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911.
M. BoulovaG. Lucazeau 《Journal of solid state chemistry》2002,167(2):425-434
Nanocrystallites of tungsten oxide samples of 2, 4, 16, 35 and 60 nm of diameter were prepared by cryosol and pyrosol techniques. The pressure- and temperature-induced phase transitions of these samples were monitored by Raman spectrometry from 0.1 MPa to 34 GPa and from 77 to 1200 K. The tetragonal (α)-orthorhombic (β)-monoclinic (γ) transitions in these nanometric samples are strongly downshifted in temperature by comparison with the bulk WO3. For instance, the tetragonal phase which exists above 1171 K for the bulk tungsten oxide can be stabilized at 700 K for the 35 nm sample. In the same way, the monoclinic P21/n-monoclinic P21/c high-pressure-induced transition is slightly shifted from 0.1 GPa to a higher pressure (1.5 GPa). The discussion of these transition-line shifts is based on thermodynamic considerations in which the surface energy of crystallites plays an important role. 相似文献
912.
913.
914.
915.
Karen Wright Fernando FormaggioClaudio Toniolo Roland TörökAntal Péter Michel WakselmanJean-Paul Mazaleyrat 《Tetrahedron letters》2003,44(22):4183-4186
Resolution of trans 3-(9-fluorenylmethyloxycarbonylamino)-1-oxyl-2,2,5,5-tetramethylpyrrolidine-4-carboxylic acid (Fmoc-POAC-OH) was quickly achieved upon esterification with (aR)-1,1′-binaphthyl-2,2′-diol, chromatographic separation of the obtained diastereomers, and facile saponification of the aryl ester function with removal of the chiral auxiliary. 相似文献
916.
917.
918.
Matthew T. AllinghamAndrew Howard-Jones Patrick J. MurphyPeter W.R. Caulkett 《Tetrahedron letters》2003,44(48):8677-8680
The preparation of the tetracyclic C2-symmetric guanidinium salts 5 and 11-13 is reported together with their application to enantioselective transformations. 相似文献
919.
Nobuo Tanaka Hironobu Iwasaki Takeshi Fukutome Ken Hosoya Takeo Araki 《Journal of separation science》1997,20(10):529-538
Pseudo-stationary phases for electrokinetic chromatography were prepared by the alkylation of starburst dendrimers (SBDs). The SBD-supported pseudo-stationary phase with dodecyl groups showed higher efficiency than short-akyl derivatives, and maintained the hydrophobic property inthe presence of methanol. The dodecyl-modified SBD provided wide migration time windows ar high methanol content to effect the separation of sixteen aromatic hydrocarbons, the priority pollutants designated by EPA, in 65% methanol. The selectivity of polymer-supported pseudo-stationary phase can be varied simply by changing the length of the alkyl groups. The dodecyl SBD showed relatively similar selectivity as sodium dodecyl culfate micelle, whereas short alkyl derivatives showed preference towards rigid and planar compounds based on the rigid and planar compounds based on the rigid polymer backbones. The selectivity of SBD-supported pseudo-stationary phases was dominated by the chain length of the alkyl groups, with the minor effect of the structure of the core and the generation of SBD where alkyl groups were attached. 相似文献
920.
碳十八键合锆胶固定相的制备与色谱性能评价 总被引:5,自引:0,他引:5
用诱导聚合胶体凝聚法(PICA)制得的二氧化锆微球与碳十八三乙氧基硅烷反应制备了碳十八键合锆胶固定相(ODZ),评价了该柱填料的色谱性能,并用此固定相分离了中性和碱性化合物。 相似文献