Hard magnetic properties of anisotropic Sm-Fe-N magnets produced by compression shearing method

Anisotropic Sm-Fe-N bulk magnets were produced by the compression shearing method using a hardened steel plate and a tungsten-carbide (WC) plate. It was found that the magnets retained the original Sm₂Fe₁₇N₃ phase structure without any appreciable decomposition of the Sm₂Fe₁₇N₃ phase. The anisotropic Sm-Fe-N bulk magnet produced using a WC plate had a higher density and higher crystallographic alignment of the Sm₂Fe₁₇N₃ phase than that produced using a hardened steel plate, and exhibited high maximum energy products of 228 kJ/m³ with a high coercivity of 0.88 MA/m.     

Mössbauer Investigation of the Itinerant Magnets U(Ga0.98Sn0.02)3 and CeFe2

The theoretical predictions that UGa₃ and CeFe₂ should be regarded as itinerant magnets stimulated new investigations. In this paper we focus on Mössbauer measurements aimed to characterize their magnetic properties. We show that the analysis of the transferred hyperfine interactions at the ¹¹⁹Sn nuclei in U(Ga_0.98Sn_0.02)₃, a type II antiferromagnet, provides direct information on the f-p hybridization and allows to determine the orientation of the U moments. The study of CeFe₂ demonstrates that the intrinsic ferromagnetism coexists with short range antiferromagnetic correlations. The instability of the ferromagnetic state is illustrated by doping CeFe₂ with a small amount of Co and by application of pressure on pure CeFe₂. Our results will be discussed in connection with neutron and synchrotron experiments.     

Effect of highly filled ferrites on non-isothermal crystallization behavior of polyamide 6 bonded ferrites

The aim of this study is to characterize the non-isothermal crystallization of polyamide 6 bonded highly filled ferrites which were prepared by the melt extrusion. Especially, the effect of ferrite concentration and its surface property on the non-isothermal crystallization were investigated by means of differential scanning calorimetry. The highly filled ferrite particles acting as obstacles could severely hinder the motion of surrounding chain segments, which were irrespective of surface nature. The ferrite could be modified by silane and obtain a visually enhanced interaction with polymer matrix which evoked the heterogeneous nucleation. Increasing this enhanced interfacial area between polymer-particle can promote the heterogeneous nucleation. However, a strong interaction can slow the motion of surrounding chain segments of particles, thereby producing a competitive effect on the crystallization rate and crystallinity. The plot of crystallization activation energy against concentration also can evaluate dispersion performance of hydrophilic fillers within hydrophobic polymer.     

Iridium and Rhodium as Permanent Chemical Modifiers for the Determination of Ag, As, Bi, Cd, and Sb by Electrothermal Atomic Absorption Spectrometry

Performance of graphite platforms coated with Ir, Rh, and a mixture of both, as permanent modifiers for Ag, As, Bi, Cd, and Sb, was evaluated. The coating process is very simple: a solution containing Ir, Rh, or a mixture of both is pipetted on the platform inserted in a graphite tube, and this is submitted to a temperature program. High pyrolysis temperatures are allowed, especially for As and Bi, 1400°C, in the Ir + Rh-coated platform. The sensitivity remains about the same for all analytes with different coatings, except for As in the Ir-coated platform, for which a remarkable gain was obtained in comparison to the other coatings. The lifetimes of the treated tubes were in the range 50 to more than 1000 cycles, being especially long for Sb and Ag in the Rh-coated platform, more than 600 and 1000 cycles, respectively. The Rh coating could not be used for Bi and Cd. Analysis of a certified reference water and of acid oyster tissue digests showed the absence of interference and good precision. Advantages of the permanent coatings are the possibility of low blanks byin situcleaning of the modifier and shorter analysis time.     

纳米复合永磁Pr9Fe74Co12B5Snx(x=0, 0.5)的磁化行为与磁黏滞性

用熔体快淬法制备了纳米复合永磁样品Pr₉Fe₇₄Co₁₂B₅ 与Pr₉Fe₇₄Co₁₂B₅Sn_0.5，分析了样品的起始磁化、反磁化过程，测得样品的总磁化率、可逆磁化率以及样品的磁黏滞性.结果表明，两样品在室温下均表现为单一硬磁相磁化行为，在低温下表现为双相行为，且由于添加Sn后使晶粒均匀化从而导致样品低温下的双相行为更加明显.添加Sn后引起样品中软磁相含量和软磁相晶粒尺寸的增加，使磁化反转中可逆磁化部分增多，且使反磁化形核场降低.磁黏滞性研究表明，热激活体积与软磁相晶粒的大小有关. 关键词： 纳米复合永磁 磁化反转 磁粘滞     

A new comprehensive study of the 3D random-field Ising model via sampling the density of states in dominant energy subspaces

The three-dimensional bimodal random-field Ising model is studied via a new finite temperature numerical approach. The methods of Wang-Landau sampling and broad histogram are implemented in a unified algorithm by using the N-fold version of the Wang-Landau algorithm. The simulations are performed in dominant energy subspaces, determined by the recently developed critical minimum energy subspace technique. The random-fields are obtained from a bimodal distribution, that is we consider the discrete (±Δ) case and the model is studied on cubic lattices with sizes 4≤L ≤20. In order to extract information for the relevant probability distributions of the specific heat and susceptibility peaks, large samples of random-field realizations are generated. The general aspects of the model's scaling behavior are discussed and the process of averaging finite-size anomalies in random systems is re-examined under the prism of the lack of self-averaging of the specific heat and susceptibility of the model.     

稀土永磁薄膜材料

简要地介绍在纳米复合稀土永磁薄膜材料、各向异性稀土永磁薄膜材料方面的进展。在纳米复合稀土永磁薄膜材料中实现磁性交换耦合和剩磁增强效应，系统地研究了其结构与磁性的关系。制备成功高磁能积的各向异性稀土永磁薄膜材料，比较了Ti或Mo缓冲层对Nd-Fe-B薄膜的表面形貌、磁畴结构和磁性能的影响。发现薄膜的表面形貌强烈地依赖于缓冲层的厚度。由于它极大地影响薄膜的成分，溅射速率被证明是控制薄膜的显微结构、表面形貌和磁性能的一个重要因素。在微磁学模型的基础上，通过分析从5到300K的矫顽力温度依赖关系。研究了各向异性Pr-Fe-B薄膜的矫顽力机制。在晶粒表面，由于磁各向异性的降低和局域退磁场的提高导致的反转畴的形核被确定为控制各向异性Pr-Fe—B薄膜的磁化反转过程的首要机制。     

爆炸荷载下矩形板的塑性动力响应

本文采用Jones-Sawczuk控制方程,导出了脉冲荷载下矩形板最大残余挠度的简单理论计算公式,并应用该公式和动态屈服条件,计算了固支方板在爆炸荷载下的最大残余挠度值,与试验结果比较,取得了令人满意的结果。     

加筋板结构的大变形

本文对受均布载荷，具有一根纵向加筋多根横向加筋的加筋板结构的残余变形导出了近似理论分析方法。从假设变形模态出发，依据极限分析原理获得可能变形模态和模态判别条件。在变形分析中，计及膜力（轴力）影响，但忽略弹性影响，得到了各变形模态下的残余变形估算公式。最后根据本文的理论分析方法和ＡＤＩＮＡ程序作了实例计算，两者的变形模态和最大残余变形均十分一致