexes. 相似文献