全文获取类型
收费全文 | 59032篇 |
免费 | 4385篇 |
国内免费 | 7133篇 |
专业分类
化学 | 50618篇 |
晶体学 | 344篇 |
力学 | 780篇 |
综合类 | 743篇 |
数学 | 6937篇 |
物理学 | 11128篇 |
出版年
2023年 | 573篇 |
2022年 | 919篇 |
2021年 | 2219篇 |
2020年 | 1897篇 |
2019年 | 1815篇 |
2018年 | 1556篇 |
2017年 | 1518篇 |
2016年 | 1842篇 |
2015年 | 1854篇 |
2014年 | 2514篇 |
2013年 | 4445篇 |
2012年 | 2598篇 |
2011年 | 3095篇 |
2010年 | 2624篇 |
2009年 | 3194篇 |
2008年 | 3468篇 |
2007年 | 3793篇 |
2006年 | 3129篇 |
2005年 | 2448篇 |
2004年 | 2380篇 |
2003年 | 2127篇 |
2002年 | 4194篇 |
2001年 | 1755篇 |
2000年 | 1373篇 |
1999年 | 1156篇 |
1998年 | 1068篇 |
1997年 | 881篇 |
1996年 | 908篇 |
1995年 | 834篇 |
1994年 | 790篇 |
1993年 | 740篇 |
1992年 | 722篇 |
1991年 | 458篇 |
1990年 | 370篇 |
1989年 | 312篇 |
1988年 | 327篇 |
1987年 | 251篇 |
1986年 | 257篇 |
1985年 | 368篇 |
1984年 | 282篇 |
1983年 | 168篇 |
1982年 | 325篇 |
1981年 | 502篇 |
1980年 | 456篇 |
1979年 | 484篇 |
1978年 | 395篇 |
1977年 | 308篇 |
1976年 | 275篇 |
1974年 | 115篇 |
1973年 | 175篇 |
排序方式: 共有10000条查询结果,搜索用时 890 毫秒
101.
Characterizations of Tb:Zn2SiO4 films on silicon wafer prepared by sol-gel dip-coating and solid-phase reaction 下载免费PDF全文
Terbium-doped Zn_2SiO_4 films were successfully prepared on Si wafers by a simple sol-gel dip-coating and solid-phase reaction method of ZnO and SiO_2. X-ray diffraction (XRD) and UV-Vis absorption results revealed that films processed below 850℃ were ZnO in wurzite structure, and films processed above 850℃ were Zn_2SiO_4 in wellimite structure. Photoluminescence measurements of the Tb-doped Zn_2SiO_4 films showed two strong emission bands at 490 and 545nm. The photoluminescence lifetime was 4.6ms. 相似文献
102.
Gregory S. Constable Alan J. Lesser E. Bryan Coughlin 《Journal of Polymer Science.Polymer Physics》2003,41(12):1323-1333
An in situ ultrasonic spectroscopy technique was used to study the ring‐opening metathesis polymerization of dicyclopentadiene catalyzed by bis(tricyclohexylphosphine)benzylidene ruthenium dichloride. A reaction cell employing a flexible poly(ethylene terephthalate) window for pulse echo ultrasonic spectroscopy was used to monitor the polymerization. The changes in the density, wave speed, acoustic modulus, and attenuation were all simultaneously monitored. In comparison with Fourier transform infrared (FTIR) spectroscopy data, the changes in the density, velocity, and modulus only accurately measured the rate constant for the metathesis of the cyclopentyl unsaturation. The ultrasonic values were within 6% of the values determined by FTIR. The activation energy for metathesis of the cyclopentyl unsaturation was 84 kJ mol?1, following first‐order kinetics. Rate constants for the polymerization of the norbornyl unsaturation could not be determined by ultrasound. The gel point, vitrification, and qualitative information about the reaction rate could be determined from the change in the attenuation. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1323–1333, 2003 相似文献
103.
该文讨论了一类非线性抛物型方程组解的性质,利用微分方程上、下解方法证明了初值适当小时,方程存在整体解;初值适当大时,解在有限时间上爆破,推广了文献[1]的结果. 相似文献
104.
