Kinetic features of ethylene polymerization over supported catalysts [2,6‐bis(imino)pyridyl iron dichloride/magnesium dichloride] with AlR3 as an activator

The effects of polymerization temperature, polymerization time, ethylene and hydrogen concentration, and effect of comonomers (hexene‐1, propylene) on the activity of supported catalyst of composition LFeCl₂/MgCl₂‐Al(i‐Bu)₃ (L = 2,6‐bis[1‐(2,6‐dimethylphenylimino)ethyl] pyridyl) and polymer characteristics (molecular weight (MW), molecular‐weight distribution (MWD), molecular structure) have been studied. Effective activation energy of ethylene polymerization over LFeCl₂/MgCl₂‐Al(i‐Bu)₃ has a value typical of supported Ziegler–Natta catalysts (11.9 kcal/mol). The polymerization reaction is of the first order with respect to monomer at the ethylene concentration >0.2 mol/L. Addition of small amounts of hydrogen (9–17%) significantly increases the activity; however, further increase in hydrogen concentration decreases the activity. The IRS and DSC analysis of PE indicates that catalyst LFeCl₂/MgCl₂‐Al(i‐Bu)₃ has a very low copolymerizing ability toward propylene and hexene‐1. MW and MWD of PE produced over these catalysts depend on the polymerization time, ethylene and hexene‐1 concentration. The activation effect of hydrogen and other kinetic features of ethylene polymerization over supported catalysts based on the Fe (II) complexes are discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5057–5066, 2007     

Transesterification of an RNA model in buffer solutions in H2O and D2O

Transesterification of a phosphodiester bond of RNA models has been studied in various buffer solutions, under neutral and slightly alkaline conditions in H₂O and D₂O. The results show that imidazole is the only buffer system where a clear buffer catalysis on the cleavage of a phosphodiester bond is observed. The rate enhancement in sulphonic acid buffers is smaller, and a sulphonate base, particularly, is inactive as a catalyst. The rate‐enhancing effect of imidazole is, however, catalytic, and the catalytic inactivity of sulphonate buffers can be attributed to their structure and/or charge. The catalysis by imidazole is a complex system which, in addition to first‐order reactions, involves a process that shows a second‐order dependence in imidazole concentration. The latter reaction becomes significant in acidic imidazole buffers (pH < pK_a), as the buffer concentration increases. The kinetic solvent deuterium isotope effect k_H/k_D, referring to first‐order catalysis by imidazole base, is 2.3 ± 0.3. That referring to second‐order catalysis is most probably much larger, but an accurate value could not be obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

样条空间S~μ_k（△）的维数

本文考虑了欧式空间Ｒ￣ｎ中任意单纯形剖分上的样条函数空间．证明了当ｋ≥（３μ＋１）２￣（ｎ－２）＋１时，计算任意单纯形剖分Δ上的ｋ次μ阶光滑样条空间的维数，可归结为计算每个σ－关联域（ｉ－单纯形σ∈Δ）Ｒ（σ）上的２￣（ｎ－ｉ－１）μ次μ阶光滑（ｉ≤ｎ－１）样条空间的维数。这里σ－关联域Ｒ（σ）是指Δ中所有包含σ的单纯形所成的单纯形剖分．     

Structural study and electrical properties of Zr-doped Nd<Subscript>2</Subscript>Sn<Subscript>2</Subscript>O<Subscript>7</Subscript> pyrochlore compounds

Nd₂Sn₂O₇ pyrochlores with the substitution of Zr⁴⁺ were prepared by conventional ceramic double sintering technique. The single-phase formation was confirmed by X-ray diffraction and neutron diffraction techniques. Relative intensity calculations for X-ray diffraction analysis were performed for oxygen positional parametersx = 0.331 and 0.375, while Rietveld refinements were employed for neutron diffraction data. The neutron diffraction study revealed that there are only two anion sites with 48f and 8b positions. This indicates that the 8a site, i.e. O(3) sublattice, is completely vacant and the structure is a perfect cubic pyrochlore with space group Fd3m (O _h ⁷ ). From the conductivity measurements, it is observed that the electronic conductivity dominates from room temperature up to about 525 K and forT > 525 K, the oxygen ion conduction dominates the charge transport in these compositions. Complex impedance spectroscopy indicates the existence of grain and grain boundary as two separate elements.     

Limited resolution in complex network community detection with Potts model approach

According to Fortunato and Barthélemy, modularity-based community detection algorithms have a resolution threshold such that small communities in a large network are invisible. Here we generalize their work and show that the q-state Potts community detection method introduced by Reichardt and Bornholdt also has a resolution threshold. The model contains a parameter by which this threshold can be tuned, but no a priori principle is known to select the proper value. Single global optimization criteria do not seem capable for detecting all communities if their size distribution is broad.     

EchSGB远距离照明条件下的焦开关

推导了复变量双曲余弦平方-高斯光束(EchSGB)被无光阑透镜聚焦后的轴上光强分布公式,在此基础上通过数值计算和分析发现,EchSGB只有在远距离照明条件下才存在焦开关现象.焦点跃变位置随光束参数和对应高斯光束的菲涅尔数不同而变化,得到了EchSGB在平顶情形下产生焦开关的相对入射距离为11.13,表明在远距离照明和无光阑透镜精密调焦时,对于EchSGB要考虑焦开关现象的影响.     

Small-world and the growing properties of the Chinese railway network

By using the tools of statistical physics and recent investigations of the scaling properties of different complex networks, the structural and evolving properties of the Chinese railway network (CRN) is studied. It has been verified that the CRN has the same small-world properties of the Indian railway network (IRN). According to the class of small-world networks, we believe the CRN is a single scale. In addition, a novel result is obtained. Measurements on the CRN indicate that the rate at which nodes acquire links depends on the node’s degree and follows a power law.