全文获取类型
收费全文 | 345篇 |
免费 | 25篇 |
国内免费 | 364篇 |
专业分类
化学 | 607篇 |
晶体学 | 6篇 |
力学 | 2篇 |
综合类 | 2篇 |
数学 | 68篇 |
物理学 | 49篇 |
出版年
2024年 | 1篇 |
2023年 | 5篇 |
2022年 | 7篇 |
2021年 | 13篇 |
2020年 | 13篇 |
2019年 | 13篇 |
2018年 | 10篇 |
2017年 | 14篇 |
2016年 | 13篇 |
2015年 | 17篇 |
2014年 | 14篇 |
2013年 | 31篇 |
2012年 | 29篇 |
2011年 | 26篇 |
2010年 | 26篇 |
2009年 | 39篇 |
2008年 | 38篇 |
2007年 | 33篇 |
2006年 | 40篇 |
2005年 | 41篇 |
2004年 | 37篇 |
2003年 | 30篇 |
2002年 | 29篇 |
2001年 | 23篇 |
2000年 | 29篇 |
1999年 | 32篇 |
1998年 | 28篇 |
1997年 | 18篇 |
1996年 | 15篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 12篇 |
1991年 | 7篇 |
1990年 | 11篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有734条查询结果,搜索用时 312 毫秒
91.
92.
93.
WeiLi Yao 《中国科学 数学(英文版)》2014,57(10):2103-2110
The purpose of this paper is to study the distribution of integers with a given number prime divisors over arithmetic progressions, via using the large-sieve inequality, Huxley-Hooley contour and the zero-density estimate, and present a Barban-Davenport-Halberstam type theorem for it. 相似文献
94.
以USY分子筛作为载体,Ni和Mo作为活性组分,利用超声辅助浸渍法(US-IM)和常规浸渍法(C-IM)制备了Ni/USY(US-IM)和Ni-Mo/USY催化剂.采用X射线衍射(XRD)、吡啶-红外光谱分析(Py-IR)和N2吸附-脱附等对催化剂进行理化性质表征,综合考察了不同改性方法以及单金属和双金属改性前后分子筛酸性和孔结构性质等的变化及其对正庚烷异构化性能的影响.实验结果表明:Mo对于Ni在USY分子筛上的均匀分布以及异构化催化性能具有协同促进作用;超声条件对双金属改性的USY结构基本无影响;超声空化作用降低了催化剂金属粒子的团聚,使其在USY表面均匀分散,增加了催化反应中所需的金属活性位点.超声辅助浸渍制备的Ni-Mo/USY中较高的金属分散度导致了较强的金属-载体相互作用,使其活性和稳定性高于常规浸渍法.在优化超声条件下,反应温度和反应时间分别为250℃和3 h,还原温度和还原时间分别为550℃和5 h,H2/C7摩尔比为0.14时,正庚烷的转化率和异构化选择性分别可以达到65.7%和74.1%. 相似文献
95.
An integer n is called lexicographic if the increasing sequence of its divisors, regarded as words on the (finite) alphabet of the prime factors (arranged in increasing size), is ordered lexicographically. This concept easily yields to a new type of multiplicative structure for the exceptional set in the Maier-Tenenbaum theorem on the propinquity of divisors, which settled a well-known conjecture of Erdös. We provide asymptotic formulae for the number of lexicographic integers not exceeding a given limit, as well as for certain arithmetically weighted sums over the same set. These results are subsequently applied to establishing an Erdös-Kac theorem with remainder for the distribution of the number of prime factors over lexicographic integers. This provides quantitative estimates for lexicographical exceptions to Erdos' conjecture that also satisfy the Hardy-Ramanujan theorem. 相似文献
96.
