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Yossef A. Elabd Marco Giacinti Baschetti Timothy A. Barbari 《Journal of Polymer Science.Polymer Physics》2003,41(22):2794-2807
Over the past 2 decades, the use of time‐resolved Fourier transform infrared/attenuated total reflection (ATR) spectroscopy for the measurement of diffusion in polymers has grown. ATR is a powerful technique for the measurement of diffusion in polymers because it is an in situ technique that is relatively inexpensive, provides reliable short‐time data, and provides a wealth of information at the molecular level. This article highlights the technique and its application to numerous studies, ranging from the diffusion of drugs in human skin to chemical warfare agents in barrier materials. In addition to these topics, recent studies with ATR to quantify and model molecular interactions during the diffusion process are reviewed. In the future, the ATR technique may have an impact on a variety of emerging fields in which diffusion in polymers plays an important role, such as fuel cells, membrane separation, sensors, and drug delivery. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2794–2807, 2003 相似文献
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为实现PTS系列频率综合器的微机控制,设计了一种简单的控制电路。在微机的控制下,通过该电路与微机的并行通讯口,用C语言编写的控制程序可以很方便的控制频率综合器的输出频率。控制程序采用菜单操作,电路所需的+5V电源由微机提供,整个控制系统简单实用,值得推广。 相似文献
75.
活性酚醛树脂中羟甲基含量的测定 总被引:12,自引:0,他引:12
本文提出一种酚醛树脂中羟甲基含量的化学分析法,分别以^13CNMR和化学分析法测定酚醛树脂的羟甲基含量。将两种测试结果与已知的投料量进行比较,证明所建立的化学分析法可行。 相似文献
76.
The synthesis and characterisation of five newβ-aminodiketones is reported: (a) 3,3,5,8,10,10-hexamethyl-5,8-diazadodecane-2,11-dione; (b) 3,3,11,11-tetramethyl-5,8-diazatridecane-2,12-dione;
(c) 3,3,12,12-tetramethyl-5,10-diazatetradecane-2,13-dione; (d) 3,3,10,10-tetramethyl-5,8-diphenyl-5,8-diazadodecane-2,11,dione
and (e) 6,7-benzo-3,3,10,10-tetramethyl-5,8-diazadodecane-2,11-dione. These compounds are discussed as potential precursors
in the synthesis of tetra-aza macrocyclic complexes. 相似文献
77.
Spherical, smooth-surfaced and mechanically stable alginate-poly(L-histidine) (PLHis) microcapsules with narrow particle size distributions were prepared by incubating calcium alginate beads in aqueous solutions of PLHis. The in vitro release characteristics, drug loading and encapsulation efficiency of the microcapsules were investigated using bovine erythrocytes hemoglobin (Hb) as a model drug. The results showed that the concentration of Ca(2+) ions had a considerable effect on the drug loading, encapsulation efficiency and in vitro release behavior of the microcapsules. When the concentration of CaCl(2) in the PLHis solution was increased from 0 to 3.0% (w/v), the drug loading and encapsulation efficiency decreased significantly from 38.0 to 4.3% and from 92.9 to 8.0%, respectively, while the total cumulative release of Hb from microcapsules in phosphate buffered saline solution (PBS, pH 6.8) decreased from 96.2 to 72.8% in 24 h. No significant protein release was observed during 70 h of incubation in hydrochloric acid solution (pH 1.2). However, under neutral conditions (PBS, pH 6.8), the Hb was completely and stably released within 24-70 h. An explosion test showed that the stability of alginate-PLHis microcapsules depended strongly on the concentration of PLHis and the calcium ions in solution. [Diagram: see text] Microscopy photo of Hb-loaded alginate-PLHis microcapsules. 相似文献
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A study of carboxylic-modified mesoporous silica in controlled delivery for drug famotidine 总被引:2,自引:0,他引:2
A series of pure silica MSU and carboxylic-modified MSU materials were prepared. The formation of mesoporous silica materials with terminal carboxylic groups on pore surface was performed by the acid-catalyzed hydrolysis of cyano to carboxylic. Then their potential applications in controlled drug delivery carriers were investigated. Drug famotidine was selected as a model molecule out of the consideration of the terminal amino groups in its molecule. The adsorption experiments show significant adsorption of famotidine on the carboxylic-modified MSU materials. And, the functionalization level of carboxylic groups has been found to be the key factor affecting the adsorption capacities of the modified MSU materials for famotidine. Subsequently, three kinds of release fluids, including simulated gastric medium, simulated intestinal medium, and simulated body fluid, were used to test the famotidine release rate from the carboxylic-modified MSU material. Obvious delayed effect has been observed for the famotidine release from the carboxylic-modified mesoporous silica material under the in vitro assays. 相似文献