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101.
Alain Adenier Eva Cabet-Deliry Sophie Griveau Florence Mercier Christine Vautrin-Ul 《Surface science》2006,600(21):4801-4812
This study investigates the spontaneous grafting of different para-substituted phenyl groups on carbon and metallic surfaces from diazonium salts solutions. Glassy carbon, nickel, zinc and iron plates were allowed to react with an acetonitrile solution of aryldiazonium tetrafluoroborate salt by simple dipping. The surfaces were characterized before and after their immersion by XPS and AFM to evidence the formation of a coating on the different materials. The results are indicative of the presence of substituted phenyl groups on all the investigated surfaces. This study also aims at correlating grafting efficiency with metal reactivities and diazonium salt electronic properties by means of AFM and FT-IRRAS. For this purpose, zinc and nickel were chosen due to their opposite reducing properties and two diazonium salts were selected with electron-donor or -withdrawing para-substituents. The results tend to indicate that redox properties of both partners (diazonium + metal) are of prime importance for grafting to occur. 相似文献
102.
XU Yichao CHEN Minru & MA Songya Academy of Mathematics Systems Science Chinese Academy of Sciences Beijing China College of Mathematics Information Sciences Henan University Kaifeng China 《中国科学A辑(英文版)》2006,49(10):1392-1404
We known that the maximal connected holomorphic automorphism group Aut (D)(0) is a semi-direct product of the triangle group T(D) and the maximal connected isotropic subgroup Iso(D)(0) of a fixed point in the complex homogeneous bounded domain D and any complex homogeneous bounded domain is holomorphic isomorphic to a normal Siegel domain D(VN,F). In this paper, we give the explicit formula of any holomorphic automorphism in T(D(VN, F)) and Iso(D(VN,F))(0), where G(0) is the unit connected component of the Lie group G. 相似文献
103.
Takuya Hashimoto Koichi Kitazawa Masaaki Nakabayashi Tadashi Shiraishi Youichi Suemune Takakazu Yamamoto Hideomi Koinuma 《应用有机金属化学》1991,5(4):325-330
For low-temperature deposition of oxide films relating to Bi-Sr-Ca-Cu-O superconductors, photo-absorption and -decomposition properties were examined with respect to copper and alkaline-earth ß-diketonates. It was confirmed that all ß-diketonates examined were promising as source materials for photochemical vapour deposition (photo-CVD) using a low-pressure mercury lamp, in view of their large light absorption coefficients at wavelength 254 nm. The light irradiation was effective for the formation of highly crystalline oxide films at temperatures below 600 °C. By combining two sources, Ca2CuO3 and SrCuO2 films were prepared. Photo-CVD of c-axis oriented Bi2Sr2CuOx film was achieved by the irradiation of ternary sources of Bi(C6H5)3 and strontium and copper ß-diketonates at 500 °C. 相似文献
104.
Kefu Fu Kevin Henbest Yufen J. Zhang Shane Valentin Ya-Ping Sun 《Journal of photochemistry and photobiology. A, Chemistry》2002,150(1-3):143-152
Dimeric fullerene macromolecules were prepared via the complexation of two fullerenylated 2,2′:6′,2″-terpyridine ligands with Fe(II) and Co(II) ions. The solubility of these macromolecules in some organic solvents allowed both their structural characterization and a study of their optical properties. The electronic absorption and emission of the macromolecules in solution were evaluated; and the results indicated no meaningful ground-state and excited singlet state intramolecular charge transfer interactions. However, the laser flash photolysis results could be explained in terms of the electron transfer quenching of the excited triplet methanofullerene moiety by the center metal–ligand complex in the macromolecules. The optical limiting properties of the macromolecules in solution were also investigated in comparison with those of the ligands for an evaluation of the complexation effects. 相似文献
105.
Yamada Kaoru Matsutani Shigeaki Uchiyama Akira Takahashi Toshio 《Journal of inclusion phenomena and macrocyclic chemistry》1991,11(1):49-54
Analyses of crown ether complexes of alkali metal ions and characterization of the complexes formed inm-nitrobenzyl alcohol have been carried out by fast atom bombardment (FAB) mass spectrometry. By using m-nitrobenzyl alcohol as a matrix for measurements, the stoichiometry of the complexes was assessed on the basis of the observed FAB peaks. In addition, the formation of crown ether-alkali metal complexes at a 2 : 1 molar ratio was enhanced by increasing the ionic radius of the metal ion in agreement with previous observations. On these grounds, FAB mass spectrometry may provide a rapid means for investigation of the complexation behavior of crown ethers and the stoichiometry of the complexes. 相似文献
106.
107.
Certain condition on the second fundamental form of CR submanifolds of maximal CR dimension of complex Euclidean space 总被引:1,自引:0,他引:1
We treat m-dimensional real submanifolds M of complex space forms ̿M when the maximal holomorphic tangent subspace is (m−1)-dimensional. On these manifolds there exists an almost contact structure F which is naturally induced from the ambient space and in this paper we study the condition h(FX,Y)−h(X,FY) = g(FX,Y)η, η∊ T⊥(M), on the structure F and on the second fundamental form h of these submanifolds. Especially when the ambient space ̿M is a complex Euclidean space, we obtain a complete classification of submanifolds M which satisfy these conditions.Mathematics Subject Classifications (2000): 53C15, 53C40, 53B20. 相似文献
108.
109.
Dmitry Yu. Murzin 《Reaction Kinetics and Catalysis Letters》2007,90(2):225-232
Reaction route analysis is applied to visualize reaction networks in several heterogeneous catalytic reactions. Combination
of the theory of complex reactions with the notion of catalytic cycles results in a topological representation of complex
mechanisms with the nodes comprising all possible surface species including free sites and branches indicating interconnections
between reactions. 相似文献
110.
Simultaneous DSC-TG and DTA-TG were used to investigate the calatytic effect of the metal on the thermal decomposition of
a cellulose matrix containing small copper particles. The techniques were also used to demonstrate the effect of the metal
particles on the subsequent activation of the carbon matrix, a process which develops the pore structure necessary to expose
the metal particles to the gas phase. Temperature programmed desorption was used to study the initial mass loss found on activation.
To quantify the catalytic effect of the copper particles on the activation process an estimate was made of the activation
energy of the catalysed and uncatalysed reactions. The work gives valuable information on the processes involved in the preparation
of a new range of metal-carbon catalysts.
In celebration of the 60th birthday of Dr. Andrew K. Galwey 相似文献