采用巨正则统计系综Monte Carlo模拟方法研究了不同温度、不同吸附方式下纯硅MCM-22型分子筛ITQ-1上苯与丙烯分子的吸附行为. 分子筛内吸附质粒子云分布模拟结果显示, 苯和丙烯主要吸附在超笼和十元环孔道内, 其中丙烯分子几乎充满了孔道内部大部分区域, 在链接超笼之间的十元环窗口也充满了丙烯分子, 而苯分子在超笼内和十元环孔道内的吸附却较为分散、均匀. 丙烯与分子筛之间相互作用能高于苯与分子筛之间的相互作用能, 使苯分子吸附相对丙烯分子更为稳定. 温度变化对分子筛上丙烯吸附远大于对苯吸附的影响, 100 kPa时温度由298 K升高至443 K导致丙烯分子吸附量迅速减少, 而对苯分子却没有显著的影响. ITQ-1分子筛上存在苯和丙烯分子的竞争吸附, 使两者吸附相互作用能最可几分布朝着折中方向移动. 苯与丙烯在分子筛内吸附等温线的模拟结果表明, 在温度较高、压力较低时, 丙烯的吸附量小于苯的吸附量. 相似文献
97.
CoMCM-41 mesoporous molecular sieves with different amounts of cobalt were synthesized via the microwave irradiation method. The samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR), temperature programmed reduction (TPR), transmission electron microscopy (TEM) and N2 adsorption-desorption technique, and thermal and hydrothermal stabilities of synthesized CoMCM-41 samples were also investigated. Results show that these synthesized materials have typical mesoporous structure of MCM-41. Also, specific surface area and pore volume of synthesized CoMCM-41 decrease with increasing amount of cobalt added, and mesoporous ordering also decreases. When the molar ratio of SiO2:CoO in the starting material is 1.0:0.05, mesoporous ordering of synthesized CoMCM-41 is the best among the four doping contents. On the other hand, results of thermal and hydrothermal tests show that CoMCM-41 after calcination at 750 °C for 3 h or hydrothermal treatment at 100 °C for 5 days still retains mesostructure. However, mesoporous framework is entirely damaged after calcination at 850 °C for 3 h. 相似文献
98.
99.
ZHAO Di-shun LI Fa-tang ZHOU Er-peng SUN Zhi-min 《高等学校化学研究》2008,24(1):96-100
Photochemical oxidation of thiophene in n-octane/water extraction system using O2 as oxidant was studied. The reaction mechanism ofthiophene oxidation was proposed. Results obtained here can be used as the reference for the oxidative desulfurization of gasoline because thiophene is one of the main components containing sulfur in fluid catalytic cracking gasoline. Thiophene dissolved in n-octane was photodecomposed and removed into the water phase at ambient temperature and atmospheric pressure. A 500 W high-pressure mercury lamp (main wave length 365 nm, 0.22 kW/m) was used as light source for irradiation, and air was introduced by a gas pump to supply O2. Thiophene can be photo-oxidized to sulfone, oxalic acid, SO4^2-, and CO2. The desulfurization yield of thiophene in n-octane is 58.9% under photo-irradiation for 5 h under the conditions of air flow at 150 mL/min and V(water):V(n-octane)=1:1. It can be improved to 92.3% by adding 0.15 g zeoliteartificial into 100 mL reaction system, which is the adsorbent for O2 and thiophene. And under such conditions, the photo-oxidation kinetics of thiophene with O2/zeoliteartificial is first-order with an apparent rate constant of 0.5047 h^-1 and a half-time of 1.37 h. The sulfur content can be depressed from 800 μL/L to less than 62 μL/L. 相似文献
100.
先采用均匀沉淀法制备出CuO—ZnO催化剂,然后以CuO—ZnO催化剂作为晶核采用水热合成法制备出CuO—ZnO/HZSM-5(氢型ZSM-5分子筛)复合催化剂.利用X射线衍射和氨程序升温脱附手段对复合催化剂进行表征,并应用于CO2催化加氢合成二甲醚的反应.研究结果表明,在相同的反应条件下,这种CuO—ZnO/HZSM-5复合催化剂与采用物理混合法制备出的复合催化剂相比具有更好的催化效果,不但提高了CO2的转化率、二甲醚的选择性以及二甲醚和甲醇的总选择性,同时还改善了催化剂的稳定性. 相似文献