Quantum teleportation by entanglement swapping with trapped ions

An effective teleportation scheme for an unknown ionic internal state via trapped ions is proposed without joint Bell-state measurement (BSM). In the constructed quantum channel process, we make use of entanglement swapping to avoid decrease in entanglement during the distributing of particles. Thus our scheme provides new prospects for quantum teleportation in a longer distance. The distinct advantage of our scheme is insensitive to the heating of vibrational mode. Furthermore, our scheme has no any individual optical access, and the successful probability also can reach 1.     

Quantum logic gates with two-level trapped ions beyond Lamb--Dicke limit

In the system with two two-level ions confined in a linear trap, this paper presents a simple scheme to realize the quantum phase gate (QPG) and the swap gate beyond the Lamb--Dicke (LD) limit. These two-qubit quantum logic gates only involve the internal states of two trapped ions. The scheme does not use the vibrational mode as the data bus and only requires a single resonant interaction of the ions with the lasers. Neither the LD approximation nor the auxiliary atomic level is needed in the proposed scheme. Thus the scheme is simple and the interaction time is very short, which is important in view of decoherence. The experimental feasibility for achieving this scheme is also discussed.     

Controlling optical responses through local dielectric resonance in nanometre metallic clusters

Optical responses in dilute composites are controlled through the local dielectric resonance of metallic clusters. We consider two located metallic clusters close to each other with admittances \varepsilon₁ and \varepsilon₂. Through varying the difference admittance ratio \eta [ = (\varepsilon₂- \varepsilon ₀) / (\varepsilon₁- \varepsilon₀)], we find that their optical responses are determined by the local resonance. There is a blueshift of absorption peaks with the increase of \eta. Simultaneously, it is known that the absorption peaks will be redshifted by enlarging the cluster size. By adjusting the nano-metallic cluster geometry, size and admittances, we can control the positions and intensities of absorption peaks effectively. We have also deduced the effective linear optical responses of three-component composites \varepsilon_e= \varepsilon₀ \bigl(1 + \sum_n=1^{n_s} [(\gamma_n2+ \eta \gamma_n2)/({\varepsilon₀(s - s_n))]} \bigr), and the sum rule of cross sections: \sum_n=1^{n_s} {(\gamma_n2+ \eta \gamma_n2 ) = N_h1+ N_h2, where N_h1and N_h2 are the numbers of \varepsilon₁ and \varepsilon₂ bonds along the electric field, respectively. These results may be beneficial to the study of surface plasmon resonances on a nanometre scale.     

Cluster states prepared by using hot trapped ions

We propose a scheme for the preparation of one-dimensional and two-dimensional cluster states by using hot trapped ions. The scheme is based on the interaction between two ions and bichromatic radiation. The vibrational mode in our protocol is only virtually excited so that the system is insensitive to the thermal field. In addition, we only use two levels of ions as qubits and the successful probability may achieve 100%.     

Non-Ionic Water-Soluble Crown-Ether-Substituted Polyfluorene as Fluorescent Probe for Lead Ion Assays

A new non-ionic water-soluble polyfluorene that contains two benzo-18-crown-6 side chains per repeat unit (PFDC) is synthesized and characterized. Upon addition of Pb²⁺ ions to a solution of PFDC, the PFDC fluorescence is strongly quenched. The minor interference from other metal ions, especial from Cu²⁺ and Hg²⁺ions, clearly shows that the PFDC can be used to detect Pb²⁺ ions with high selectivity. The fluorescence quenching of PFDC in solution originates from the multivalent coordination of the crown-ether moieties to Pb²⁺ ions followed by precipitation. In comparison to ionic conjugated polymers, the pH of the medium shows less effect on the binding of non-ionic PFDC to Pb²⁺ ions.

     

荧光光谱法研究锌(Ⅱ)存在下诺氟沙星与牛血清白蛋白的结合作用

在模拟生理条件下,用荧光光谱法研究了诺氟沙星对牛血清白蛋白以及锌(Ⅱ)对诺氟沙星和牛血清白蛋白荧光光谱特性的影响。实验结果表明,诺氟沙星和锌(Ⅱ)都可以使牛血清白蛋白的荧光强度发生猝灭。根据荧光猝灭双倒数图计算诺氟沙星和牛血清白蛋白之间的结合常数为6.80×105,结合位点数为1.21。由此可见,诺氟沙星和牛血清白蛋白之间有很强的结合作用,这为诺氟沙星在体内被蛋白质储存和转运提供了条件。并且在锌(Ⅱ)存在下,诺氟沙星与牛血清白蛋白的结合作用有所增强。荧光猝灭双倒数图计算的结果表明,诺氟沙星和牛血清白蛋白之间的结合常数和结合位点数均随锌(Ⅱ)浓度的增大而增大。通过对锌(Ⅱ)、诺氟沙星和牛血清白蛋白的结合反应的研究,进一步探讨了诺氟沙星、锌(Ⅱ)在生物体内与蛋白质相互作用的机理。     

表面等离子共振(SPR)——一种新型化学检测方法的原理

近年来,表面等离子共振(SPR)现象、由于在金属纳米材料研究以及在作为灵敏检测不同化学和生化物种信号的报告器方面有着特殊的应用价值,因而受到广泛的关注.本文较详细的介绍了表面等离子共振现象的形成机制,特别对如何利用本方法作为一种新型的物种检测报告器的有关问题做了较系统的讨论.     

有机物模板合成磷酸铝

用3种模板采用固相合成方法,以氯化铝和磷酸二氢铵为原料合成了磷酸铝,产物经XRD,IR,化学分析和ICPS表征。实验结果表明它们对金属铬离子具有良好的吸附性能。     

轮古常渣及其组分中金属钒卟啉的分离与鉴定

采用改进的溶剂萃取方法对轮古常渣及其组分中的金属钒卟啉进行分离。结果表明,从轮古常渣中分离出的卟啉钒的质量分数为18.5%,从轮古常渣正庚烷可溶质和沥青质中分离出的卟啉钒的质量分数分别为68.0%和9.2%。用紫外-可见光谱对萃取出来的金属钒卟啉和甲磺酸脱金属后得到的游离卟啉进行表征。结果表明,轮古常渣及其正庚烷可溶质和沥青质中的金属钒卟啉主要是初卟啉。对轮古常渣中的游离卟啉进行基质辅助激光解吸电离飞行时间质谱分析证明,轮古常渣中的金属钒卟啉主要是初卟啉。     

The heat capacity of small metallic grains studied by the random matrices theory

The random matrices theory is applied to a study of the heat capacity of small metallic grains. The numerical calculations indicate that the level distribution and the difference between the particles respectively with an even and an odd numbers of electrons are important for the heat capacity of the small metallic grains at a low temperature and the level correlation mainly affects the heat capacity at a high temperature.