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101.
Telisha Traut‐Johnstone Frederik H. Kriel Raymond Hewer D. Bradley G. Williams 《Acta Crystallographica. Section C, Structural Chemistry》2014,70(12):1121-1124
The mixed organic–inorganic title salt, C7H18N2O2+·C2HO4−·Cl−, forms an assembly of ionic components which are stabilized through a series of hydrogen bonds and charge‐assisted intermolecular interactions. The title assembly crystallizes in the monoclinic C2/c space group with Z = 8. The asymmetric unit consists of a 4‐(3‐azaniumylpropyl)morpholin‐4‐ium dication, a hydrogen oxalate counter‐anion and an inorganic chloride counter‐anion. The organic cations and anions are connected through a network of N—H...O, O—H...O and C—H...O hydrogen bonds, forming several intermolecular rings that can be described by the graph‐set notations R33(13), R21(5), R12(5), R21(6), R23(6), R22(8) and R33(9). The 4‐(3‐azaniumylpropyl)morpholin‐4‐ium dications are interconnected through N—H...O hydrogen bonds, forming C(9) chains that run diagonally along the ab face. Furthermore, the hydrogen oxalate anions are interconnected via O—H...O hydrogen bonds, forming head‐to‐tail C(5) chains along the crystallographic b axis. The two types of chains are linked through additional N—H...O and O—H...O hydrogen bonds, and the hydrogen oxalate chains are sandwiched by the 4‐(3‐azaniumylpropyl)morpholin‐4‐ium chains, forming organic layers that are separated by the chloride anions. Finally, the layered three‐dimensional structure is stabilized via intermolecular N—H...Cl and C—H...Cl interactions. 相似文献
102.
103.
Zeynep Güven Lars Denker Hadi Dolati Daniela Wullschläger Dr. Bartosz Trzaskowski Dr. René Frank 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(32):e202200673
Donor-acceptor cyclopropanes or cyclobutanes are dipolar reagents, which are widely used in the synthesis of complex organic (hetero)cycles in ring expansion reactions. Applying this concept to boron containing heterocycles, the four-membered borete cyclo-iPr2N-BC10H6 reacted with the carbon donor ligands 2,6-xylylisonitrile and the carbene IMes :C(NMesCH)2 with ring expansion and ring fusion, respectively. In particular, the tetracyclic structure formed with IMes displays zwitterionic character and absorption in the visible region. In contrast to the carbene IMes, the heavier carbenoids :Si(NDippCH)2 and :Ga(AmIm) with a two-coordinate donor atom afford spiro-type bicyclic compounds, which display four-coordinate geometry at silicon or gallium. (TD-)DFT calculations provide deeper insight into the mechanism of formation and the absorption properties of these new compounds. 相似文献
104.
以北京师范大学化学专业的无机化学课程改革为例,从教学内容、教学方法、课程考核等方面探讨无机化学课程优化和改革。明确教学目标,提升教学质量,达成化学(师范)专业的毕业要求,全面提升学生的思想政治素养、专业知识技能和教育情怀。 相似文献
105.
回顾了吉林大学无机化学学科教材建设的历史,从恢复高考招生制度后我国的第一部无机化学教材的编写,到该书第2版、第3版的修订,到配套的无机化学实验教材及无机化学习题集、无机化学习题解答的编写,处处凝结着无机化学教师们智慧的结晶,形成了厚重的历史积淀。随着新世纪的到来,顺应新时代要求、新兴的编者队伍在教学实践中成长壮大,编写出全新的无机化学教材。经过几代教师的努力,无机化学教材不断发展和完善,形成了多层次、系统性、立体化、高质量的精品无机化学教材体系,可满足不同层次、不同专业、不同教学计划的需求,在全国高校无机化学教学活动中发挥了重要作用。 相似文献
106.
