基于形变晶粒增殖过程的弹塑性本构模型*

本文根据多晶金属变形的细观过程特征,将形变晶粒分为三类.提出塑性形变晶粒增殖的概念,并由此导出较为简洁的弹塑性本构关系.能对若干实验结果给出合理的解释.表明材料的宏观屈服、率相关和加工硬化等现象与形变晶粒演化的动力学过程密切相关.     

Micro–macro approach for the rock salt behaviour

Rock salt is considered as a pure aggregate of halite (mineral NaCl) crystals and its behaviour is investigated by a micro–macro approach. The behaviour of the polycrystalline aggregate is deduced from the properties of the constituent halite crystals. A model for the elastoplastic behaviour of halite crystal has been deduced from experimental data available in the literature. The basic equations of the micro–macro model for the polycrystalline medium and the calculation method are then presented and the elastoplastic behaviour of rock salt is investigated by this method. The hardening effects obtained for the polycrystal are found to be very different from those obtained for FCC metal polycrystals. The differences are explained as a consequence of differences of families of glide systems in these crystals. Finally, the internal stresses in the polycrystal are studied in order to elucidate the origin of cracking and damage of the rock salt.     

ZnSe多晶化学机械抛光研究

本文针对ZnSe多晶的性能,在试验的基础上,研究出一套实用的、行之有效的ZnSe多晶加工工艺,并重点讨论了化学机械抛光工艺.同时对加工后零件的工艺参数、表面质量及透过率的测试,结果表明所采用的化学机械加工法可取得非常好的抛光效果.     

低温制备≥99.5;多晶氧化铝陶瓷

本文通过引入稀土氧化物Y2O3、Tm2O3为烧结助剂低温制备了氧化铝含量大于99.5;的多晶氧化铝陶瓷.实验表明:稀土氧化物的加入能够明显降低99.5;多晶氧化铝陶瓷的烧结温度,提高致密度.Y2O3、Tm2O3混合烧结助剂与单一稀土氧化物的烧结助剂相比能够明显抑制晶粒的生长,促进晶粒的均匀发育.当Y2O3+Tm2O3的含量为0.3;质量分数时,99.5;多晶氧化铝陶瓷的相对密度可达99.2;理论密度,抗弯强度为533MPa,显微硬度为17.2GPa.陶瓷断裂主要以穿晶断裂为主.     

PREDICTION OF YIELD FUNCTIONS ON BCC POLYCRYSTALS

By the nonlinear optimization theory, we predict the yield function of single BCC crystals in Hill's criterion form. Then we give a formula on the macroscopic yield function of a BCC polycrystal Ω under Sachs' model, where the volume average of the yield functions of all BCC crystallites in Ω is taken as the macroscopic yield function of the BCC polycrystal. In constructing the formula, we try to find the relationship among the macroscopic yield function, the orientation distribution function (ODF), and the single BCC crystal's plasticity. An expression for the yield stress of a uniaxial tensile problem is derived under Taylor's model in order to compare the expression with that of the macroscopic yield function.     

室温铁磁性Sr3YCo4O10.5+δ多晶有序化的烧结工艺及电磁性能

采用固相反应法制备了不同烧结温度(950~1 180 ℃)、烧结时间、烧结次数共7种工艺的Sr₃YCo₄O_10.5+δ多晶块材,通过热分析、XRD、SEM确定了有序化相变和最佳烧结工艺(1 180 ℃/24 h+1 180 ℃/24 h),并研究了多晶的电磁性能。结果表明,964 ℃完全晶化的四方相Sr₃YCo₄O_10.5在1 042 ℃吸氧(δ)完成有序化,生成Sr₃YCo₄O_10.5+δ,而1 100 ℃和1 180 ℃烧结的样品均出现(103)、(215)超结构峰,验证了其结构的有序性。块材均呈半导体电输运行为,二次烧结晶格完整性提高,晶粒长大,300 K时电阻率仅为0.06 Ω·cm,居里温度(T_c)~335 K,零场冷曲线(ZFC)上的Hopkinson峰源于低温时被冻结的磁矩随温度升高转向磁场方向,磁化强度在298 K达到最大,随后受热扰动的影响减小。室温铁磁性源于有序结构导致的中自旋或高自旋态Co³⁺的e_g轨道有序。     

高压下金刚石烧结体系中的界面结合问题和新型多晶金刚石的研究

 进行了高压下金刚石掺质烧结机制有关的理论和实验研究。考虑到掺质和尺寸效应，得到了金刚石烧结体系中拉普拉斯第二定律的一个普适性方程和相应的界面结合特征方程。报导了高压下金刚石和掺质物行为的若干实验和分析结果。在此基础上获得具有特种界面结构的新型多晶金刚石。这种金刚石在拉丝模，特别在成品拉丝模的应用上显出其优越性。它的用途正在扩大。     

溶剂热法合成无水NaBiO3多晶粉末

Anhydrous NaBiO₃ polycrystal powders have been prepared through a new process in which the alkoxides were used as precursors and the parent ROH as medium. The influences of precursors and medium for products were investigated. The reducibility of Bi(Ⅲ) in solvthermal process and the morphology of NaBiO₃ powders were studied.     

Scalable Wet Deposition of Zeolite AEI with a High Degree of Preferred Crystal Orientation

Producing zeolite films with controlled preferred orientation on an industrial scale is a long‐standing challenge. Herein we report on a scalable approach to the direct wet deposition of zeolite thin films and membranes while maintaining a high degree of control over the preferred crystal orientation. As a proof of concept, thin films comprising aluminophosphate zeolite AEI were cast on silicon wafer or porous alumina substrates. Electrical properties and separation performance of the zeolite thin films/membranes were engineered through controlling degree of preferred crystal orientation.