Activation of Carbon Dioxide and Synthesis of Propylene Carbonate

Cycloaddition of carbon dioxdie and propylene oxide to propylene carbonate catalyzed by tetra-tert-butyl metal phthalocyanine in the presence of tributylamine(TBA) shows higher yield than catalyzed by unsubstituted metal phthalocyanine.Comparing different catalysts of diverse metals,(t-Bu)4PcMg is more active than (t-Bu)PcFe ,But(t-Bu)4PcCo and (t-Bu)4PcNi only have low catalytic activities towards the reaction.Moreover,the yield will increase as the temperature increases.     

Determination of proteins at nanogram levels by a resonance light-scattering technique with tetra-substituted sulphonated aluminum phthalocyanine

This is the first report on the determination of proteins with tetra-substituted sulphonated aluminum phthalocyanine (AlS₄Pc) by resonance light-scattering (RLS). At pH 3.0, the weak RLS of AlS₄Pc can be enhanced by the addition of proteins. Based on this, a novel quantitative method has been developed for the determination of proteins in aqueous solutions. Under optimal conditions, the linear ranges of the calibration curves were 0.050–2.0 μg ml⁻¹ for both human serum albumin (HSA) and human r-IgG. The detection limits were 12.7 ng ml⁻¹ for HSA and 16.1 ng ml⁻¹ for human r-IgG. The method has been applied to the analysis of total protein in human serum samples collected from the hospital and the results were in good agreement with those reported by the hospital, which indicates that the method presented here is not only sensitive, simple, but also reliable and suitable for practical applications.     

四磺酸基酞菁锌在水和非水溶剂中的电化学性质研究

在非水溶剂（二甲基亚砜（ＤＭＳＯ）及Ｎ,Ｎ＿二甲基甲酰胺（ＤＭＦ））中的伏安曲线．呈现三对电流峰,表明存在三个可逆或准可逆酞菁配体的单电子转移过程,而在水溶液中则不呈现准可逆行为,且波形改变很大．此外,还比较了四磺酸基酞菁锌的水溶液在自然光和红光（６００～７００ｎｍ）照射下的循环伏安曲线,其氧化还原峰的数目和峰电位基本不变,但在红光照射下比自然光照射下的峰电流明显增大．     

Sulfide ion electrooxidation catalysed by cobalt phthalocyanine microcrystals

Electrooxidation of sulfide ion catalysed by microcrystals of cobalt phthalocyanine was investigated by cyclic voltammetry in 0.5M KNO₃ at pH 9.22. Traces of catalyst were immobilized at the surface of a paraffin-impregnated graphite electrode by the mechanical transfer of its powder. The electro-oxidation of HS^– proceeds in two irreversible steps, with the first peak between 0 V and –0.12 V and the second at 0.17 V. The first step is second order in HS^– and its product is the adsorbed disulfide, which may further dissociate to give adsorbed sulfur atoms. The reduction of sulfur occurs at –0.1 V.     

酞菁键合硅胶的制备及分离取代酞菁异构体

制备和表征了一种新的酞菁键合硅胶，三-β-(辛巯基)-β-(磺酰胺基)-酞菁铜键合硅胶。研究了该键合酞菁硅胶作为HPLC固定相的基本色谱性能。实验结果表明，该固定相可以分离四-α-(2，2，4-三甲基-3-戊氧基)酞菁(铜、镍)的4种异构体，也可以观察到四-α-(2，2，4-三甲基-3-戊氧基)无金属酞菁的4种异构体，而商业C₁₈(VERTEX Eurospher)却只能观察到两组峰，表明这种酞菁键合硅胶固定相在分析、分离一些取代酞菁异构体方面比商业C₁₈具有更好的分离效果。     

New polythiophenes bearing electron-acceptor phthalocyanine chromophores

Two new donor-acceptor copolymers comprising a polythiophene backbone, and bearing phthalocyanine chromophores on the side chains have been prepared. Preliminary photophysical characterization of these materials by FTIR photoinduced absorption indicates that electron transfer from the polythiophene to the phthalocyanine units takes place.     

四磺化酞菁钴在微乳液、醇-水体系中的二聚现象研究

采用分光光度法研究了四磺化酞菁钴（ＣｏＴＳＰｃ），在微乳液（ＴｒｉｔｏｎＸ－１００－壬烷－正戊醇－水）、醇－水（甲醇、乙醇、丙醇）体系中的二聚现象，计算了ＣｏＴＳＰｃ的二聚常数ＫＤ。结果表明，ＣｏＴＳＰｃ的二聚常数ＫＤ值随着微乳液中表面活性的浓度及醇－水溶液的介电常数的增加而减小。     

金属酞菁化合物在TiO2表面的分散研究

Dispersion of copper(Ⅱ) phthalocyanine (CuPc), copper(Ⅱ) phthalocyaninesulfonate (CuPcS) and cobalt(Ⅱ)phthalocyaninetetrasulfonate (CoPcTS) on the surface of titanium dioxide was investigated by XRD, XPS, FT-IR and UV-Vis techniques. Results show that interaction between CuPc and TiO2 was very weak and CuPc was difficult to disperse on the surface of the support. While partly sulfurized CuPcS could be dispersed on the surface of support through sulfo-groups and its dispersion capacity was determined to be 0.085 g CuPcS/g TiO2. Completely sulfurlzed CoPcTS could also be dispersed on the surface of TiO2 as a monolayer and its dispersion capacity was 0.12 g CoPcTS/g TiO2. Interactions of the sulfo-groups as well as the electrons of CoPcTS with the surface of TiO2 could be evidenced by FT-IR characterization. Therefore, it was suggested that CoPcTS molecules be adsorbed on the surface of TiO2 in a flat-lying mode while CuPcS in a slanting one. UV-Vis spectra show that the dispersed CuPcS and CoPcTS molecules exist in both forms of monomers and dimers.     

Synthesis of alkyl-substituted phosphorus phthalocyanines and triazatetrabenzocorroles

New alkyl-substituted phosphorus phthalocyanines and triazatetrabenzocorroles were synthesized. The structures of these complexes were confirmed by ¹H, ¹³C, and ³¹P NMR spectroscopy, mass spectrometry, and electronic absorption spectroscopy. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1403–1407, July, 2007.     

四(α-高歧化度烷氧基)酞菁合成关键步骤的研究

烷氧基邻苯二腈是酞菁合成的重要中间体,但高歧化度烷氧基邻苯二腈的合成由于副产物多,产率低下而成为此类酞菁应用的"瓶颈".文中对反应副产物进行了分离纯化,并利用红外、气质联用、1HMR和元素分析等测试手段对其进行了表征.且根据测试数据推导出了副产物结构式为1,2,1'2' 四腈基 3,3' 二苯基醚.这一副反应机制的阐明,对于寻求对主反应有利的条件,具有重要的意义.