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991.
The steady state of temperature modulated power compensation DSC has been theoretically investigated for measurements of complex
heat capacity, taking accounts of heat capacities of heat paths, heat loss to the environment, and mutual heat exchange between
the sample and the reference material. Thermal contact between the sample cell and the cell holder is also taken into accounts.
Rigorous and general solutions are obtained. From these solutions application of the technique to heat capacity measurements
is discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
992.
Z. L. Zhang M. H. Zhong F. M. Liu F. P. Zhong F. Wu 《Journal of Thermal Analysis and Calorimetry》1999,58(2):413-419
An apparatus to study the battery system has been set up. The thermal effects of charge and discharge of Ni-MH batteries have been studied. The calorimetric measurements indicate that the net heat dissipation during charging is larger than that during discharging. It is observed that the ratio of heat dissipation to charging energy varies with charging capacity, and almost 90 percent of charging energy is lost as heat dissipation near the end of the charging process at 97.7 mA. A jump of thermal curve near the end of discharge due to a secondary electrode reaction has been observed.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
993.
Tan Zhi-Cheng Zhang Ji-Biao Shang-He Meng 《Journal of Thermal Analysis and Calorimetry》1999,55(1):283-289
A computerized adiabatic calorimeter for heat capacity measurements in the temperature range 80–400 K has been constructed.
The sample cell of the calorimeter, which is about 50 cm3 in internal volume, is equipped with a platinum resistance thermometer and surrounded by an adiabatic shield and a guard
shield. Two sets of 6-junction chromel-copel thermocouples are mounted between the cell and the shields to indicate the temperature
differences between them. The adiabatic conditions of the cell are automatically controlled by two sets of temperature controller.
The reliability of the calorimeter was verified through heat capacity measurements on the standard reference material α-Al2O3. The results agreed well with those of the National Bureau of Standards (NBS): within ±0.2% throughout the whole temperature
region. The heat capacities of high-purity graphite and polystyrene were precisely measured in the interval 260–370 K by using
the above-mentioned calorimeter. The results were tabulated and plotted and the thermal behavior of the two materials was
discussed in detail. Polynomial expressions for calculation of the heat capacities of the two substances are presented.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
994.
Tojo T. Atake T. Mori T. Yamamura H. 《Journal of Thermal Analysis and Calorimetry》1999,57(2):447-458
The heat capacity of 9.70 and 11.35 mol% yttria stabilized zirconia ((ZrO2)1–x(Y2O3)x; x=0.0970, 0.1135) was measured by adiabatic calorimetry between 13 and 300 K, and some thermodynamic functions were calculated and given in a table. A large excess heat capacity extending from the lowest temperature to room temperature with a broad maximum at about 75 K was found in comparison with the heat capacity calculated from those of pure zirconia and yttria on the basis of simple additivity rule. The shape of the excess heat capacity is very similar to the Schottky anomaly, which may be attributed to a softening of lattice vibration. The amount of the excess heat capacity decreased with increasing yttria doping, while the maximum temperature did not vary. The relationships among the excess heat capacity, defect structure and interatomic force constants, and also the role of oxygen vacancy were discussed.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
995.
吸附式空调的性能研究 总被引:6,自引:0,他引:6
1引言近年来固体吸附式制冷或热泵得到了制冷工程研究领域的普遍关注,已有各种吸附式制冷机/热泵被开发研制的报导,其中大多数是活性炭一甲醇、分子筛一水、硅胶一水、氯化钙一氨以及金属氢化物一氢等。其中比较典型的有太阳能热利用的间隙式制冷机[‘]、回热型循环制冷机[‘]和复叠式制冷系统[’]。新的热力循环,如热波型制冷循环l‘]和对流热波型制冷循环问也在不断研究探索之中。对吸附式制冷的研究兴趣主要在于这种制冷方式没有CFCS方面的问题、其价格效用比高、结构简单、与吸收式制冷系统比不需溶液泵或分馏装置,另外它… 相似文献
996.
1前言随着电子计算机技术的飞速发展,电路的集成化程度日益提高,芯片的热负荷也不断增大。据报道,在本世纪末,芯片表面热流密度将达106W/m‘II]。如果没有有效的冷却技术,芯片温度一旦超过设计标准,就会导致性能急剧恶化,故障率大大增加。而目前工业上普遍采用的风冷技术,无论是自然对流还是强迫对流,都由于空气热容小,流速受到噪声的限制又不可过大,因此冷却能力一般不超过10‘W/m‘[‘]。在这种情况下,冷却技术的改进对微电子发展起着至关重要的作用。射流冷却时流体法向冲击传热表面,形成很薄的速度和温度边界层,因… 相似文献
997.
大平板瞬态热传导问题的一种新的近似解法 总被引:1,自引:0,他引:1
1引言大平板瞬态热传导问题有着广泛的工程应用背景。对于复杂的初边值条件或含内热源问题,以及工程上常见的多层复合平壁对象,分析求解难度很大甚至无法求解。在此类情况下往往采用数值方法。但是单纯的数值解不便于理解影响该问题的各种参数的物理意义。因此,各种近似分析方法得到了发展[1,2]。但在近似精度上,往往难以对整个时间坐标范围都达到较高的精度,这就使得近似解更多地局限于定性分析。此外,对于不同的初边值条件或含内热源问题,近似解的形式相异,降低了解的通用性。增加了求解的工作量。本文提出一种基于矩阵理论… 相似文献
998.
999.
1000.
This paper gives the general solutions of axial symmetrical ring shells for all values of slenderness ratio. This solution is newly brought out, and can be used to solve various practical problems, including corrugated tubes, thermal expansion joints, Borden tubes, etc. 相似文献