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101.
Growth of gem-grade nitrogen-doped diamond crystals heavily doped with the addition of Ba(N3)2 下载免费PDF全文
Additive Ba(N 3) 2 as a source of nitrogen is heavily doped into the graphite-Fe-based alloy system to grow nitrogendoped diamond crystals under a relatively high pressure (about 6.0 GPa) by employing the temperature gradient method.Gem-grade diamond crystal with a size of around 5 mm and a nitrogen concentration of about 1173 ppm is successfully synthesised for the first time under high pressure and high temperature in a China-type cubic anvil highpressure apparatus.The growth habit of diamond crystal under the environment with high degree of nitrogen doping is investigated.It is found that the morphologies of heavily nitrogen-doped diamond crystals are all of octahedral shape dominated by {111} facets.The effects of temperature and duration on nitrogen concentration and form are explored by infrared absorption spectra.The results indicate that nitrogen impurity is present in diamond predominantly in the dispersed form accompanied by aggregated form,and the aggregated nitrogen concentration in diamond increases with temperature and duration.In addition,it is indicated that nitrogen donors are more easily incorporated into growing crystals at higher temperature.Strains in nitrogen-doped diamond crystal are characterized by micro-Raman spectroscopy.Measurement results demonstrate that the undoped diamond crystals exhibit the compressive stress,whereas diamond crystals heavily doped with the addition of Ba(N 3) 2 display the tensile stress. 相似文献
102.
近红外漫反射线性加和光谱在烟叶复烤配方中的应用 总被引:3,自引:0,他引:3
应用近红外光谱分析技术进行烟叶复烤配方的辅助分析以及设计过程中,需要大量的不同混合比例的样品光谱,而混合样品光谱在实际生产过程中是很难获得的;且不同分级的样品很难实现均匀混合,不可避免的引入误差.文章提出了应用近红外漫反射光谱的线性加和原理产生"理论混合均匀光谱"来代替实际的混合样品光谱,不仅能够消除混合不均匀造成的误... 相似文献
103.
Case-cohort sampling is a commonly used and efficient method for studying large cohorts. In many situations, some covariates are easily measured on all cohort subjects, and surrogate measurements of the expensive covariates also may be observed. In this paper, to make full use of the covariate data collected outside the case-cohort sample, we propose'a class of weighted estimators with general time-varying weights for the additive hazards model, and the estimators are shown to be consistent and asymptotically normal. We also identify the estimator within this class that maximizes efficiency, and simulation studies show that the efficiency gains of the proposed estimator over the existing ones can be substantial in practical situations. A real example is provided. 相似文献
104.
We establish the additive theorem of L^2-decay rate for multi- dimensional Markov process with independent marginal processes. Using this and the decomposition method, we obtain explicit upper and lower bounds for decay rate of non-ergodic Jackson network. In some cases, we get the exact decay rate. 相似文献
105.
In many applications,covariates can be naturally grouped.For example,for gene expression data analysis,genes belonging to the same pathway might be viewed as a group.This paper studies variable selection problem for censored survival data in the additive hazards model when covariates are grouped.A hierarchical regularization method is proposed to simultaneously estimate parameters and select important variables at both the group level and the within-group level.For the situations in which the number of parameters tends to∞as the sample size increases,we establish an oracle property and asymptotic normality property of the proposed estimators.Numerical results indicate that the hierarchically penalized method performs better than some existing methods such as lasso,smoothly clipped absolute deviation(SCAD)and adaptive lasso. 相似文献
106.
Let be a densely defined operator on a Banach space X. Characterizations of when generates a C0‐semigroup on X are known. The famous result of Lumer and Phillips states that it is so if and only if is dissipative and is dense in X for some . There exists also a rich amount of Banach space results concerning perturbations of dissipative operators. In a recent paper Tyran–Kamińska provides perturbation criteria of dissipative operators in terms of ergodic properties. These results, and others, are shown to remain valid in the setting of general non–normable locally convex spaces. Applications of the results to concrete examples of operators on function spaces are also presented. 相似文献
107.
Lijun Jia Huaiwu Zhang Jun Luo Yingli Liu Qiye Wen 《Journal of magnetism and magnetic materials》2010,322(14):1934-1938
MgO was introduced into low-temperature sintered Z-type hexaferrites in order to improve their high-frequency electromagnetic properties. In the doped samples the major Z-type phase coexists with a small amount of W-type magnetoplumbite phase. The addition of MgO causes a decrease of the average grain size and an increase of the magnetocrystalline anisotropy (K1) and the saturation magnetization (Ms) with the increment of K1 being larger than that of Ms. These factors result in a reduce of the initial permeability. Also, the samples with MgO additive exhibit higher Q-factor and dc resistivity. Furthermore, the introduction of MgO can decrease the dielectric constant and improve the dielectric loss tangent of the samples by reducing the electronic transition in octahedral site (B-site) between Fe2+ and Fe3+ ions. 相似文献
108.
109.
The heat of formation of a number of key C1 and C2 chlorofluorocarbons and hydrochlorofluorocarbons have been calculated by G3, G3MP2, G3MP2B3 and G3B3 methods. Based on the results of the atomization approach, it was found that the errors are approximately dependent upon the number of C-F or C-Cl bonds. Moreover, the bond additive correction (BAC) procedure and isodesmic reactions approach improved the accuracy and decreased these system errors significantly. The extended comparison between the BAC procedure and isodesmic reaction approaches had been made; the latter yielded the best results and showed broader applicability. 相似文献
110.
Radon exhalation rate from fly ash samples and from the homogeneous mixture of fly ash of different proportions additive in soil and cement samples to study the effect of the addition was measured by cup dosimeter using SSNTDs. Radon activities were found to vary from (1018±38) to ( whereas the radon exhalation rate varied from (366±14) to . A gradual increase has been observed in samples having fly ash as an additive in cement samples whereas a gradual decrease was observed in soil samples after the addition of fly ash. 238U in fly ash was measured by a low-level NaI (Tl)-based gamma ray spectrometer. The results show enhancement in U concentration in fly ash as compared to coal samples, whereas radon exhalation rate is less in fly ash samples. 相似文献