Emmanuel DardennesÁrpád Kovács-Kulyassa Andrea RenzettiJanos Sapi Jean-Yves Laronze 《Tetrahedron letters》2003,44(2):221-223
Chiral pyrano- and pyrrolidino-fused tryptamines were prepared by a diasteroselective trimolecular condensation between indole, Garner's aldehyde and Meldrum's acid, followed by selective functional group transformations. 相似文献
105.
An intermolecular aldol reaction of 20S-camptothecin-7-aldehyde in the presence of strong bases affords an unusual dimeric compound, the structure and stereochemistry of which was assigned on the basis of NMR analysis and MM2 calculations. 相似文献
106.
Grindstone Chemistry--a greatly evolved version of Toda’s method of grinding solids together for solvent-free chemical reactions--has been described and its usefulness illustrated by the successful application of this technique to a simplified process for conducting the multi-component Biginelli reaction for the synthesis of physiologically active tetrahydropyrimidinones. 相似文献
107.
Multilinear interpolation is a powerful tool used in obtaining strong-type boundedness for a variety of operators assuming only a finite set of restricted weak-type estimates. A typical situation occurs when one knows that a multilinear operator satisfies a weak Lq estimate for a single index q (which may be less than one) and that all the adjoints of the multilinear operator are of similar nature, and thus they also satisfy the same weak Lq estimate. Under this assumption, in this note we give a general multilinear interpolation theorem which allows one to obtain strong-type boundedness for the operator (and all of its adjoints) for a large set of exponents. The key point in the applications we discuss is that the interpolation theorem can handle the case q?1. When q>1, weak Lq has a predual, and such strong-type boundedness can be easily obtained by duality and multilinear interpolation (cf. Interpolation Spaces, An Introduction, Springer, New York, 1976; Math. Ann. 319 (2001) 151; in: Function Spaces and Applications (Lund, 1986), Lecture Notes in Mathematics, Vol. 1302, Springer, Berlin, New York, 1988; J. Amer. Math. Soc. 15 (2002) 469; Proc. Amer. Math. Soc. 21 (1969) 441). 相似文献
108.
利用激光溅射 分子束的技术 ,结合反射飞行时间质谱计 ,研究了Cu+、Ag+、Au+与乙硫醇的气相化学反应。结果显示这三种金属离子与 (CH3 CH2 SH) n 反应形成一系列团簇离子M+(CH3 CH2 SH) n,且团簇离子尺寸不一样。Ag+、Au+与乙硫醇的反应还生成了 (CH3 CH2 SH) +n ,由此推测Cu+、Ag+、Au+与乙硫醇团簇的反应存在两种通道 ,一种通道是生成M+(CH3 CH2 SH) n,另一种是生成 (CH3 CH2 SH) +n 。Cu+、Au+与乙硫醇的反应还生成了M+(H2 S) (M =Cu、Au) ,但是实验中没有观察到Ag+(H2 S) ,理论计算表明Ag+(H2 S)很不稳定。另外 ,分析产物离子M+(CH3 CH2 SH) n 的强度发现 ,n =1~ 2之间存在明显的强度突变现象 相似文献
109.
5-Perfluorophenyl 4,5-dihydro-1H-pyrazoles were synthesized from 1,3-dipolar cycloaddition reaction of perfluorobenyl 2,4,6-triisopropylbenzenesulfonylhydrazone and α,β-unsaturated carbonyl compounds or acrylonitrile in THF or water. It was worthy to note that better results were obtained when water was employed as the solvent, which was considered as an effective, economic and environmentally friendly method to synthesize these pyrazole derivatives. 相似文献
110.
R. Bairava Ganesh Hitoshi Matsuo Takahiro Kawamura Yoshihiro Kangawa Koji Arafune Yoshio Ohshita Masafumi Yamaguchi Koichi Kakimoto 《Journal of Crystal Growth》2008,310(11):2697-2701
Multicrystalline silicon was grown by unidirectional solidification method using the accelerated crucible rotation technique. The application of the accelerated crucible rotation technique in unidirectional solidification method induced growth striations across the axial direction of the grown crystal. This striation pattern was observed from carbon concentration distribution, obtained by using Fourier transform infrared spectroscopy. The generated striation pattern was found to be weak and discontinuous. Some striations were absent, probably due to back melting, caused during each crucible rotation. From the growth striations and applied time period in crucible rotation, the growth rate was estimated by using Fourier transformation analysis. 相似文献