手性无机纳米材料因为具有优异的光物理特性及广泛的应用价值而备受关注。通过采用手性配体对无机纳米材料的表面进行修饰或将无机纳米材料与手性模板进行组装获得的手性结构,可以与光子强烈作用引起偏振态的改变,产生圆偏振光(circularly polarized light, CPL)。从产生机理来讲,CPL主要包括圆偏振荧光和圆偏振散射,在一些情况下这两个机理是共存的。本文总结了硫族半导体纳米材料、金属纳米团簇、钙钛矿、镧系配合物及其他复合纳米材料中CPL的研究进展。此外,还讨论了不同的手性无机纳米材料中CPL的主要来源。本综述得出的结论有望在分子水平上实现对CPL活性材料的各向异性因子进行调控,促进其在量子计算、光学数据存储、信息加密、3D显示器和光学传感等多个领域的发展。 相似文献
107.
This study is aimed to establish a simple, rapid, and accurate ion chromatography approach for the simultaneous detection of six inorganic anions in urine. Various performance parameters affecting the determination of anions were optimized, including the selection of sample protein precipitation agent, eluent, and flow rate. The final eluent was 3.6 mmol/L sodium carbonate and 12% isopropanol with a flow rate of 0.6 mL/min. Acetonitrile was used for pretreatment to precipitate proteins, and the volume ratio of urine to acetonitrile was 1:4. The correlation coefficient of the target anion calibration curve ranged from 0.9973 to 0.9999. The limit of detection ranged from 1.50 to 12.0 μg/L, and the method detection limit ranged from 15.0 to 120 μg/L. The standard recovery rate for low, medium, and high concentrations ranged from 90 to 110%. The inter-day and intra-day relative standard deviations were <5%. The method has high accuracy and good reproducibility and is suitable for the separation and determination of anions in urine. 相似文献
108.
Lorenzo Mirizzi Mattia Carnevale Massimiliano DArienzo Chiara Milanese Barbara Di Credico Silvia Mostoni Roberto Scotti 《Molecules (Basel, Switzerland)》2021,26(12)
The development of effective thermally conductive rubber nanocomposites for heat management represents a tricky point for several modern technologies, ranging from electronic devices to the tire industry. Since rubber materials generally exhibit poor thermal transfer, the addition of high loadings of different carbon-based or inorganic thermally conductive fillers is mandatory to achieve satisfactory heat dissipation performance. However, this dramatically alters the mechanical behavior of the final materials, representing a real limitation to their application. Moreover, upon fillers’ incorporation into the polymer matrix, interfacial thermal resistance arises due to differences between the phonon spectra and scattering at the hybrid interface between the phases. Thus, a suitable filler functionalization is required to avoid discontinuities in the thermal transfer. In this challenging scenario, the present review aims at summarizing the most recent efforts to improve the thermal conductivity of rubber nanocomposites by exploiting, in particular, inorganic and hybrid filler systems, focusing on those that may guarantee a viable transfer of lab-scale formulations to technological applicable solutions. The intrinsic relationship among the filler’s loading, structure, morphology, and interfacial features and the heat transfer in the rubber matrix will be explored in depth, with the ambition of providing some methodological tools for a more profitable design of thermally conductive rubber nanocomposites, especially those for the formulation of tires. 相似文献
109.
无机纳米颗粒在塑料抗紫外的研究中一直备受关注,主要介绍了四种(TiO2、ZnO、SiO2、CeO2)典型的无机纳米颗粒在该领域的应用。首先归纳了其既能吸收又能反射或散射紫外线的抗紫外机理;其次,分别论述了不同无机纳米颗粒适用的紫外光波长范围,以在塑料中的添加方法和应用特点为主线,重点介绍了国内外四种无机纳米颗粒在塑料抗紫外性能中的研究现状和进展;最后,将四种无机纳米颗粒在塑料抗紫外性能中的应用特点进行了对比,提出了应用过程中存在的分散和相容性差等问题,以期为无机纳米颗粒的深入应用和发展提供一定的参考。 相似文献
110.